Chemistry:2-Chlorobenzaldehyde

From HandWiki

2-Chlorobenzaldehyde (o-chlorobenzaldehyde) is an organic compound with the formula ClC
5
H
4
CHO
. It is one of three isomeric monochlorinated benzaldehyde. 3-Chlorobenzaldehyde and 4-chlorobenzaldehyde are the other isomers. Whereas benzaldehyde is prone to autoxidation, the 2-chloro derivatives are more air-stable.

Synthesis and uses

It is produced by hydrolysis of 2-chlorobenzal chloride:[1]

ClC
5
H
4
CHCl
2
+ H
2
O → ClC
5
H
4
CHO + 2 HCl

2-Chlorobenzaldehyde is used in production of CS gas. It reacts with malononitrile to form CS.[2]

References

  1. Brühne, Friedrich; Wright, Elaine (2011). "Benzaldehyde". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a03_463.pub2. ISBN 978-3-527-30385-4. 
  2. "Synthesis of ortho-chlorobenzalmalononitrile". https://patents.google.com/patent/US3963770A.