Chemistry:Ytterbium(III) nitride
From HandWiki
| Names | |
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| Other names
Ytterbium mononitride, azanylidynytterbium, nitridoytterbium[1]
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| NYb | |
| Molar mass | 187.052 g·mol−1 |
| Appearance | black powder |
| Density | 6.57 g/cm3 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Ytterbium nitride is a binary inorganic compound of ytterbium and nitrogen with the chemical formula YbN.[2][3]
Synthesis
Reaction of ytterbium hydride and ammonia at 800°C:[4]
- 2YbH
2 + 2NH
3 → 2YbN + 5H
2
- 2YbH
Reaction of ytterbium and nitrogen with an admixture of hydrogen under pressure at 500–600°C::
- 2Yb + N
2 → 2YbN
- 2Yb + N
Physical properties
YbN forms black powder. The compound is notable for its high melting point.[5]
Uses
YbN holds potential applications in the fields of electronics and optics.[5]
Also used as an additive for special alloys, ceramic materials, semiconductors.[6]
References
- ↑ "ytterbium nitride" (in en). chemsrc.com. https://www.chemsrc.com/en/cas/24600-77-9_684635.html.
- ↑ "Ytterbium Nitride" (in en). American Elements. https://www.americanelements.com/ytterbium-nitride-24600-77-9.
- ↑ O'Bannon, Loran (6 December 2012) (in en). Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. p. 280. ISBN 978-1-4613-2655-7. https://books.google.com/books?id=pM_gBwAAQBAJ&dq=Ytterbium+nitride&pg=PA280. Retrieved 31 January 2024.
- ↑ Samsonov, Grigoriĭ Valentinovich (1965) (in en). High-temperature Compounds of Rare Earth Metals with Nonmetals. Consultants Bureau. p. 169. https://books.google.com/books?id=Iu0yAAAAMAAJ&q=Ytterbium+nitride. Retrieved 31 January 2024.
- ↑ 5.0 5.1 "Ytterbium Nitride Powder, YbN, CAS 24600-77-9 - Heeger Materials" (in en-us). Heeger Materials Inc. https://heegermaterials.com/nitride-powder/1693-ytterbium-nitride-powder-ybn-cas-24600-77-9.html.
- ↑ "Ytterbium Nitride (YbN) Powder (CAS No. 24600-77-9)" (in en). samaterials.com. https://www.samaterials.com/nitrogen/1925-ytterbium-nitride-powder.html.
Salts and covalent derivatives of the nitride ion
| NH3 | He(N2)11 | ||||||||||||||||
| Li3N | Be3N2 | BN | β-C3N4 g-C3N4 |
N2 | NxOy | NF3 | Ne | ||||||||||
| Na3N | Mg3N2 | AlN | Si3N4 | PN P3N5 |
SxNy SN S4N4 |
NCl3 | Ar | ||||||||||
| K3N | Ca3N2 | ScN | TiN | VN | CrN Cr2N |
MnxNy | FexNy | CoN | Ni3N | CuN | Zn3N2 | GaN | Ge3N4 | As | Se | NBr3 | Kr |
| Rb3N | Sr3N2 | YN | ZrN | NbN | β-Mo2N | Tc | Ru | Rh | PdN | Ag3N | CdN | InN | Sn | Sb | Te | NI3 | Xe |
| Cs3N | Ba3N2 | Hf3N4 | TaN | WN | Re | Os | Ir | Pt | Au | Hg3N2 | TlN | Pb | BiN | Po | At | Rn | |
| Fr3N | Ra3N | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La | CeN | Pr | Nd | Pm | Sm | Eu | GdN | Tb | Dy | Ho | Er | Tm | Yb | Lu | |||
| Ac | Th | Pa | UN | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||
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