Physics:Quantum Eigenstates and eigenvalues
Quantum eigenstates and eigenvalues describe the states of a quantum system that yield definite results when a physical observable is measured. Each observable is represented by an operator, whose eigenvalues correspond to measurable quantities.[1]

Mathematical formulation
In quantum mechanics, observables are represented by operators acting on wavefunctions. An eigenstate satisfies:
where:
- is a linear operator
- is the eigenvalue
- is the eigenfunction (eigenstate)
This equation means that applying the operator does not change the form of the state, only its magnitude.[2]
Physical interpretation
Eigenstates correspond to states with definite measurement outcomes:
- Measuring observable in eigenstate yields with certainty
- After measurement, the system remains in that eigenstate
- General states can be expressed as superpositions of eigenstates
This is a central postulate of quantum mechanics.[3]
Energy eigenstates
A key example is the Hamiltonian operator , which represents the total energy:
where:
- are discrete energy levels
- are stationary states
These states evolve in time as:
Orthogonality and completeness
Eigenstates of a Hermitian operator have important properties:
- Orthogonality:
- Completeness: Any wavefunction can be expressed as a sum of eigenstates
These properties allow expansion of arbitrary quantum states in a basis of eigenfunctions.[5]
Applications
Eigenstates and eigenvalues are fundamental in:
- Atomic and molecular spectra
- Quantum measurements
- Quantum computing (basis states)
- Solving Schrödinger equations
They provide the link between mathematical operators and physical observables.[6]
See also
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