Chemistry:Manganese oxalate
From HandWiki
| Names | |
|---|---|
| Other names
Manganese(II) oxalate, Manganese(2+) oxalate, Lindbergite
| |
| Identifiers | |
3D model (JSmol)
|
|
| ChemSpider | |
| EC Number |
|
PubChem CID
|
|
| UNII | |
| |
| |
| Properties | |
| C2MnO4 | |
| Molar mass | 142.956 g·mol−1 |
| Appearance | Light pink crystals |
| Density | 2.43 |
| insoluble | |
Solubility product (Ksp)
|
1.7×10−7[1] |
| Hazards | |
| GHS pictograms | 
|
| GHS Signal word | Warning |
| H302, H312 | |
| P264, P270, P280, P301+312, P302+352, P312, P322, P330, P363, P501 | |
| Related compounds | |
Related compounds
|
Magnesium oxalate Strontium oxalate Barium oxalate Iron(II) oxalate Iron(III) oxalate Praseodymium oxalate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Manganese oxalate is a chemical compound, a salt of manganese and oxalic acid with the chemical formula MnC2O4.[2][3] The compound creates light pink crystals, does not dissolve in water, and forms crystalline hydrates.[4] It occurs naturally as the mineral Lindbergite.[5]
Synthesis
Exchange reaction between sodium oxalate and manganese chloride:
- [math]\displaystyle{ \mathsf{ MnCl_2 + Na_2C_2O_4 + 2H_2O \ \xrightarrow{}\ MnC_2O_4\cdot 2H_2O\downarrow + 2NaCl } }[/math]
Physical properties
Manganese oxalate forms light pink crystals.
It does not dissolve in water, p Ksp= 6.8.
Forms crystalline hydrates of the composition MnC2O4•n H2O, where n = 2 and 3.[6]
Crystalline hydrate of the composition MnC2O4•2H2O forms light pink crystals of the orthorhombic system, space group P212121, cell parameters a = 0.6262 nm, b = 1.3585 nm, c = 0.6091 nm, Z = 4, melts in its own crystallization water at 100°C.[7][8]
Chemical properties
Decomposes on heating:
- [math]\displaystyle{ \mathsf{ MnC_2O_4 \ \xrightarrow{215^oC}\ MnO + CO\uparrow + CO_2\uparrow } }[/math]
Application
- Manganese oxalate is used as an auxiliary siccative.
- Manganese oxalate precursor is used to synthesize single phase nanoparticles of various manganese oxides, such as MnO, Mn2O3, and Mn3O4.[9]
See also
References
- ↑ John Rumble (June 18, 2018) (in English). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–188. ISBN 978-1138561632.
- ↑ Lunge, Georg (1924) (in en). Lunge and Keane's Technical Methods of Chemical Analysis. 2d Ed., Edited by Charles A. Keane ...and P.C.L. Thorne. Gurney and Jackson. p. 61. https://books.google.com/books?id=-RNuAAAAIAAJ&q=Manganese+oxalate. Retrieved 5 August 2021.
- ↑ Young, Philena Anne (1928) (in en). The Volumetric Determination of Vanadium and Chromium in Special Alloy Steels: Ceric Sulfate as a Volumetric Oxidizing Agent. Mack Printing Company. p. 74. https://books.google.com/books?id=A0jPAAAAMAAJ&q=Manganese+oxalate. Retrieved 5 August 2021.
- ↑ Donkova, B.; Mehandjiev, D. (2004). "Mechanism of decomposition of manganese(II) oxalate dihydrate and manganese(II) oxalate trihydrate" (in English). Thermochimica Acta 421 (1–2): 141–149. doi:10.1016/j.tca.2004.04.001. ISSN 0040-6031. https://inis.iaea.org/search/search.aspx?orig_q=RN:36074968. Retrieved 5 August 2021.
- ↑ Atencio, Daniel; Coutinho, José M.V.; Graeser, Stefan; Matioli, Paulo A.; Menezes Filho, Luiz A.D. (2004). "Lindbergite, a new Mn oxalate dihydrate from Boca Rica mine, Galiléia, Minas Gerais, Brazil, and other occurrences" (in English). American Mineralogist 89 (7): 1087–1091. doi:10.2138/am-2004-0721. ISSN 1945-3027. Bibcode: 2004AmMin..89.1087A. https://pubs.geoscienceworld.org/msa/ammin/article-abstract/89/7/1087/44298/Lindbergite-a-new-Mn-oxalate-dihydrate-from-Boca. Retrieved 1 December 2021.
- ↑ Nedyalkova, Miroslava; Antonov, Vladislav (1 January 2018). "Manganese oxalates - structure-based Insights" (in en). Open Chemistry 16 (1): 1176–1183. doi:10.1515/chem-2018-0123. ISSN 2391-5420.
- ↑ Puzan, Anna N.; Baumer, Vyacheslav N.; Lisovytskiy, Dmytro V.; Mateychenko, Pavel V. (1 April 2018). "Structure disordering and thermal decomposition of manganese oxalate dihydrate, MnC2O4·2H2O" (in en). Journal of Solid State Chemistry 260: 87–94. doi:10.1016/j.jssc.2018.01.022. ISSN 0022-4596. Bibcode: 2018JSSCh.260...87P. https://www.sciencedirect.com/science/article/abs/pii/S0022459618300409. Retrieved 5 August 2021.
- ↑ Donkova, Borjana; Avdeev, Georgi (1 August 2015). "Synthesis and decomposition mechanism of γ-MnC2O4·2H2O rods under non-isothermal and isothermal conditions" (in en). Journal of Thermal Analysis and Calorimetry 121 (2): 567–577. doi:10.1007/s10973-015-4590-4. ISSN 1588-2926. https://link.springer.com/article/10.1007%2Fs10973-015-4590-4. Retrieved 5 August 2021.
- ↑ Ahmad, Tokeer; Ramanujachary, Kandalam V.; Lofland, Samuel E.; Ganguli, Ashok K. (24 November 2004). "Nanorods of manganese oxalate: a single source precursor to different manganese oxide nanoparticles (MnO, Mn2O3, Mn3O4)" (in en). Journal of Materials Chemistry 14 (23): 3406–3410. doi:10.1039/B409010A. ISSN 1364-5501. https://pubs.rsc.org/en/Content/ArticleLanding/JM/2004/B409010A. Retrieved 5 August 2021.
 |  |
