Chemistry:Kaempferol 7-O-glucoside

From HandWiki
Kaempferol 7-O-glucoside
Kaempferol 7-O-glucoside.svg
Names
IUPAC name
7-(β-D-Glucopyranosyloxy)-3,4′,5-trihydroxyflavone
Systematic IUPAC name
3,5-Dihydroxy-2-(4-hydroxyphenyl)-7-{[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-4H-1-benzopyran-4-one
Other names
Kaempferol-7-O-beta-D-glucoside
Identifiers
3D model (JSmol)
ChemSpider
UNII
Properties
C21H20O11
Molar mass 448.380 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Kaempferol 7-O-glucoside is a flavonol glucoside. It can be found in Smilax china,[1] and in the fern Asplenium rhizophyllum, and its hybrid descendants, as part of a complex with caffeic acid.[2]

Derivatives

Amurensin is the tert-amyl alcohol derivative of kaempferol 7-O-glucoside. 6'''-O-acetyl amurensin is found in the leaves of Phellodendron japonicum.[3]

References

  1. Xu, W.; Liu, J.; Li, C.; Wu, H. Z.; Liu, Y. W. (2008). "Kaempferol-7-O-β-d-glucoside (KG) isolated from Smilax china L. rhizome induces G2/M phase arrest and apoptosis on HeLa cells in a p53-independent manner". Cancer Letters 264 (2): 229–240. doi:10.1016/j.canlet.2008.01.044. PMID 18343026. 
  2. Harborne, Jeffrey B.; Williams, Christine A.; Smith, Dale M. (1973). "Species-specific kaempferol derivatives in ferns of the Appalachian Asplenium complex". Biochemical Systematics and Ecology 1 (1): 51–54. doi:10.1016/0305-1978(73)90035-5. 
  3. Chiu, C. Y.; Li, C. Y.; Chiu, C. C.; Niwa, M.; Kitanaka, S.; Damu, A. G.; Lee, E. J.; Wu, T. S. (2005). "Constituents of Leaves of Phellodendron japonicum MAXIM. And Their Antioxidant Activity". Chemical & Pharmaceutical Bulletin 53 (9): 1118. doi:10.1248/cpb.53.1118.