Chemistry:Spodumene

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Short description: Pyroxene, single chain inosilicate mineral
Spodumene
Spodumene-usa59abg.jpg
Walnut Hill Pegmatite Prospect, Huntington, Hampshire County, Massachusetts, U.S. (size: 14.2 x 9.2 x 3.0 cm)
General
CategoryInosilicate
Formula
(repeating unit)
lithium aluminium silicate, LiAl(SiO3)2
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupC2/c
Unit cella = 9.46 Å, b = 8.39 Å
c = 5.22 Å
β = 110.17°; Z = 4
Identification
ColorHighly variable: white, colorless, gray, pink, lilac, violet, yellow and green, may be bicolored; emerald green - hiddenite; lilac - kunzite; yellow - triphane
Crystal habitprismatic, generally flattened and elongated, striated parallel to {100}, commonly massive
TwinningCommon on {100}
CleavagePerfect prismatic, two directions {110} ∧ {110} at 87°
FractureUneven to subconchoidal
TenacityBrittle
Mohs scale hardness6.5–7
|re|er}}Vitreous, pearly on cleavage
Streakwhite
Specific gravity3.03–3.23
Optical propertiesBiaxial (+)
Refractive indexnα = 1.648–1.661 nβ = 1.655–1.670 nγ = 1.662–1.679
Birefringenceδ = 0.014–0.018
PleochroismStrong in kunzite: α-purple, γ-colorless; hiddenite: α-green, γ-colorless
2V angle54° to 69°
Fusibility3.5
Solubilityinsoluble
Other characteristicsTenebrescence, chatoyancy
References[1][2][3][4]

Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, LiAl(SiO3)2, and is a source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, prismatic crystals, often of great size. Single crystals of 14.3 m (47 ft) in size are reported from the Black Hills of South Dakota, United States .[6][7]

The naturally-occurring low-temperature form α-spodumene is in the monoclinic system , and the high-temperature β-spodumene crystallizes in the tetragonal system. α-spodumene converts to β-spodumene at temperatures above 900 °C.[4] Crystals are typically heavily striated parallel to the principal axis. Crystal faces are often etched and pitted with triangular markings.

Discovery and occurrence

Spodumene was first described in 1800 for an occurrence in the type locality in Utö, Södermanland, Sweden. It was discovered by Brazilian naturalist Jose Bonifacio de Andrada e Silva. The name is derived from the Greek spodumenos (σποδούμενος), meaning "burnt to ashes", owing to the opaque ash-grey appearance of material refined for use in industry.[1]

Spodumene occurs in lithium-rich granite pegmatites and aplites. Associated minerals include: quartz, albite, petalite, eucryptite, lepidolite and beryl.[2]

% Global Lithium Hard Rock Resources By Company. Major car manufacturers and lithium battery chemical converters are securing long-term agreements for lithium supply, a key raw material in the production of electric vehicle (EV) battery cells

Transparent material has long been used as a gemstone with varieties kunzite and hiddenite noted for their strong pleochroism. Source localities include Democratic Republic of Congo, Afghanistan, Australia , Brazil , Madagascar (see mining), Pakistan , Québec in Canada , and North Carolina and California in the United States

Since 2018, the Democratic Republic of Congo (DRC) has been known to have the largest lithium spodumene hard rock deposit in the world, with mining operations occurring in the central DRC territory of Manono, Tanganyika Province.[8] The total resource of the deposit located in Manono has the potential to be in the magnitude of 1.5 billion tons of high-grade low-impurities lithium spodumene hard-rock. The two largest pegmatites (known as the Carriere de l'Este Pegmatite and the Roche Dure Pegmatite) are each of similar size or larger than the famous Greenbushes Pegmatite in Western Australia. By 2023, theDemocratic Republic of Congo is expected to be a significant supplier of lithium to the world by means of its high-grade and low-impurity spodumene. As of 2021, the Australia n company AVZ Minerals[9] is developing the Manono Lithium and Tin project and has a resource size of 400 million tonnes of high grade low impurities at 1.65% lithium oxide (Li2O)[10] spodumene hard-rock based on studies and drilling of Roche Dure, one of several pegmatites in the deposit.

Economic importance

Spodumene is an important source of lithium, for use in ceramics, mobile phone and automotive batteries, medicine, Pyroceram and as a fluxing agent. As of 2019, around half of lithium is extracted from mineral ores, which mainly consist of spodumene. Lithium is extracted from spodumene by fusing in acid after roasting to convert it to the more reactive β-spodumene. The advantage of spodumene as a lithium source compared to brine sources is the higher lithium concentration, at the expense of a higher extraction cost.[11]

In 2016, the price was forecast to be $500–600/ton for years to come.[12] However, price spiked above $800 in January 2018, and production increased more than consumption, reducing the price to $400 in September 2020.[13][14]

World production of lithium via spodumene was around 80,000 metric tonnes per annum in 2018, primarily from the Greenbushes pegmatite of Western Australia and from some China and Chile an sources. The Talison mine in Greenbushes, Western Australia, is reported to be the 2nd largest and to have the highest grade of ore at 2.4% Li2O (2012 figures).[15]

In 2020, Australia expanded spodumene mining to become the leading lithium producing country in the world.[16]

Extraction of lithium from spodumene is challenging due to the tight binding of lithium in the crystal structure. Processing methods rely on roasting at high temperature with various reagents. At temperatures in excess of 800 °C (1,470 °F), the spodumene is converted from the alpha structure to a more open beta structure from which the lithium is more easily extracted by the reagents. Suitable extraction reagents include alkali metal sulfates, such as sodium sulfate; sodium carbonate; chlorine; or hydrofluoric acid.[17]

An important economic concentrate of spodumene, known as spodumene concentrate 6 or SC6, is a high-purity lithium ore with approximately 6 percent lithium content being produced as a raw material for the subsequent production of lithium-ion batteries for electric vehicles.[18][19]

Gemstone varieties

Hiddenite

Hiddenite is a pale, emerald-green gem variety first reported from Alexander County, North Carolina, U.S.[20] It was named in honor of William Earl Hidden (16 February 1853 - 12 June 1918), mining engineer, mineral collector, and mineral dealer.[21]

This emerald-green variety of spodumene is colored by chromium, just as for emeralds. Not all green spodumene is colored with chromium, which tend to have a lighter color, and therefore are not true hiddenite.[clarification needed]

Kunzite

Kunzite is a purple-colored gemstone, a variety of spodumene, with the color coming from minor to trace amounts of manganese. Some (but not all) kunzite used for gemstones has been heated to enhance its color. It is also frequently irradiated to enhance the color. Exposure to sunlight will fade its color.[21]

Kunzite was discovered in 1902, and was named after George Frederick Kunz, Tiffany & Co's chief jeweler at the time, and a noted mineralogist.[21] It has been found in Brazil , the U.S., Canada , CIS, Mexico, Sweden, Western Australia, Afghanistan and Pakistan .[21]

Triphane

Triphane is the name used for yellowish varieties of spodumene.[22]

See also

Notes

  1. 1.0 1.1 Spodumene, Mindat.org
  2. 2.0 2.1 Anthony, John W., Bideaux, Richard A., Bladh, Kenneth W., and Nichols, Monte C. (1990). Handbook of Mineralogy. Mineral Data Publishing, Tucson, Arizona
  3. Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., ISBN:0-471-80580-7
  4. 4.0 4.1 Deer, Howie and Zussman, Rock Forming Minerals, v. 2 Chain Silicates, Wiley, 1963 pp. 92-98
  5. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. https://www.cambridge.org/core/journals/mineralogical-magazine/article/imacnmnc-approved-mineral-symbols/62311F45ED37831D78603C6E6B25EE0A. 
  6. Schwartz, G. (1928). "The Black Hills Mineral Region". American Mineralogist 13: 56–63. http://www.minsocam.org/msa/collectors_corner/arc/black_hills.htm. 
  7. Robert Louis Bonewitz, 2005, Rock and Gem, London, Dorling Kindersley
  8. "This Congo project could supply the world with lithium". MiningDotCom. 10 December 2018. https://www.mining.com/one-congo-project-supply-world-lithium/. 
  9. "AVZ Minerals Limited". https://avzminerals.com.au/. 
  10. "AVZ Minerals Definitive Feasibility Study (DFS - April 2020)". https://avzminerals.com.au/manono-project-definitive-feasibility-review. 
  11. Rioyo, Javier; Tuset, Sergio; Grau, Ramón (12 August 2020). "Lithium Extraction from Spodumene by the Traditional Sulfuric Acid Process: A Review". Mineral Processing and Extractive Metallurgy Review 43: 97–106. doi:10.1080/08827508.2020.1798234. ISSN 0882-7508. https://doi.org/10.1080/08827508.2020.1798234. 
  12. "Spodumene concentrate forecasted price 2020". 21 July 2016. https://www.statista.com/statistics/712619/price-forecast-of-spodumene/. 
  13. Shi, Carrie; Ouerghi, Dalila (5 October 2020). "Demand pick-up halts spodumene price fall". https://www.metalbulletin.com/Article/3954467/Demand-pick-up-halts-spodumene-price-fall.html. 
  14. "Lithium Resources and Energy Quarterly". December 2019. https://publications.industry.gov.au/publications/resourcesandenergyquarterlydecember2019/documents/Resources-and-Energy-Quarterly-December-2019-Lithium.pdf. 
  15. "Greenbushes Lithium Mine". http://www.goldendragoncapital.com/greenbushes-lithium-mine/. 
  16. Jaskula, Brian W. (January 2020). "Mineral Commodity Summaries 2020". https://pubs.usgs.gov/periodicals/mcs2020/mcs2020-lithium.pdf. 
  17. Choubey, Pankaj K.; Kim, Min-seuk; Srivastava, Rajiv R.; Lee, Jae-chun; Lee, Jin-Young (April 2016). "Advance review on the exploitation of the prominent energy-storage element: Lithium. Part I: From mineral and brine resources". Minerals Engineering 89: 119–137. doi:10.1016/j.mineng.2016.01.010. 
  18. Jamasmie, Cecilia (28 September 2020). "Piedmont Lithium stock soars on confirmed Tesla deal". mining.com. https://www.mining.com/piedmont-lithium-soars-after-confirming-tesla-deal/. Retrieved 13 March 2021. 
  19. Piedmont Lithium Signs Sales Agreement with Tesla, 28 September 2020, retrieved 14 March 2021.
  20. Smith, John Lawrence. "Hiddenite, an emerald-green variety of spodumene." American Journal of Science 3.122 (1881): 128-130.
  21. 21.0 21.1 21.2 21.3 Cook, Robert B. (1 September 1997). "Connoisseur's Choice: Spodumene var. Kunzite, Nuristan, Afghanistan". Rocks & Minerals 72 (5): 340–343. doi:10.1080/00357529709605063. ISSN 0035-7529. https://doi.org/10.1080/00357529709605063. 
  22. Brooks, Kent (2020). "Lithium minerals". Geology Today 36 (5): 192–197. doi:10.1111/gto.12326. ISSN 1365-2451. https://onlinelibrary.wiley.com/doi/abs/10.1111/gto.12326. 

References

  • Kunz, George Frederick (1892). Gems and Precious Stones of North America. New York: The Scientific Publishing Company.
  • Palache, C., Davidson, S. C., and Goranson, E. A. (1930). "The Hiddenite deposit in Alexander County, N. Carolina". American Mineralogist Vol. 15 No. 8 p. 280
  • Webster, R. (2000). Gems: Their Sources, Descriptions and Identification (5th ed.), pp. 186–190. Great Britain: Butterworth-Heinemann.
  • The key players in Quebec lithium , "Daily News", The Northern Miner, 11 August 2010.

External links