Chemistry:Costaclavin
From HandWiki
Costaclavin is an ergoline fungal isolate, chemically related to festuclavine. It was first isolated from Agropyrum fungi in 1956[1] and its chemical structure was elucidated in 1976.[2]
Several laboratory syntheses of costaclavin have been reported.[3][4]
References
- ↑ Abe, Matazō; Yamatodani, Saburō; Yamano, Togō; Kusumoto, Mitsugi (1956). "Isolation of Two New Water-Soluble Alkaloids, Pyroclavine and Costaclavine". Bulletin of the Agricultural Chemical Society of Japan 20: 59–60. doi:10.1080/03758397.1956.10857305.
- ↑ Ninomiya, Ichiya; Kiguchi, Toshiko (1976). "New synthesis of clavine: Determination of the structure of costaclavine by nuclear magnetic resonance spectroscopy". Journal of the Chemical Society, Chemical Communications (16): 624. doi:10.1039/C39760000624.
- ↑ Liu, Haichao; Zhang, Xiwu; Shan, Dong; Pitchakuntla, Mallesham; Ma, Yongfan; Jia, Yanxing (2017). "Total Syntheses of Festuclavine, Pyroclavine, Costaclavine, epi -Costaclavine, Pibocin A, 9-Deacetoxyfumigaclavine C, Fumigaclavine G, and Dihydrosetoclavine". Organic Letters 19 (12): 3323–3326. doi:10.1021/acs.orglett.7b01504. PMID 28593757.
- ↑ Osanai, Kumi; Yokoyama, Yuusaku; Kondo, Kazuhiro; Murakami, Yasuoki (1999). "Total Synthesis of Optically Active Costaclavine. Synthetic Studies of Indoles and Related Compounds. Part 48". Chemical and Pharmaceutical Bulletin 47 (11): 1587–1590. doi:10.1248/cpb.47.1587.
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