Chemistry:Jadarite

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Jadarite
Natural History Center Svilajnac 16.JPG
Jadarite on display at the Natural History Center in Svilajnac, Serbia
General
CategoryNesosilicate
Formula
(repeating unit)		LiNaSiB3O7OH
Strunz classification9.AJ.40
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/n
Unit cella = 6.816(2), b = 13.789(2)
c = 6.758(2) [Å]; β = 111.08(2)°; Z = 4
Identification
Formula mass219.46 g/mol
ColorWhite
Crystal habitAs microscopic anhedral grains
FractureIrregular to conchoidal
TenacityBrittle
Mohs scale hardness4 - 5
|re|er}}Dull
StreakWhite
DiaphaneityTranslucent to opaque
Specific gravity2.45
Optical propertiesBiaxial
Ultraviolet fluorescenceWeak pink to orange under UV
References[1][2]

Jadarite is a white, earthy monoclinic silicate mineral,[1] sodium lithium boron silicate hydroxide[4] (LiNaSiB3O7(OH) or Na2OLi2O(SiO2)2(B2O3)3H2O).

Discovery and classification

Jadarite was discovered in December 2004, in drill core from the Jadar Valley (Serbian: Јадар, Jadar, IPA: [jadaɾ]) in Serbia, from which it is named. The find was located 10 km (6.2 mi) southwest of the Cer mountain.[5] Findings were originally located in the villages of Jarebice and Slatina[6] and later in Draginac.[7]

Exploration geologists from Rio Tinto Exploration discovered the mineral as small rounded nodules in drill core, and were unable to match it with previously known minerals. Jadarite was confirmed as a new mineral after scientists at the Natural History Museum in London and the National Research Council of Canada conducted tests on it.[8][4]

Commercialization

The mineral discovery may be commercially important because the mineral contains lithium and boron, both relatively rare industrially important elements. Lithium is used for lithium batteries; boron is used in alloys, ceramic, glasses, and other applications.[6]

It was originally estimated that there are 200 million tons of the lithium borate ore, which would make the future Jadar mines one of the world's largest lithium deposits, supplying 10% of the world's demand for lithium.[9] Later on, United States Geological Survey concluded that lithium supply is closer to 1.51% of world's demand for lithium.[10][11] Of that, the Lower Jadar ore deposit has 114.5 million tons with an average content of the profitable components of 1.8% of lithium oxide and 13.1% of boron oxide.

In May 2017, Rio Tinto announced that the Jadar area has one of the largest lithium deposits in the world, lifting Lower Jadar's deposits to 136 million tons. The company stated that the ore deposit's mineral resource estimation confirmed the quality of the mineral. Extraction is scheduled to begin in 2023, with a projected underground exploitability of 50 years.

A jadarite processing plant next to the mines, which will process the ore into lithium carbonate and boric acid, is also planned. The prototype facility has been constructed by the scientists from Serbia, Australia, and USA, and is being tested in Melbourne. Testing includes the processing of the jadarite concentrate.[12]

On 25 July 2017 a memorandum was signed by Rio Tinto and the Government of Serbia, represented by the prime minister Ana Brnabić, which confirmed the year 2023 as the starting year, but also revealed that only now the working groups will be formed, studies will be conducted, and the process of issuing the permits will begin. The entire enterprise was named "Project Jadar".[13]

By 2020, future exploitation of the jadarite and extraction of lithium instigated heated public and academic debate, especially after the Rio Tinto's destruction of the Juukan Gorge in Australia . Environmentalists, local population and some scientists and professors are against it, citing usage of large quantities of water and various acids and other chemicals in the production process, which will contaminate 2,000 ha (4,900 acres) of fertile, arable land, salinize the underground waters and pollute the rivers of Jadar and Drina. Other experts claim that there is no reason not to trust company's claim it will follow the highest anti-pollution measures, that waters are safe and that land is not that fertile after all. The company itself stated it will employ the new, experimental process which prevents pollution and which was tested 2,000 times in Australia.[14][15][16][17]

(As of November 2021), construction of a mine has not begun.[18] Amidst the growing opposition, Rio Tinto's Serbian branch "Rio Sava Exploration" announced that construction of the mine will begin in 2022, to be finished in 2026. The company claimed it already invested $250 million in the project, with additional $200 million planned for 2021.[19] However, on 20 January 2022 Serbian prime minister Ana Brnabić announced the cancellation of the project, after mass protests organised by ecological organisations in Serbia.[20]

Kryptonite

Jadarite's chemical formula is similar but not identical to the formula ("sodium lithium boron silicate hydroxide with fluorine") invented for the fictional substance kryptonite in the 2006 film Superman Returns. This coincidence attracted mass-media attention in 2007, shortly after jadarite's discovery.[21][22][23][24]

The new mineral, unlike the fictional material in the movie, does not contain fluorine and does not have a green glow.[21]

References

  1. ↑ 1.0 1.1 "Jadarite". mindat.org. 2007. http://mindat.org/min-31570.html. 
  2. ↑ Webmineral data
  3. ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W. 
  4. ↑ 4.0 4.1 'Kryptonite' discovered in mine. BBC News
  5. ↑ Tanjug (25 May 2009), "Jadarski kriptonit nije na prodaju" (in sr), Politika 
  6. ↑ 6.0 6.1 S.Trifunović (18 June 2009). "Jadarit još čeka" (in sr). Politika. http://www.politika.rs/sr/clanak/91878/Ekonomija/Jadarit-jos-ceka. 
  7. ↑ Aleksandar Apostolovski (17 April 2010). "Supermen oboren u Jadru" (in sr). Politika. http://www.politika.rs/sr/clanak/131568/Drustvo/Supermen-oboren-u-Jadru. 
  8. ↑ Whitfield, Pamela. LiNaSiB3O7(OH) a novel structure of the new borosilicate mineral jadarite determined from laboratory powder diffraction data Acta Crystallographica Section B Structural Science, International Union of Crystallography, DOI 10.1107/S0108768107010130, ISSN 0567-7408. (abstract).
  9. ↑ S.P. (22 November 2016). ""Rio Tinto" otvorila info centar: Sve informacije o najčuvenijem projektu "Jadar"" (in sr). Blic. http://www.blic.rs/vesti/srbija/rio-tinto-otvorila-info-centar-sve-informacije-o-najcuvenijem-projektu-jasdar/mj49bf9. 
  10. ↑ Slađana Vukašinović (14 June 2021). "SRBIJA NEMA 10 ODSTO SVETSKIH ZALIHA LITIJUMA VEĆ 1,51 ODSTO" (in sr). Blic. https://www.blic.rs/biznis/privreda-i-finansije/srbija-nema-10-odsto-svetskih-zaliha-litijuma-vec-151-odsto-sta-pokazuje-novo/ke1r9ge. 
  11. ↑ USGS (January 2021). "U.S. Geological Survey, Mineral Commodity Summaries" (in en). USGS. https://pubs.usgs.gov/periodicals/mcs2021/mcs2021-lithium.pdf. 
  12. ↑ Aleksandar Mikavica (20 May 2017), "Jadarit - novo srpsko zlato" (in sr), Politika: 13, http://www.politika.rs/sr/clanak/381036/Jadarit-novo-srpsko-zlato 
  13. ↑ "Proizvodnja litijuma od 2023." (in sr), Politika: 10, 25 July 2017 
  14. ↑ Gordana Grujić (20 December 2020). (in sr)Politika: p. 12. 
  15. ↑ Vesna Prodanović (20 December 2020). (in sr)Politika: pp. 12–13. 
  16. ↑ Dragana Đorđević (20 December 2020). (in sr)Politika: p. 13. 
  17. ↑ Balkan Green Energy News (6 November 2020). "Voices of discontent over Rio Tinto's jadarite mine investment in Serbia grow louder". Balkan Green Energy News. https://balkangreenenergynews.com/voices-of-discontent-over-rio-tintos-jadarite-mine-investment-in-serbia-grow-louder/. 
  18. ↑ "Rio Tinto's past casts a shadow over Serbia's hopes of a lithium revolution" (in en). the Guardian. 19 November 2021. https://www.theguardian.com/global-development/2021/nov/19/rio-tintos-past-casts-a-shadow-over-serbias-hopes-of-a-lithium-revolution. 
  19. ↑ "Изградња рудника за вађење јадарита почиње 2022. године" (in sr). Politika: p. 10. 4 March 2021. 
  20. ↑ "Serbia scraps plans for Rio Tinto lithium mine after protests". 21 January 2022. https://www.theguardian.com/world/2022/jan/20/serbia-scraps-plans-for-rio-tinto-lithium-mine-after-protests. 
  21. ↑ 21.0 21.1 "'Kryptonite' discovered in mine", BBC News, 24 Apr 2007, http://news.bbc.co.uk/1/hi/6584229.stm 
  22. ↑ ABC
  23. ↑ CNN
  24. ↑ Washington Post



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