Chemistry:Manganese(II) fluoride
From HandWiki
| |
| Names | |
|---|---|
| IUPAC name
Manganese(II) fluoride
| |
| Identifiers | |
3D model (JSmol)
|
|
| ChemSpider | |
| EC Number |
|
PubChem CID
|
|
| RTECS number |
|
| UNII | |
| |
| |
| Properties | |
| MnF2 | |
| Molar mass | 92.934855 g/mol |
| Appearance | pale pink crystalline |
| Density | 3.98 g/cm3[1] |
| Melting point | 856 °C (1,573 °F; 1,129 K)[1] |
| Boiling point | 1,820 °C (3,310 °F; 2,090 K) |
| 1.02 g/100 ml | |
| +10,700·10−6 cm3/mol | |
| Hazards[2] | |
| GHS pictograms | 
|
| GHS Signal word | Warning |
| H302, H312, H315, H319, H332, H335 | |
| P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P305+351+338, P312, P321, P322, P330, P332+313, P337+313, P362, P363, P403+233, P405, P501 | |
| Flash point | non-flammable |
| Related compounds | |
Other anions
|
Manganese(II) chloride Manganese(II) bromide Manganese(II) iodide |
Other cations
|
Technetium(VI) fluoride Rhenium(VII) fluoride Manganese(III) fluoride Manganese(IV) fluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
 verify (what is   ?)
| |
| Infobox references | |
Manganese(II) fluoride is the chemical compound composed of manganese and fluoride with the formula MnF2. It is a light pink solid, the light pink color being characteristic for manganese(II) compounds. It is made by treating manganese and diverse compounds of manganese(II) in hydrofluoric acid. Like some other metal difluorides, MnF2 crystallizes in the rutile structure, which features octahedral Mn centers.[3]
Uses
MnF2 is used in the manufacture of special kinds of glass and lasers.[4] It is a canonical example of uniaxial antiferromagnet (with Neel temperature of 68 K)[5] which has been experimentally studied since early on.[6]
References
- ↑ 1.0 1.1 Maurice Griffel; J. W. Stout (1950). "Preparation of Single Crystals of Manganous Fluoride. The Crystal Structure from X-Ray Diffraction. The Melting Point and Density" (in English). Journal of the American Chemical Society 72 (10): 4351–4353. doi:10.1021/ja01166a004.
- ↑ "339288 Manganese(II) fluoride 98%". Sigma-Aldrich. http://www.sigmaaldrich.com/catalog/search/ProductDetail/ALDRICH/339288.
- ↑ Stout, J. W.; Reed, Stanley A. (1954). "The Crystal Structure of MnF2, FeF2, CoF2, NiF2 and ZnF2". J. Am. Chem. Soc. 76 (21): 5279–5281. doi:10.1021/ja01650a005.
- ↑ Ayres, D. C.; Hellier, Desmond (1997). Dictionary of Environmentally Important Chemicals. CRC Press. pp. 195. ISBN 0-7514-0256-7. https://books.google.com/books?id=UTKWehimCkEC&q=%22Manganese(II)+fluoride+%22&pg=PA195. Retrieved 2008-06-18.
- ↑ Felcher, G. P; Kleb, R (20 November 1996). "Antiferromagnetic domains and the spin-flop transition of MnF 2". Europhysics Letters (EPL) 36 (6): 455–460. doi:10.1209/epl/i1996-00251-7. Bibcode: 1996EL.....36..455F.
- ↑ Stout, J. W.; Matarrese, L. M. (1 January 1953). "Magnetic Anisotropy of the Iron-Group Fluorides". Reviews of Modern Physics 25 (1): 338–343. doi:10.1103/RevModPhys.25.338. Bibcode: 1953RvMP...25..338S.
 |  |
