Chemistry:Potassium fulminate

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Potassium fulminate
K+−C≡N+−O−
Names
IUPAC name
Potassium oxidoazaniumylidynemethane
Identifiers
3D model (JSmol)
ChemSpider
Properties
CKNO
Molar mass 81.115 g·mol−1
Density 1.8 g/cm3
Hazards
Main hazards Explosive
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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Potassium fulminate is the potassium salt of the fulminate ion. Its only use, aside from chemical demonstrations, is in the percussion caps for some early rifles. Usually prepared by reacting a potassium amalgam with mercury fulminate,[1] it is much less sensitive due to the ionic bond between potassium and carbon, unlike the weaker covalent bond between mercury and carbon.

See also

References

  1. ↑ Z. Iqbal and A. D. Yoffe (1967). "Electronic Structure and Stability of the Inorganic Fulminates". Proceedings of the Royal Society of London 302 (1468): 35–49. doi:10.1098/rspa.1967.0225. Bibcode: 1967RSPSA.302...35I.