Chemistry:Selenogallate
Selenogallates (or selenidogallates) are chemical compounds which contain anionic units of selenium connected to gallium. They can be considered as gallates where selenium substitutes for oxygen. Similar compounds include the thiogallates and selenostannates. They are in the category of chalcogenotrielates or more broadly chalcogenometallates.[1]
Formation
Selenogallates may be produced by heating a metal azide with gallium monoselenide and selenium in a sealed tube.[1]
Selenogallates containing Se2 units are formed by heating with selenium. Conversely, by heating, extra selenium vapour can be lost forming a compound with less selenium.[2]
Properties
Most selenogallates are semiconductors. Their resistance drops on exposure to light. Also selenogallates are often coloured, most often red.
Selenogallate structures can include rings such as the four-membered ring: [GaSeGaSe] or the five-membered [GaSeSeGaSe]. These can be linked into chains.
Use
Selenogallates are primarily of research interest. They are being researched for photovoltaic cells where efficiencies over 20% are possible,[3] and for photoconductors, and non-linear optical devices.
List
name | chem | mw | crystal system | space group | unit cell Å | volume | density | comment | CAS
no |
references |
---|---|---|---|---|---|---|---|---|---|---|
LiGaSe2 | 234.581 | orthorhombic | Pna21 | a=6.8478 b=8.2575 c=6.5521 Z=4 | 370.5 | 4.206 | band gap 3.39; SHG | [4] | ||
[H2dap]4Ga4Se10 dap = 1,2-diaminopropane | monoclinic | C2/c | a 10.821 b 10.820 c 21.386, β 97.265° | [5] | ||||||
[(dienH2)(dienH)3]Ga5Se10 dien = diethylenetriamine | monoclinic | P21/c | a 6.3116 b 13.748 c 47.890 β 90.640° | chain | [6] | |||||
[(tetaH2)3(teta)]Ga6Se12 teta = triethylenetetramine | monoclinic | Cc | a 20.566 b 25.896 c 12.785 β 125.568° | chain | [6] | |||||
[bappH2][Ga2Se4] bapp =1,4-Bis-(3-aminopropyl)piperazine | 657.63 | triclinic | P1 | a=6.3517 b=7.8498 c=10.7818 α=71.457° β=84.925° γ=72.084° Z=1 | 484.93 | 2.30 | yellow; | [7] | ||
[1,3-pdaH2][Ga2Se2(Se2)(Se3)] 1,3-pda = 1,3-diaminopropane | monoclinic | P21 | a 7.5724 b 12.3856 c 8.0889 β 94.120° | band gap 2.08 eV; GaSeSeSeGaSe & GaSeSeGaSe rings; red | [8] | |||||
[1,4-bdaH2][Ga2Se3(Se2)] 1,4-bda = 1,4-diaminobutane | monoclinic | C2/c | a 11.7660 b 11.7743 c 10.9763 β 110.170° | band gap 2.32 eV; orange | [8] | |||||
[Me2NH2]2[Ga2Se2(Se2)2] | monoclinic | P21/c | a 14.13 b 8.456 c 14.07 β 100.32° | band gap 2.07 eV; red | [8] | |||||
α-[AEPH]2[Ga2Se2(Se2)2] AEP = N-(2-aminoethyl)piperazine | monoclinic | Pn | a 6.981 b 15.436 c 11.831 β 91.462° | band gap 1.93 eV; red | [8] | |||||
β-[AEPH]2[Ga2Se2(Se2)2] | monoclinic | P21/c | a 10.623 b 16.495 c 7.163 β 94.93° | band gap 2.10 eV; red | [8] | |||||
[Ga(en)3][Ga3Se7(en)] · H2O | 1090.02 | orthorhombic | Pna21 | a=14.279 b=9.616 c=19.676 Z=4 | 2701.6 | 2.680 | bicyclic Ga3Se7 | [9] | ||
NaGaS2 | monoclinic | C2/c | a 10.226 b 10.227 c 13.506 β 100.926° | 1389.9 | [10] | |||||
NaGaS2•H2O | monoclinic | C2/c | a=9.5160 b=113986 c=17.8761 β=101.590 | 1899 | [10] | |||||
NaGa3Se5 | 626.95 | orthorhombic | P212121 | a=9.764 b=13.624 c=27.000 Z=16 | 3591.6 | 4.638 | [11] | |||
KGaSe2 | 266.74 | monoclinic | C2/c | a = 10.878, b = 10.872, c = 15.380, β = 100.18° Z=16 | 1790.3 | 3.959 | air stable; light yellow; mp=965 °C; [Ga4Se10]8− units connected into sheets; band gap 2.60 eV | [12] | ||
MnGa2Se4 | band gap 2.7 eV | [13] | ||||||||
[Mn(en)3][Ga2Se5] en = Ethylenediamine | 771.51 | orthorhombic | Pbcn | a=9.772 b=15.297 c=13.749 Z=4 | 2055.2 | 2.50 | red; {[Ga2Se5]2-}∞ chains Ga2Se2 and Ga2Se3 rings | [7] | ||
[Mn(dap)3]0.5GaSe2 | orthorhombic | Cmcm | a 9.645 b 16.754 c 12.891 | [5] | ||||||
[Mn(atep)]Ga2S4 atep = 4-(2-aminoethyl)triethylenetetramine | monoclinic | P21/n | a 9.909 b 11.947 c 14.831, β 102.268° | [5] | ||||||
[Co(en)3]Ga2Se | orthorhombic | Cmcm | a 9.692 b 15.631 c 12.698 | band gap 3.27 eV | [6] | |||||
{[Ni(tepa)]2SO4}[Ni(tepa)(Ga4S6(SH)4)] tepa = tetraethylenepentamine | monoclinic | C2/c | a 38.829 b 12.290 c 22.471 β 98.398° | [5] | ||||||
cupric selenogallate | CuGaSe2 | 291.186 | tetragonal | a = 5.5963 c = 11.0036 Z=4 | 344.617 | 5.612 | metallic grey | [14] | ||
ZnGa2Se4 | tetragonal | I42m | [15] | |||||||
ZnGa2Se4 | cubic | Fm3m | >15.5GPa | [15] | ||||||
Na3Zn2Ga2Se4 | 519.90 | tetragonal | I41acd | a 13.481 c 19.26 Z=16 | 3500 | 3.946 | red | [16] | ||
Na6Zn3Ga2Se9 | monoclinic | C2/c | a 16.71 b 16.69 c 13.79 β 101.346° | [17] | ||||||
KZn4Ga5Se12 | R3 | SHG | [18] | |||||||
LiGaGe2Se6 | 695.60 | orthorhombic | Fdd2 | a 12.5035 b 23.710 c 7.1177 | 2110.1 | 4.336 | brown; band gap 2.64 eV; mp=710 °C | [19][20] | ||
Li2Ga2GeS6 | orthorhombic | Fdd2 | a=12.0796 b=22.73 c=6.84048 | [21] | ||||||
NaGaGe3Se8 | monoclinic | P21/c | a 7.233 b 11.889 c 17.550 β 101.75° | [22] | ||||||
KGaGeSe4 | 497.25 | monoclinic | P21/c | a=7.3552 b=12.4151 c=17.6213 β =97.026 Z=8 | 1597.02 | 4.136 | yellow | [23] | ||
RbGaSe2 | 313.11 | monoclinic | C2/c | a = 10.954, b = 10.949, c = 16.064, β = 99.841° Z=16 | 1898.2 | 4.382 | colourless; mp=930 °C; ∞2[Ga4Se88−] layers of supertetrahedra; | [1] | ||
RbZn4Ga5Se12 | R3 | SHG | [18] | |||||||
RbGaGeSe4 | 543.62 | orthorhombic | Pnma | a=17.5750 b=7.4718 c=12.4449 Z=8 | 1634.23 | 4.419 | orange | [23] | ||
AgGaSe2 | tetragonal | I42d | a = 5.9921, c = 10.883 | 5.71 | transparent from 0.71 to 18 µm; band gap ~1.7 | [24] | ||||
AgGa5Se8 | P42m | a=5.50 c=11.04 | band gap 2.1 eV | [24] | ||||||
Ag9GaSe6 | P213 | band gap 0.56 eV | [24] | |||||||
Ag9GaSe6 | cubic | F43m | a=11.126 | [24] | ||||||
LixAg1–xGaSe2 (x = 0.2–0.8) | tetragonal | I42d | SHG | [4] | ||||||
KAg3Ga8Se14 | 2025.91 | monoclinic | Cm | a 12.8805 b 11.6857 c 9.6600 β 115.998° Z=2 | 1306.87 | 5.148 | orange | [25] | ||
AgGaGe5Se12 | red; transparent for 0.6–16.5 μm; band gap 2.2 eV | [26] | ||||||||
CdGa2Se4 | tetragonal | I4 | a=5.3167 c=10.2858 Z=2 | semiconductor | [27][28] | |||||
CdGa2Se4 | cubic | F43m | a=5.64 Z=4 | >21 GPa metallic | [28] | |||||
CdGa2Se4 | cubic | Fm3m | a=5.03 Z=4 | 4-7.4 GPa | [28] | |||||
KCd4Ga5Se12 | trigonal | R3 | a 14.362 b 14.362 c 9.724 | [29] | ||||||
RbCd4Ga5Se12 | trigonal | R3 | a 14.4055 b 14.4055 c 9.7688 | band gap 2.19 eV; SHG=19×AgGaS2 | [30][29] | |||||
InGaSe2 | tetragonal | I4/mcm | a = 8.051, c = 6.317 Z=4 | [31] | ||||||
SnGa4Se7 | 622.08 | monoclinic | Pc | a=7.269 b=6.361 c=12.408 β =106.556 Z=2 | 549.9 | 3.757 | light yellow;SHG 3.8 × AgGaS2 | [32] | ||
KGaSnSe4-cP84 | 543.35 | cubic | Pa3 | a=13.5555 Z=12 | 2490.8 | 4.347 | red | [23] | ||
RbGaSnSe4-cP84 | cubic | Pa3 | a=13.7200 Z=12 | 589.72 | 4.550 | [23] | ||||
RbGaSn2Se6 | 866.33 | trigonal | R3 | a=10.4697 c=9.476 Z=3 | 899.5 | 4.798 | deep red | [33] | ||
SnGa2GeSe6 | 804.48 | orthorhombic | Fdd2 | a = 47.195, b = 7.521, c = 12.183, Z = 16 | 4324 | 4.943 | red; SHG 1.7 × AgGaS2 | |||
CsGaSe2-mC64 | monoclinic | C2/c | a = 11.043, b = 11.015, c = 16.810, β = 99.49°, Z = 16 | 2016.7 | light grey; layers of supertetrahedra ∞2[Ga4Se84–]; band gap 3.5 eV | [34] | ||||
CsGaSe2-mC16 | monoclinic | C2/c | a = 7.651, b = 12.552, c = 6.170, β = 113.62°, Z = 4 | 542.9 | over 610 °C; chains ∞1[GaSe2–] | [34] | ||||
CsGaSe3 | monoclinic | P21/c | a=7.727, b=13.014, c=6.705, β=106.39°, Z=4 | red; chains; band gap 2.25 eV | [35] | |||||
Cs2Ga2Se5 | 800.07 | monoclinic | C2/c | a = 15.3911, b = 7.3577, c = 12.9219, β = 126.395°, Z = 4 | 1177.89 | 4.51 | yellow; ∞1[Ga2Se3(Se2)2–] band gap 1.95 eV | [36] | ||
Cs4Ga6Se11 | triclinic | P1 | a=9.707 b=9.888 c=16.780 α=76.425° β=77.076° γ=60.876° | 1356.3 | ∞1[Ga6Se11]4– | [37] | ||||
Cs6Ga2Se6 | monoclinic | P21/c | a=8.480 b=13.644 c=11.115 β =126.22 Z=2 | mp=685 °C; isolated double tetrahedra [Ga2Se6]6− | [38] | |||||
Cs8Ga4Se10 | triclinic | P1 | a= 7.870 b=9.420 c=11.282 α=103.84° β=93.43° γ=80.88° Z=1 | 4.42 | tetrameric | [39] | ||||
Cs10Ga6Se14 | monoclinic | C2/m | a=18.233 b=12.889 c=9.668 β=108.20 Z=2 | 4.39 | hexameric | [39] | ||||
(Cs6Cl)6Cs3[Ga53Se96] | 16671.51 | trigonal | R3m | a = 11.990, c = 50.012 Z=1 | 6226.5 | 4.446 | yellow; band gap 2.74 eV | [40] | ||
CsZn4Ga5Se12 | trigonal | R3 | [18] | |||||||
CsGaGeSe4 | 591.06 | orthorhombic | Pnma | a=17.7666 b=7.5171 c=12.6383 Z=8 | 1687.9 | 4.652 | white | [23] | ||
Cs2Ge3Ga6Se14 | 2007.41 | P3m1 | a=7.6396 c=13.5866 Z=1 | 686.72 | 4.854 | black | [41] | |||
CsAgGa2Se4 | monoclinic | P21/c | a=11.225, b=7.944, c=21.303, β=103.10, Z=8 | 1850.3 | layered | [42] | ||||
CsCd4Ga5Se12 | trigonal | R3 | a 14.4204 b 14.4204 c 9.7803 | band gap 2.21 eV; SHG=16×AgGaS2 | [30][29] | |||||
BaGa4Se7 | monoclinic | Pc | a = 7.625, b = 6.511, c = 14.702, β = 121.24° | transparent between 0.47 and 18.0 μm; melts 968 °C; SHG | [43][44] | |||||
Ba4Ga2Se8 | 132.48 | monoclinic | P21/c | a=13.2393 b=6.4305 c=20.6432 β =104.3148 Z=4 | 1702.90 | 5.151 | black air stable; band gap 1.51 eV | [45][46] | ||
Ba5Ga2Se8 | orthorhombic | Cmca | a 23.433 b 12.461 c 12.214 | band gap 2.51 eV | [47] | |||||
Ba5Ga4Se10 | 1755.18 | tetragonal | I4/mcm | a = 8.752, c = 13.971 Z = 2 | 1070.2 | 5.447 | red; bicyclic ring with Ga-Ga bridge; band gap 2.20 eV | [48] | ||
Ba3GaSe4Cl | orthorhombic | Pnma | a 12.691 b 9.870 c 8.716 | [49] | ||||||
Ba3GaSe4Br | orthorhombic | Pnma | a = 12.8248, b = 9.9608, c = 8.7690 Z = 4 | band gap 1.7 eV | [50] | |||||
LiBa4Ga5Se12 | 1852.42 | tetragonal | P421c | a 13.591 c 6.515 Z=2 | 1203.3 | 5.113 | yellow; band gap 2.44 eV; SHG 1.7×AgGaS2 | [30][51] | ||
NaBaGaSe3 | orthorhombic | Pnma | a 20.46 b 9.177 c 7.177 | 1347 | colourless | [52] | ||||
(Na0.60Ba0.70)Ga2Se4 | tetragonal | I4cm | a 7.9549 c 6.2836 | 397.6 | 4.725 | pale yellow | [53] | |||
KBa3Ga5Se10Cl2 | tetragonal | I4 | a 8.6341 c 15.644 | 1166.2 | band gap 2.04 eV; SHG=10×AgGaS2 | [30][54] | ||||
MnBa4Ga4Se10Cl2 | tetragonal | I4 | 8.5858 c 15.7739 | band gap 2.8 eV; SHG=30×AgGaS2 | [30][55] | |||||
FeBa4Ga4Se10Cl2 | tetragonal | I4 | a 8.578 c 15.717 | band gap 1.88 eV | [30][55] | |||||
CoBa4Ga4Se10Cl2 | tetragonal | I4 | a 8.572 c 15.716 | band gap 2.02 eV | [30][55] | |||||
Cu0.5Ba4Ga4.5Se10Cl2 | tetragonal | I4 | a 8.559 c 15.778 | band gap 2.6 eV; SHG=39×AgGaS2 | [30][55] | |||||
CuBa4Ga5Se12 | P421c | a = 13.598, c = 6.527, Z = 2 | band gap 1.45 eV; SHG=3×AgGaS2 | [30][56] | ||||||
ZnBa4Ga4Se10Cl2 | tetragonal | I4 | a 8.561 c 15.757 | band gap 3.08 eV; SHG=59×AgGaS2 | [30][55] | |||||
Ba10Zn7Ga6Se26 | tetragonal | I42m | a 11.2907 c 21.760 Z=2 | 2774.0 | 5.151 | yellow | [57] | |||
Ba4Ga4GeSe12 | 1848.35 | tetragonal | P421c | a=13.5468 c=6.4915 Z=2 | 1191.29 | 5.153 | orange yellow; band gap 2.18 eV | [45][58] | ||
BaGa2GeSe6 | R3 | [59] | ||||||||
RbBa3Ga5Se10Cl2 | tetragonal | I4 | a 8.6629 c 15.6379 | band gap 2.05 eV; SHG=20×AgGaS2 | [30][54] | |||||
Ba2GaYSe5 | triclinic | P1 | a 7.2876Å b 8.6597Å c 9.3876Å, α 103.51° β 103.04° γ 107.43° | [60] | ||||||
Ba4AgGaSe6 | 1199.44 | orthorhombic | Pnma | a=9.1006 b=4.472 c=17.7572 Z=2 | 722.71 | 5.512 | dark red; air stable; band gap 2.50 | [61] | ||
Ba4AgGa5Se12 | 1953.35 | tetragonal | P421c | a 13.6544 c 6.5215 Z=2 | 1215.9 | 5.335 | yellow | [51] | ||
Ba7AgGa5Se15 | trigonal | P31c | a 10.0467 c 18.689 | band gap 2.60 eV | [62] | |||||
CdBa4Ga4Se10Cl2 | tetragonal | I4 | a 8.611 c 15.805 | band gap 3.05 eV; SHG=52×AgGaS2 | [30][55] | |||||
Ba5CdGa6Se12 | 2401.82 | orthorhombic | Ama2 | a=24.2458 b=19.1582 c=6.6208 Z=4 | 3075.4 | 5.187 | yellow; air stable; band gap 2.60 eV; mp=866 °C | [45][63] | ||
BaGa2SnSe6 | 869.23 | trigonal | R3 | a = 10.145, c = 9.249 Z = 3 | 824.4 | 5.253 | red; SHG 5.2×AgGaS2 | [64] | ||
Ba4Ga4SnSe12 | 1894.45 | tetragonal | P421c | a 13.607 c 6.509 Z=2 | 1205.2 | 5.221 | red; band gap 2.16 eV | [65] | ||
Ba6Ga2SnSe11 | 1950.73 | monoclinic | P21/c | a 18.715 b 7.109 c 19.165, β 103.29° | 2481.5 | 5.221 | red; bad gap 1.99 eV | [65] | ||
Ba2AsGaSe5 | 814.12 | orthorhombic | Pnma | a = 12.632, b = 8.973, c = 9.203, Z = 4 | 1043.1 | 5.184 | black | [66] | ||
CsBa3Ga5Se10Cl2 | tetragonal | I4 | a 8.734 c 15.697 | 1197.6 | band gap 2.08 eV; SHG=100×AgGaS2 | [30][54] | ||||
NaLaGa4Se8 | orthorhombic | Fddd | a 21.1979 b 21.1625 c 12.7216 | [67] | ||||||
La3MnGaSe7 | 1094.11 | hexagonal | P63 | a 10.5894 c 6.3458 Z=2 | 616.25 | 5.896 | black | [68] | ||
La3FeGaSe7 | hexagonal | P63 | a=10.5042 c=6.3496 | 606.74 | [69] | |||||
La3CoGaSe7 | hexagonal | P63 | a=10.5104 c=6.3708 | 609.48 | [69] | |||||
La3NiGaSe7 | hexagonal | P63 | a=10.4826 c=6.3964 | 608.71 | [69] | |||||
La3CuGaSe7 | 1102.71 | hexagonal | P63 | a=10.626 c=6.392 Z=2 | 626.0 | 5.859 | [45] | |||
La3ZnGaSe7 | 1104.54 | hexagonal | P63 | a=10.630 c=6.374 Z=2 | 623.7 | 5.881 | [45] | |||
La3Ag0.6GaSe7 | hexagonal | P63 | a=10.6, c=6.4 Z=2 | [70] | ||||||
La3CdGaSe7 | hexagonal | P63 | a=10.606 c=6.380 Z=2 | 621.5 | 6.153 | [45] | ||||
Ba2GaLaSe5 | orthorhombic | Pnma | a 12.5049 b 9.6288 c 8.7355 | [71] | ||||||
NaCeGa4Se8 | orthorhombic | Fddd | a 21.141 b 21.138 c 12.712 | [67] | ||||||
Ce3CuGaSe7 | 1106.34 | hexagonal | P63 | a=10.6007 c=6.3775 Z=2 | 620.65 | 5.920 | [45] | |||
Ba2GaCeSe5 | orthorhombic | Fddd | a 12.494 b 9.599 c 8.738 | [71] | ||||||
Pr3CuGaSe7 | 1108.71 | hexagonal | P63 | a=10.4181 c=6.3743 Z=2 | 599.16 | 6.146 | [45] | |||
NaNdGa4Se8 | orthorhombic | Fddd | a 21.015 b 21.045 c 12.709 | [67] | ||||||
Nd3FeGaSe7 | hexagonal | P63 | a 10.2453 c 6.4076 Z=2 | 582.47 | [72] | |||||
Nd3CoGaSe7 | hexagonal | P63 | a=10.2296 c=6.4272 | 582.47 | [69] | |||||
Nd3NiGaSe7 | hexagonal | P63 | a=10.2117 c=6.4066 | 578.57 | [69] | |||||
Nd3CuGaSe7 | 1118.70 | hexagonal | P63 | a=10.3426 c=6.3869 Z=2 | 591.7 | 6.279 | [45] | |||
Ba2GaNdSe5 | triclinic | P1 | a 7.29Å b 8.7914Å c 9.47Å, α 103.77° β 102.91° γ 107.72° | [60] | ||||||
SmGa2Se4 | rhombic | a=21.34, b=21.60, c=12.74 | [73] | |||||||
Ba2GaSmSe5 | triclinic | P1 | a 7.3017Å b 8.7635Å c 9.4554Å, α 103.672° β 102.963° γ 107.637° | [60] | ||||||
Gd3FeGaSe7 | hexagonal | P63 | a 10.0762 c 6.4265 Z=2 | [72] | ||||||
Ba2GaGdSe5 | triclinic | P1 | a 7.2834Å b 8.7062Å c 9.4079Å, α 103.65° β 103.02° γ 107.52° | [60] | ||||||
Dy3FeGaSe7 | hexagonal | P63 | a 9.9956Å c 6.398 Z=2 | [72] | ||||||
Ba2GaDySe5 | triclinic | P1 | a 7.2772Å b 8.6543Å c 9.3792Å, α 103.53° β 103.07° γ 107.43° | [60] | ||||||
Ba2GaErErSe5 | triclinic | P1 | a 7.2721Å b 8.6258Å c 9.3621Å, α 103.41° β 103.13° γ 107.39° | [60] | ||||||
Ba2GaTbSe5 | triclinic | P1 | a 7.309 b 8.719 c 9.433, α 103.548° β 103.039° γ 107.520° | [71] | ||||||
Ba2GaHoSe5 | triclinic | P1 | a 7.2964 b 8.670 c 9.406, α 103.482° β 103.049° γ 107.423° | [71] | ||||||
Ba2GaTmSe5 | triclinic | P1 | a 7.2884 b 8.6376 c 9.3823, α 103.429° β 103.075° γ 107.360° | [71] | ||||||
Ba2GaYbSe5 | triclinic | P1 | a 7.2864 b 8.6257 c 9.3716, α 103.4154° β 103.0369° γ 107.3396° | [71] | ||||||
Ba2GaLuSe5 | triclinic | P1 | a 7.2829 b 8.6120 c 9.368, α 103.362° β 103.051° γ 107.308° | [71] | ||||||
HgGa2Se4 | [74] | |||||||||
KHg4Ga5Se12 | 2137.58 | trigonal | R3 | a 14.3203 b 14.3203 c 9.7057 Z=3 | 1723.7 | 6.178 | band gap 1.61 eV; SHG=20×AgGaS2 | [30][75][76] | ||
TlGaSe2 | 432.01 | monoclinic | C2/c | a=10.760 b=10.762 c=15.626 β=100.19 Z=16 | 1780.8 | 6.445 | black; layers of supertetrahedra; mp 804 °C; band gap 1.87 eV | [77] | ||
TlGaGeSe4 | 662.52 | orthorhombic | Pnma | a=17.4742 b=7.4105 c=11.9406 Z=8 | 1546.22 | 5.692 | [23] | |||
Tl2Ga2GeSe6 | tetragonal | I4/mmc | a=8.0770 c=6.2572 Z=4 | [78] | ||||||
Tl0.8Ga0.8Ge1.2Se4-mC112 | 622.22 | monoclinic | C2/c | a=13.5831 b=7.4015 c=30.7410 β =96.066 Z=16 | 3073.3 | 5.379 | red | [23] | ||
TlGaSnSe4-mP56 | 701.04 | monoclinic | P21/c | a=7.501 b=12.175 c=18.203 β =97.164 Z=8 | 1649.4 | 5.646 | red | [23] | ||
TlGaSnSe4-cP84 | 708.62 | cubic | Pa3 | a=13.4755 Z=12 | 2447.0 | 5.770 | red | [23] | ||
Tl2Ga2SnSe6 | tetragonal | I4/mmc | a=8.095 c=6.402 Z=4 | [78] | ||||||
TlGaSn2Se6 | R3 | a=10.3289 c=9.4340 | 871.64 | 5.6301 | dark grey in bulk; maroon powder | [79] | ||||
PbGa2Se4 | 662.47 | orthorhombic | Fddd | a =12.73 b=21.26 c=21.55 Z=32 | 5830 | 6.036 | yellow to red; mp 780 °C; band gap 1.83 eV | [80][81] | ||
Pb0.72Mn2.84Ga2.95Se8 | hexagonal | P6 | a 17.550 c 3.8916 | [82] | ||||||
PbGa2GeSe6 | orthorhombic | Fdd2 | mp 720 °C biaxial (−) | [59] | ||||||
Pb4Ga4GeSe12 | tetragonal | P421c | a = 13.064 c = 6.310 Z=2 | [83] | ||||||
Ba2GaBiSe5 | orthorhombic | Pnma | a=12.691 b=9.190 c=9.245 Z=4 | 1078.2 | 5.841 | yellow | [84] |
References
- ↑ 1.0 1.1 1.2 Friedrich, Daniel; Schlosser, Marc; Pfitzner, Arno (2017-11-17). "Synthesis and Structural Characterization of the layered Selenogallate RbGaSe 2: Synthesis and Structural Characterization of the layered Selenogallate RbGaSe 2" (in en). Zeitschrift für anorganische und allgemeine Chemie 643 (21): 1589–1592. doi:10.1002/zaac.201700288. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201700288.
- ↑ Friedrich, Daniel; Schlosser, Marc; Näther, Christian; Pfitzner, Arno (7 May 2018). "In Situ X-ray Diffraction Study of the Thermal Decomposition of Selenogallates Cs 2 [Ga 2 (Se 2 ) 2– x Se 2+ x ] ( x = 0, 1, 2)". Inorganic Chemistry 57 (9): 5292–5298. doi:10.1021/acs.inorgchem.8b00324. PMID 29667827.
- ↑ Luque, Antonio; Hegedus, Steven (2011-03-29) (in en). Handbook of Photovoltaic Science and Engineering. John Wiley & Sons. ISBN 978-0-470-97612-8. https://books.google.com/books?id=sLMkCsde1u4C.
- ↑ 4.0 4.1 Peng, Jing; Liu, Xinyao; Wang, Jie; Zhang, Shaoqing; Xiao, Xiao; Xiong, Zhengbin; Zhang, Kuibao; Chen, Baojun et al. (2023-07-31). "Crystal Growth, Characterization, and Properties of Nonlinear Optical Crystals of Li x Ag 1– x GaSe 2 for Mid-Infrared Applications" (in en). Inorganic Chemistry 62 (30): 12067–12078. doi:10.1021/acs.inorgchem.3c01582. ISSN 0020-1669. PMID 37475677. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c01582.
- ↑ 5.0 5.1 5.2 5.3 Zhou, Jian; Zhang, Yong; Bian, Guo-Qing; Li, Chun-Yin; Chen, Xiao-Xia; Dai, Jie (2008-07-02). "Structural Study of Organic−Inorganic Hybrid Thiogallates and Selenidogallates in View of Effects of the Chelate Amines" (in en). Crystal Growth & Design 8 (7): 2235–2240. doi:10.1021/cg700821n. ISSN 1528-7483. https://pubs.acs.org/doi/10.1021/cg700821n.
- ↑ 6.0 6.1 6.2 Zhou, Jian; Li, Chun-Ying; Zhang, Yong; Dai, Jie (2009-04-10). "Three 1-D selenidogallates [GaSe 2 − n , displaying conformational variations"] (in en). Journal of Coordination Chemistry 62 (7): 1112–1120. doi:10.1080/00958970802468617. ISSN 0095-8972. https://www.tandfonline.com/doi/full/10.1080/00958970802468617.
- ↑ 7.0 7.1 Xu, Chao; Zhang, Jing-Jing; Duan, Taike; Chen, Qun; Zhang, Qian-Feng (2011-09-01). "Solvothermal Syntheses and Crystal Structures of New One-dimensional Selenogallates [bappH 2 [Ga 2 Se 4 ] (bapp = 1,4-Bis-(3-aminopropyl)piperazine) and [Mn(en) 3 ][Ga 2 Se 5 ] (en = Ethylenediamine)"] (in en). Zeitschrift für Naturforschung B 66 (9): 877–881. doi:10.1515/znb-2011-0902. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-2011-0902/html.
- ↑ 8.0 8.1 8.2 8.3 8.4 Xiong, Wei-Wei; Li, Jian-Rong; Feng, Mei-Ling; Huang, Xiao-Ying (2011). "Solvothermal syntheses, crystal structures, and characterizations of a series of one-dimensional organic-containing gallium polyselenides" (in en). CrystEngComm 13 (20): 6206. doi:10.1039/c1ce05507k. ISSN 1466-8033. http://xlink.rsc.org/?DOI=c1ce05507k.
- ↑ Fehlker, Andreas; Blachnik, Roger; Reuter, Hans (1999). "[Ga(en)3[Ga3Se7(en)] · H2O: Ein Galliumchalkogenid mit Ketten aus [Ga3Se6Se2/2(en)]3–-Bicyclen"] (in de). Zeitschrift für anorganische und allgemeine Chemie 625 (7): 1225–1228. doi:10.1002/(SICI)1521-3749(199907)625:7<1225::AID-ZAAC1225>3.0.CO;2-H. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3749%28199907%29625%3A7%3C1225%3A%3AAID-ZAAC1225%3E3.0.CO%3B2-H.
- ↑ 10.0 10.1 Adhikary, Amit; Yaghoobnejad Asl, Hooman; Sandineni, Prashanth; Balijapelly, Srikanth; Mohapatra, Sudip; Khatua, Sajal; Konar, Sanjit; Gerasimchuk, Nikolay et al. (2020-07-14). "Unusual Atmospheric Water Trapping and Water Induced Reversible Restacking of 2D Gallium Sulfide Layers in NaGaS 2 Formed by Supertetrahedral Building Unit" (in en). Chemistry of Materials 32 (13): 5589–5603. doi:10.1021/acs.chemmater.0c00836. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.0c00836.
- ↑ Xu, Qian-Ting; Han, Shan-Shan; Li, Jia-Nuo; Guo, Sheng-Ping (2022-04-11). "NaGa 3 Se 5 : An Infrared Nonlinear Optical Material with Balanced Performance Contributed by Complex {[Ga 3 Se 5 − } ∞ Anionic Network"] (in en). Inorganic Chemistry 61 (14): 5479–5483. doi:10.1021/acs.inorgchem.2c00623. ISSN 0020-1669. PMID 35344370. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00623.
- ↑ Feng, Kai; Mei, Dajiang; Bai, Lei; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (August 2012). "Synthesis, structure, physical properties, and electronic structure of KGaSe2" (in en). Solid State Sciences 14 (8): 1152–1156. doi:10.1016/j.solidstatesciences.2012.05.028. Bibcode: 2012SSSci..14.1152F. https://linkinghub.elsevier.com/retrieve/pii/S1293255812001914.
- ↑ González, J.; Rico, R.; Calderón, E.; Quintero, M.; Morocoima, M. (1999). "Absorption Edge of MnGa2Se4 Single Crystals under Hydrostatic Pressure" (in en). Physica Status Solidi B 211 (1): 45–49. doi:10.1002/(SICI)1521-3951(199901)211:1<45::AID-PSSB45>3.0.CO;2-8. ISSN 1521-3951. Bibcode: 1999PSSBR.211...45G. https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3951%28199901%29211%3A1%3C45%3A%3AAID-PSSB45%3E3.0.CO%3B2-8.
- ↑ Abrahams, S. C.; Bernstein, J. L. (August 1974). "Piezoelectric nonlinear optic CuGaSe 2 and CdGeAs 2 : Crystal structure, chalcopyrite microhardness, and sublattice distortion" (in en). The Journal of Chemical Physics 61 (3): 1140–1146. doi:10.1063/1.1681987. ISSN 0021-9606. Bibcode: 1974JChPh..61.1140A. http://aip.scitation.org/doi/10.1063/1.1681987.
- ↑ 15.0 15.1 Errandonea, D.; Kumar, Ravhi S.; Manjón, F. J.; Ursaki, V. V.; Tiginyanu, I. M. (2008-09-15). "High-pressure x-ray diffraction study on the structure and phase transitions of the defect-stannite ZnGa2Se4 and defect-chalcopyrite CdGa2S4" (in en). Journal of Applied Physics 104 (6): 063524–063524–9. doi:10.1063/1.2981089. ISSN 0021-8979. Bibcode: 2008JAP...104f3524E. http://aip.scitation.org/doi/10.1063/1.2981089.
- ↑ Chen, Ruijiao; Wu, Xiaowen; Su, Zhi (2018). "Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)" (in en). Dalton Transactions 47 (43): 15538–15544. doi:10.1039/C8DT03281E. ISSN 1477-9226. PMID 30345442. http://xlink.rsc.org/?DOI=C8DT03281E.
- ↑ Abudurusuli, Ailijiang; Wu, Kui; Rouzhahong, Yilimiranmu; Yang, Zhihua; Pan, Shilie (2018). "Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances" (in en). Inorganic Chemistry Frontiers 5 (6): 1415–1422. doi:10.1039/C8QI00182K. ISSN 2052-1553. http://xlink.rsc.org/?DOI=C8QI00182K.
- ↑ 18.0 18.1 18.2 Chen, Man-Man; Zhou, Sheng-Hua; Wei, Wenbo; Wu, Xin-Tao; Lin, Hua; Zhu, Qi-Long (2021-06-17). "AZn 4 Ga 5 Se 12 (A = K, Rb, or Cs): Infrared Nonlinear Optical Materials with Simultaneous Large Second Harmonic Generation Responses and High Laser-Induced Damage Thresholds". Inorganic Chemistry 60 (13): 10038–10046. doi:10.1021/acs.inorgchem.1c01359. PMID 34134479.
- ↑ Yelisseyev, Alexander P.; Isaenko, Ludmila I.; Krinitsin, Pavel; Liang, Fei; Goloshumova, Alina A.; Naumov, Dmitry Yu.; Lin, Zheshuai (2016-09-06). "Crystal Growth, Structure, and Optical Properties of LiGaGe 2 Se 6" (in en). Inorganic Chemistry 55 (17): 8672–8680. doi:10.1021/acs.inorgchem.6b01225. ISSN 0020-1669. PMID 27529433. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01225.
- ↑ Mei, Dajiang; Yin, Wenlong; Feng, Kai; Lin, Zheshuai; Bai, Lei; Yao, Jiyong; Wu, Yicheng (2012-01-16). "LiGaGe 2 Se 6 : A New IR Nonlinear Optical Material with Low Melting Point" (in en). Inorganic Chemistry 51 (2): 1035–1040. doi:10.1021/ic202202j. ISSN 0020-1669. PMID 22221169. https://pubs.acs.org/doi/10.1021/ic202202j.
- ↑ Isaenko, L.I.; Yelisseyev, A.P.; Lobanov, S.I.; Krinitsin, P.G.; Molokeev, M.S. (September 2015). "Structure and optical properties of Li2Ga2GeS6 nonlinear crystal" (in en). Optical Materials 47: 413–419. doi:10.1016/j.optmat.2015.06.014. Bibcode: 2015OptMa..47..413I. https://linkinghub.elsevier.com/retrieve/pii/S0925346715003742.
- ↑ Li, Xiaoshuang; Li, Chao; Gong, Pifu; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2016). "Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 20" (in en). Dalton Transactions 45 (2): 532–538. doi:10.1039/C5DT03682H. ISSN 1477-9226. PMID 26599138. http://xlink.rsc.org/?DOI=C5DT03682H.
- ↑ 23.0 23.1 23.2 23.3 23.4 23.5 23.6 23.7 23.8 Friedrich, Daniel; Byun, Hye Ryung; Hao, Shiqiang; Patel, Shane; Wolverton, Chris; Jang, Joon Ik; Kanatzidis, Mercouri G. (2020-10-14). "Layered and Cubic Semiconductors A Ga M ′ Q 4 ( A + = K + , Rb + , Cs + , Tl + ; M ′ 4+ = Ge 4+ , Sn 4+ ; Q 2– = S 2– , Se 2– ) and High Third-Harmonic Generation" (in en). Journal of the American Chemical Society 142 (41): 17730–17742. doi:10.1021/jacs.0c08638. ISSN 0002-7863. PMID 32933252. https://pubs.acs.org/doi/10.1021/jacs.0c08638.
- ↑ 24.0 24.1 24.2 24.3 Larsen, Jes K.; Donzel-Gargand, Olivier; Sopiha, Kostiantyn V.; Keller, Jan; Lindgren, Kristina; Platzer-Björkman, Charlotte; Edoff, Marika (2021-02-22). "Investigation of AgGaSe 2 as a Wide Gap Solar Cell Absorber" (in en). ACS Applied Energy Materials 4 (2): 1805–1814. doi:10.1021/acsaem.0c02909. ISSN 2574-0962. https://pubs.acs.org/doi/10.1021/acsaem.0c02909.
- ↑ Li, Jia-Nuo; Yao, Wen-Dong; Li, Xiao-Hui; Liu, Wenlong; Xue, Huai-Guo; Guo, Sheng-Ping (2021). "A novel promising infrared nonlinear optical selenide KAg 3 Ga 8 Se 14 designed from benchmark AgGaQ 2 (Q = S, Se)" (in en). Chemical Communications 57 (9): 1109–1112. doi:10.1039/D0CC07396B. ISSN 1359-7345. PMID 33410852. http://xlink.rsc.org/?DOI=D0CC07396B.
- ↑ Ni, Youbao; Hu, Qianqian; Wu, Haixin; Han, Weimin; Yu, Xuezhou; Mao, Mingsheng (2021-06-10). "The Investigation on Mid-Far Infrared Nonlinear Crystal AgGaGe5Se12 (AGGSe)" (in en). Crystals 11 (6): 661. doi:10.3390/cryst11060661. ISSN 2073-4352.
- ↑ Kim, Chang-Dae; Cho, Tong-San; Kim, Jae-Kuen; Kim, Wha-Tek; Park, Hong-Lee (1987-12-15). "Spin-orbit coupling effects in CdGa 2 Se 4 : Co 2 + single crystals" (in en). Physical Review B 36 (17): 9283–9285. doi:10.1103/PhysRevB.36.9283. ISSN 0163-1829. PMID 9942799. Bibcode: 1987PhRvB..36.9283K. https://link.aps.org/doi/10.1103/PhysRevB.36.9283.
- ↑ 28.0 28.1 28.2 Grzechnik, A.; Ursaki, V.V.; Syassen, K.; Loa, I.; Tiginyanu, I.M.; Hanfland, M. (August 2001). "Pressure-Induced Phase Transitions in Cadmium Thiogallate CdGa2Se4" (in en). Journal of Solid State Chemistry 160 (1): 205–211. doi:10.1006/jssc.2001.9224. Bibcode: 2001JSSCh.160..205G. https://linkinghub.elsevier.com/retrieve/pii/S0022459601992242.
- ↑ 29.0 29.1 29.2 Lin, Hua; Chen, Ling; Zhou, Liu-Jiang; Wu, Li-Ming (2013-08-28). "Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AX II 4 X III 5 Se 12" (in en). Journal of the American Chemical Society 135 (34): 12914–12921. doi:10.1021/ja4074084. ISSN 0002-7863. PMID 23902474. https://pubs.acs.org/doi/10.1021/ja4074084.
- ↑ 30.00 30.01 30.02 30.03 30.04 30.05 30.06 30.07 30.08 30.09 30.10 30.11 30.12 30.13 Abudurusuli, Ailijiang; Li, Junjie; Tong, Tinghao; Yang, Zhihua; Pan, Shilie (2020-04-20). "LiBa 4 Ga 5 Q 12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold" (in en). Inorganic Chemistry 59 (8): 5674–5682. doi:10.1021/acs.inorgchem.0c00431. ISSN 0020-1669. PMID 32248682. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c00431.
- ↑ Deiseroth, H.-J.; Müller, D.; Hahn, H. (June 1985). "Strukturuntersuchungen an InGaSe2 und InGaTe2" (in de). Zeitschrift für anorganische und allgemeine Chemie 525 (6): 163–172. doi:10.1002/zaac.19855250619. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19855250619.
- ↑ Luo, Zhong-Zhen; Lin, Chen-Sheng; Cui, Hong-Hua; Zhang, Wei-Long; Zhang, Hao; He, Zhang-Zhen; Cheng, Wen-Dan (2014-04-22). "SHG Materials SnGa 4 Q 7 (Q = S, Se) Appearing with Large Conversion Efficiencies, High Damage Thresholds, and Wide Transparencies in the Mid-Infrared Region" (in en). Chemistry of Materials 26 (8): 2743–2749. doi:10.1021/cm5006955. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm5006955.
- ↑ Lin, Hua; Chen, Hong; Zheng, Yu-Jun; Yu, Ju-Song; Wu, Xin-Tao; Wu, Li-Ming (2017). "Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 6" (in en). Dalton Transactions 46 (24): 7714–7721. doi:10.1039/C7DT01384A. ISSN 1477-9226. PMID 28537606. http://xlink.rsc.org/?DOI=C7DT01384A.
- ↑ 34.0 34.1 Friedrich, Daniel; Schlosser, Marc; Pfitzner, Arno (2016-07-06). "Synthesis, Crystal Structure, and Physical Properties of Two Polymorphs of CsGaSe 2 , and High-Temperature X-ray Diffraction Study of the Phase Transition Kinetics" (in en). Crystal Growth & Design 16 (7): 3983–3992. doi:10.1021/acs.cgd.6b00532. ISSN 1528-7483. https://pubs.acs.org/doi/10.1021/acs.cgd.6b00532.
- ↑ Do, Junghwan; Kanatzidis, Mercouri G. (April 2003). "The One-dimensional Polyselenide Compound CsGaSe3" (in de). Zeitschrift für anorganische und allgemeine Chemie 629 (4): 621–624. doi:10.1002/zaac.200390105. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200390105.
- ↑ Friedrich, Daniel; Schlosser, Marc; Pfitzner, Arno (April 2014). "Synthesis and Structural Characterization of Cs 2 Ga 2 Se 5: Synthesis and Structural Characterization of Cs 2 Ga 2 Se 5" (in en). Zeitschrift für anorganische und allgemeine Chemie 640 (5): 826–829. doi:10.1002/zaac.201400046. https://epub.uni-regensburg.de/30538/1/155_Cs2Ga2Se5.pdf.
- ↑ Friedrich, Daniel; Greim, Dominik; Schlosser, Marc; Siegel, Renée; Senker, Jürgen; Pfitzner, Arno (2018-12-03). "Synthese und Charakterisierung von Cs 4 Ga 6 Q 11 ( Q =S, Se) – Chalkogenogallate mit außergewöhnlichen polymeren Anionen" (in en). Angewandte Chemie 130 (49): 16442–16447. doi:10.1002/ange.201805239. ISSN 0044-8249. Bibcode: 2018AngCh.13016442F. https://onlinelibrary.wiley.com/doi/10.1002/ange.201805239.
- ↑ Deiseroth, Hans-Jörg; Fu-Son, Han (1983-02-01). "Cs 6 Ga 2 Se 6 , ein ternäres Selenogallat(III) mit isolierten [Ga 2 Se 6 6- -Ionen/Cs 6 Ga 2 Se 6 , a Ternary Selenogallate(III) with Isolated [Ga 2 Se 6 ] 6- Ions"] (in en). Zeitschrift für Naturforschung B 38 (2): 181–182. doi:10.1515/znb-1983-0212. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-1983-0212/html.
- ↑ 39.0 39.1 Deiseroth, H. J. (1984-08-01). "Ungewöhnliche lineare, oligomere Anionen [Ga n Se 2n+2 (n + 4) - (n =2,4,6) in festen Selenogallaten des Cäsiums"] (in en). Zeitschrift für Kristallographie - Crystalline Materials 166 (1–4): 283–296. doi:10.1524/zkri.1984.166.14.283. ISSN 2196-7105. https://www.degruyter.com/document/doi/10.1524/zkri.1984.166.14.283/html.
- ↑ Lin, Hua; Chen, Hong; Lin, Zi-Xiong; Zhao, Hua-Jun; Liu, Peng-Fei; Yu, Ju-Song; Chen, Ling (February 2016). "(Cs 6 Cl) 6 Cs 3 [Ga 53 Se 96 : A Unique Long Period-Stacking Structure of Layers Made from Ga 2 Se 6 Dimers via Cis or Trans Intralayer Linking"] (in en). Inorganic Chemistry 55 (3): 1014–1016. doi:10.1021/acs.inorgchem.5b02846. ISSN 0020-1669. PMID 26792549. https://pubs.acs.org/doi/10.1021/acs.inorgchem.5b02846.
- ↑ Ma, Ni; Xiong, Lin; Chen, Ling; Wu, Li-Ming (December 2019). "Vibration uncoupling of germanium with different valence states lowers thermal conductivity of Cs2Ge3Ga6Se14" (in en). Science China Materials 62 (12): 1788–1797. doi:10.1007/s40843-019-1192-y. ISSN 2095-8226. http://link.springer.com/10.1007/s40843-019-1192-y.
- ↑ Mei, Dajiang; Yin, Wenlong; Feng, Kai; Bai, Lei; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (February 2012). "Synthesis, structure, and electronic structure of CsAgGa2Se4" (in en). Journal of Solid State Chemistry 186: 54–57. doi:10.1016/j.jssc.2011.11.014. Bibcode: 2012JSSCh.186...54M. https://linkinghub.elsevier.com/retrieve/pii/S0022459611006177.
- ↑ Zhai, Naixia; Li, Chao; Xu, Bo; Bai, Lei; Yao, Jiyong; Zhang, Guochun; Hu, Zhanggui; Wu, Yicheng (2017-02-23). "Temperature-Dependent Sellmeier Equations of IR Nonlinear Optical Crystal BaGa4Se7" (in en). Crystals 7 (3): 62. doi:10.3390/cryst7030062. ISSN 2073-4352.
- ↑ Yao, Jiyong; Mei, Dajiang; Bai, Lei; Lin, Zheshuai; Yin, Wenlong; Fu, Peizhen; Wu, Yicheng (2010-10-18). "BaGa 4 Se 7 : A New Congruent-Melting IR Nonlinear Optical Material" (in en). Inorganic Chemistry 49 (20): 9212–9216. doi:10.1021/ic1006742. ISSN 0020-1669. PMID 20863100. https://pubs.acs.org/doi/10.1021/ic1006742.
- ↑ 45.0 45.1 45.2 45.3 45.4 45.5 45.6 45.7 45.8 Iyer, Abishek K (2018). Structural diversity and optical properties of ternary and quaternary chalcogenides. doi:10.7939/R33N20W55. https://era.library.ualberta.ca/items/048fea6e-a512-435c-8d42-f5630e2b6f43.
- ↑ Yin, Wenlong; Iyer, Abishek K.; Lin, Xinsong; Mar, Arthur (May 2016). "Ba4Ga2Se8: A ternary selenide containing chains and discrete S e 2 2 − units" (in en). Journal of Solid State Chemistry 237: 144–149. doi:10.1016/j.jssc.2016.02.014. Bibcode: 2016JSSCh.237..144Y. https://linkinghub.elsevier.com/retrieve/pii/S002245961630038X.
- ↑ Mei, Dajiang; Yin, Wenlong; Lin, Zheshuai; He, Ran; Yao, Jiyong; Fu, Peizhen; Wu, Yicheng (February 2011). "Syntheses and characterization of two new selenides Ba5Al2Se8 and Ba5Ga2Se8" (in en). Journal of Alloys and Compounds 509 (6): 2981–2985. doi:10.1016/j.jallcom.2010.11.178. https://linkinghub.elsevier.com/retrieve/pii/S0925838810029415.
- ↑ Yin, Wenlong; Mei, Dajiang; Feng, Kai; Yao, Jiyong; Fu, Peizhen; Wu, Yicheng (2011). "Ba5Ga4Se10: a new selenidogallate containing the novel [Ga4Se1010− anionic cluster with Ga in a mixed-valence state"] (in en). Dalton Transactions 40 (36): 9159–9162. doi:10.1039/c1dt10748h. ISSN 1477-9226. PMID 21822514. http://xlink.rsc.org/?DOI=c1dt10748h.
- ↑ Feng, Kai; Yin, Wenlong; Lin, Zuohong; Yao, Jiyong; Wu, Yicheng (2013-10-07). "Five New Chalcohalides, Ba 3 GaS 4 X (X = Cl, Br), Ba 3 MSe 4 Cl (M = Ga, In), and Ba 7 In 2 Se 6 F 8 : Syntheses, Crystal Structures, and Optical Properties" (in en). Inorganic Chemistry 52 (19): 11503–11508. doi:10.1021/ic401820a. ISSN 0020-1669. PMID 24024885. https://pubs.acs.org/doi/abs/10.1021/ic401820a.
- ↑ Yin, Wenlong; Iyer, Abishek K.; Xing, Wenhao; Kang, Bin; Mar, Arthur (April 2020). "Quaternary chalcogenide halides Ba3GaSe4Br and Ba3InSe4Br" (in en). Journal of Solid State Chemistry 284: 121189. doi:10.1016/j.jssc.2020.121189. Bibcode: 2020JSSCh.28421189Y. https://linkinghub.elsevier.com/retrieve/pii/S0022459620300190.
- ↑ 51.0 51.1 Yin, Wenlong; Feng, Kai; Mei, Dajiang; Yao, Jiyong; Fu, Peizhen; Wu, Yicheng (2012). "Ba2AgInS4 and Ba4MGa5Se12 (M = Ag, Li): syntheses, structures, and optical properties" (in en). Dalton Transactions 41 (8): 2272–2276. doi:10.1039/c2dt11895e. ISSN 1477-9226. PMID 22214992. http://xlink.rsc.org/?DOI=c2dt11895e.
- ↑ Abudurusuli, Ailijiang; Wu, Kui; Rouzhahong, Yilimiranmu; Yang, Zhihua; Pan, Shilie (2018). "NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers" (in en). Dalton Transactions 47 (45): 16044–16047. doi:10.1039/C8DT04048F. ISSN 1477-9226. PMID 30393800. http://xlink.rsc.org/?DOI=C8DT04048F.
- ↑ Li, Ya-Nan; Xue, Huaiguo; Guo, Sheng-Ping (2020-03-16). "(Na 0.60 Ba 0.70 )Ga 2 Se 4 : An Infrared Nonlinear Optical Crystal Designed using AgGaSe 2 as the Template" (in en). Inorganic Chemistry 59 (6): 3546–3550. doi:10.1021/acs.inorgchem.0c00196. ISSN 0020-1669. PMID 32125150. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c00196.
- ↑ 54.0 54.1 54.2 Yu, Peng; Zhou, Liu-Jiang; Chen, Ling (February 2012). "Noncentrosymmetric Inorganic Open-Framework Chalcohalides with Strong Middle IR SHG and Red Emission: Ba 3 AGa 5 Se 10 Cl 2 (A = Cs, Rb, K)" (in en). Journal of the American Chemical Society 134 (4): 2227–2235. doi:10.1021/ja209711x. ISSN 0002-7863. PMID 22239154. https://pubs.acs.org/doi/10.1021/ja209711x.
- ↑ 55.0 55.1 55.2 55.3 55.4 55.5 Li, Yan-Yan; Liu, Peng-Fei; Hu, Lei; Chen, Ling; Lin, Hua; Zhou, Liu-Jiang; Wu, Li-Ming (July 2015). "Strong IR NLO Material Ba 4 MGa 4 Se 10 Cl 2 : Highly Improved Laser Damage Threshold via Dual Ion Substitution Synergy" (in en). Advanced Optical Materials 3 (7): 957–966. doi:10.1002/adom.201500038. https://onlinelibrary.wiley.com/doi/10.1002/adom.201500038.
- ↑ Kuo, Shu-Ming; Chang, Yu-Ming; Chung, In; Jang, Joon-Ik; Her, Bo-Hsian; Yang, Siao-Han; Ketterson, John B.; Kanatzidis, Mercouri G. et al. (2013-06-25). "New Metal Chalcogenides Ba 4 CuGa 5 Q 12 (Q = S, Se) Displaying Strong Infrared Nonlinear Optical Response" (in en). Chemistry of Materials 25 (12): 2427–2433. doi:10.1021/cm400311v. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm400311v.
- ↑ Li, Yan-Yan; Wang, Hui; Sun, Bo-Wen; Ruan, Qin-Qin; Geng, Yan-Ling; Liu, Peng-Fei; Wang, Lei; Wu, Li-Ming (2019-02-06). "Ba 10 Zn 7 M 6 Q 26 : Two New Mid-infrared Nonlinear Optical Crystals with T2 Supertetrahedron 3D Framework" (in en). Crystal Growth & Design 19 (2): 1190–1197. doi:10.1021/acs.cgd.8b01644. ISSN 1528-7483. https://pubs.acs.org/doi/10.1021/acs.cgd.8b01644.
- ↑ Yin, Wenlong; Iyer, Abishek K.; Li, Chao; Lin, Xinsong; Yao, Jiyong; Mar, Arthur (September 2016). "Noncentrosymmetric selenide Ba4Ga4GeSe12: Synthesis, structure, and optical properties" (in en). Journal of Solid State Chemistry 241: 131–136. doi:10.1016/j.jssc.2016.06.004. Bibcode: 2016JSSCh.241..131Y. https://linkinghub.elsevier.com/retrieve/pii/S0022459616302316.
- ↑ 59.0 59.1 Badikov, Valeriy V.; Badikov, Dmitrii V.; Wang, Li; Shevyrdyaeva, Galina S.; Panyutin, Vladimir L.; Fintisova, Anna A.; Sheina, Svetlana G.; Petrov, Valentin (2019-08-07). "Crystal Growth and Characterization of a New Quaternary Chalcogenide Nonlinear Crystal for the Mid-Infrared: PbGa 2 GeSe 6" (in en). Crystal Growth & Design 19 (8): 4224–4228. doi:10.1021/acs.cgd.9b00118. ISSN 1528-7483. https://pubs.acs.org/doi/10.1021/acs.cgd.9b00118.
- ↑ 60.0 60.1 60.2 60.3 60.4 60.5 Yin, Wenlong; Feng, Kai; Wang, Wendong; Shi, Youguo; Hao, Wenyu; Yao, Jiyong; Wu, Yicheng (2012-06-18). "Syntheses, Structures, Optical and Magnetic Properties of Ba 2 M Ln Se 5 (M = Ga, In; Ln = Y, Nd, Sm, Gd, Dy, Er)" (in en). Inorganic Chemistry 51 (12): 6860–6867. doi:10.1021/ic300604a. ISSN 0020-1669. PMID 22671989. https://pubs.acs.org/doi/10.1021/ic300604a.
- ↑ Lei, Xiao-Wu; Yang, Min; Xia, Sheng-Qing; Liu, Xiao-Cun; Pan, Ming-Yan; Li, Xin; Tao, Xu-Tang (April 2014). "Synthesis, Structure and Bonding, Optical Properties of Ba 4 MTrQ 6 (M=Cu, Ag; Tr=Ga, In; Q=S, Se)" (in en). Chemistry: An Asian Journal 9 (4): 1123–1131. doi:10.1002/asia.201301495. PMID 24519897. https://onlinelibrary.wiley.com/doi/10.1002/asia.201301495.
- ↑ Yin, Wenlong; He, Ran; Feng, Kai; Hao, Wenyu; Yao, Jiyong; Wu, Yicheng (July 2013). "Synthesis, structure, optical property, and electronic structure of Ba7AgGa5Se15" (in en). Journal of Alloys and Compounds 565: 115–119. doi:10.1016/j.jallcom.2013.02.180. https://linkinghub.elsevier.com/retrieve/pii/S0925838813005227.
- ↑ Yin, Wenlong; Iyer, Abishek K.; Li, Chao; Yao, Jiyong; Mar, Arthur (2017). "Ba 5 CdGa 6 Se 15 , a congruently-melting infrared nonlinear optical material with strong SHG response" (in en). Journal of Materials Chemistry C 5 (5): 1057–1063. doi:10.1039/C6TC05111A. ISSN 2050-7526. http://xlink.rsc.org/?DOI=C6TC05111A.
- ↑ Li, Xiaoshuang; Li, Chao; Gong, Pifu; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2015). "BaGa 2 SnSe 6 : a new phase-matchable IR nonlinear optical material with strong second harmonic generation response" (in en). Journal of Materials Chemistry C 3 (42): 10998–11004. doi:10.1039/C5TC02337H. ISSN 2050-7526. http://xlink.rsc.org/?DOI=C5TC02337H.
- ↑ 65.0 65.1 Yin, Wenlong; Lin, Zuohong; Kang, Lei; Kang, Bin; Deng, Jianguo; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2015). "Syntheses, structures, and optical properties of Ba 4 Ga 4 SnSe 12 and Ba 6 Ga 2 SnSe 11" (in en). Dalton Transactions 44 (5): 2259–2266. doi:10.1039/C4DT02244K. ISSN 1477-9226. PMID 25523931. http://xlink.rsc.org/?DOI=C4DT02244K.
- ↑ Li, Chao; Li, Xiaoshuang; Huang, Hongwei; Yao, Jiyong; Wu, Yicheng (2015-10-19). "Ba 2 AsGaSe 5 : A New Quaternary Selenide with the Novel [AsGaSe 5 4– Cluster and Interesting Photocatalytic Properties"] (in en). Inorganic Chemistry 54 (20): 9785–9789. doi:10.1021/acs.inorgchem.5b01501. ISSN 0020-1669. PMID 26418301. https://pubs.acs.org/doi/10.1021/acs.inorgchem.5b01501.
- ↑ 67.0 67.1 67.2 Choudhury, Amitava; Dorhout, Peter K. (2008-05-01). "Synthesis, Structure, and Optical Properties of the Quaternary Seleno-gallates Na Ln Ga 4 Se 8 ( Ln = La, Ce, Nd) and Their Comparison with the Isostructural Thio-gallates" (in en). Inorganic Chemistry 47 (9): 3603–3609. doi:10.1021/ic701986j. ISSN 0020-1669. PMID 18345598. https://pubs.acs.org/doi/10.1021/ic701986j.
- ↑ He, Jianqiao; Wang, Zhe; Zhang, Xian; Cheng, Ye; Gong, Yu; Lai, Xiaofang; Zheng, Chong; Lin, Jianhua et al. (2015). "Synthesis, structure, magnetic and photoelectric properties of Ln 3 M 0.5 M′Se 7 (Ln = La, Ce, Sm; M = Fe, Mn; M′ = Si, Ge) and La 3 MnGaSe 7" (in en). RSC Advances 5 (65): 52629–52635. doi:10.1039/C5RA05629B. ISSN 2046-2069. Bibcode: 2015RSCAd...552629H. http://xlink.rsc.org/?DOI=C5RA05629B.
- ↑ 69.0 69.1 69.2 69.3 69.4 Rudyk, Brent W.; Stoyko, Stanislav S.; Oliynyk, Anton O.; Mar, Arthur (February 2014). "Rare-earth transition-metal gallium chalcogenides RE3MGaCh7 (M=Fe, Co, Ni; Ch=S, Se)" (in en). Journal of Solid State Chemistry 210 (1): 79–88. doi:10.1016/j.jssc.2013.11.003. Bibcode: 2014JSSCh.210...79R. https://linkinghub.elsevier.com/retrieve/pii/S0022459613005409.
- ↑ Iyer, Abishek K.; Yin, Wenlong; Rudyk, Brent W.; Lin, Xinsong; Nilges, Tom; Mar, Arthur (November 2016). "Metal ion displacements in noncentrosymmetric chalcogenides La3Ga1.67S7, La3Ag0.6GaCh7 (Ch=S, Se), and La3MGaSe7 (M=Zn, Cd)" (in en). Journal of Solid State Chemistry 243: 221–231. doi:10.1016/j.jssc.2016.08.031. Bibcode: 2016JSSCh.243..221I. https://linkinghub.elsevier.com/retrieve/pii/S0022459616303383.
- ↑ 71.0 71.1 71.2 71.3 71.4 71.5 71.6 Yin, Wenlong; Zhang, Dong; Zhou, Molin; Iyer, Abishek K.; Pöhls, Jan-Hendrik; Yao, Jiyong; Mar, Arthur (September 2018). "Quaternary rare-earth selenides Ba2REGaSe5 and Ba2REInSe5" (in en). Journal of Solid State Chemistry 265: 167–175. doi:10.1016/j.jssc.2018.05.041. Bibcode: 2018JSSCh.265..167Y. https://linkinghub.elsevier.com/retrieve/pii/S0022459618302391.
- ↑ 72.0 72.1 72.2 Yin, Wenlong; Wang, Wendong; Kang, Lei; Lin, Zheshuai; Feng, Kai; Shi, Youguo; Hao, Wenyu; Yao, Jiyong et al. (June 2013). "Ln3FeGaQ7: A new series of transition-metal rare-earth chalcogenides" (in en). Journal of Solid State Chemistry 202: 269–275. doi:10.1016/j.jssc.2013.03.029. Bibcode: 2013JSSCh.202..269Y. https://linkinghub.elsevier.com/retrieve/pii/S0022459613001448.
- ↑ Alieva, O. A.; Aliev, O. M.; Rustamov, P. G. (1987). "SmSe-Ga2Se3 system" (in Russian). Zhurnal Neorganicheskoj Khimii 32 (1): 252–254. ISSN 0044-457X. http://inis.iaea.org/Search/search.aspx?orig_q=RN:18088683.
- ↑ Gomis, O.; Vilaplana, R.; Manjón, F. J.; Santamaría-Pérez, D.; Errandonea, D.; Pérez-González, E.; López-Solano, J.; Rodríguez-Hernández, P. et al. (2013-02-21). "High-pressure study of the structural and elastic properties of defect-chalcopyrite HgGa 2 Se 4" (in en). Journal of Applied Physics 113 (7): 073510–073510–10. doi:10.1063/1.4792495. ISSN 0021-8979. Bibcode: 2013JAP...113g3510G. http://aip.scitation.org/doi/10.1063/1.4792495.
- ↑ Zhou, Molin; Yang, Yi; Guo, Yangwu; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng; Chen, Chuangtian (2017-09-26). "Hg-Based Infrared Nonlinear Optical Material KHg 4 Ga 5 Se 12 Exhibits Good Phase-Matchability and Exceptional Second Harmonic Generation Response" (in en). Chemistry of Materials 29 (18): 7993–8002. doi:10.1021/acs.chemmater.7b03143. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.7b03143.
- ↑ Johnsen, Simon; Liu, Zhifu; Peters, John A.; Song, Jung-Hwan; Peter, Sebastian C.; Malliakas, Christos D.; Cho, Nam Ki; Jin, Hosub et al. (2011-06-28). "Thallium Chalcogenide-Based Wide-Band-Gap Semiconductors: TlGaSe 2 for Radiation Detectors" (in en). Chemistry of Materials 23 (12): 3120–3128. doi:10.1021/cm200946y. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm200946y.
- ↑ Makhnovets, G.; Myronchuk, G.; Piskach, L.; Parasyuk, O.; Kityk, I.V.; Piasecki, M. (November 2018). "Phase diagram and specific band gap features of novel TlGaSe2: Zn+2(Cd+2, Hg+2) crystals" (in en). Journal of Alloys and Compounds 768: 667–675. doi:10.1016/j.jallcom.2018.07.282. https://linkinghub.elsevier.com/retrieve/pii/S092583881832783X.
- ↑ 78.0 78.1 Babizhetskyy, Volodymyr; Levytskyy, Volodymyr; Smetana, Volodymyr; Wilk-Kozubek, Magdalena; Tsisar, Oksana; Piskach, Lyudmyla; Parasyuk, Oleg; Mudring, Anja-Verena (2020-02-25). "New cation-disordered quaternary selenides Tl 2 Ga 2 Tt Se 6 ( Tt =Ge, Sn)" (in en). Zeitschrift für Naturforschung B 75 (1–2): 135–142. doi:10.1515/znb-2019-0169. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-2019-0169/html.
- ↑ Parasyuk, Oleh; Babizhetskyy, Volodymyr; Khyzhun, Oleg; Levytskyy, Volodymyr; Kityk, Iwan; Myronchuk, Galyna; Tsisar, Oksana; Piskach, Lyudmyla et al. (2017-11-07). "Novel Quaternary TlGaSn2Se6 Single Crystal as Promising Material for Laser Operated Infrared Nonlinear Optical Modulators" (in en). Crystals 7 (11): 341. doi:10.3390/cryst7110341. ISSN 2073-4352.
- ↑ Bletskan, D. I.; Frolov, V. V.; Kabatsii, V. M.; Kranichets, M.; Gule, E. G. (2006). "Photoconductivity and photoluminescence of PbGa2Se4crystals" (in en). Chalcogenide Letters 3 (12). ISSN 1584-8663. https://chalcogen.ro/Bletskan-articol.pdf.
- ↑ Wu, Kui; Pan, Shilie; Wu, Hongping; Yang, Zhihua (February 2015). "Synthesis, structures, optical properties and electronic structures of PbGa2Q4 (Q=S, Se) crystals" (in en). Journal of Molecular Structure 1082: 174–179. doi:10.1016/j.molstruc.2014.11.019. Bibcode: 2015JMoSt1082..174W. https://linkinghub.elsevier.com/retrieve/pii/S0022286014011259.
- ↑ Zhou, Molin; Jiang, Xingxing; Guo, Yangwu; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2017-07-17). "Pb 0.65 Mn 2.85 Ga 3 S 8 and Pb 0.72 Mn 2.84 Ga 2.95 Se 8 : Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties" (in en). Inorganic Chemistry 56 (14): 8454–8461. doi:10.1021/acs.inorgchem.7b01157. ISSN 0020-1669. PMID 28644026. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01157.
- ↑ Chen, Yu-Kun; Chen, Mei-Chun; Zhou, Liu-Jiang; Chen, Ling; Wu, Li-Ming (2013-08-05). "Syntheses, Structures, and Nonlinear Optical Properties of Quaternary Chalcogenides: Pb 4 Ga 4 GeQ 12 (Q = S, Se)" (in en). Inorganic Chemistry 52 (15): 8334–8341. doi:10.1021/ic400995z. ISSN 0020-1669. PMID 23848994. https://pubs.acs.org/doi/10.1021/ic400995z.
- ↑ Wu, Xiaowen; Gu, Xiaofeng; Pan, Hui; Hu, Yi; Wu, Kui (2018-04-13). "Synthesis, Crystal Structures, Optical Properties and Theoretical Calculations of Two Metal Chalcogenides Ba2AlSbS5 and Ba2GaBiSe5" (in en). Crystals 8 (4): 165. doi:10.3390/cryst8040165. ISSN 2073-4352.
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