Physics:Barium stannate

From HandWiki
Barium stannate

Perovskite crystal structure
Names
Other names
  • Barium tin oxide
  • Barium tin trioxide
  • Tin barium oxide
Identifiers
3D model (JSmol)
ChemSpider
Properties[1]
BaO3Sn
Molar mass 304.034 g·mol−1
Appearance white solid
Density 7.24 g/cm3
slightly soluble
Structure[2]
cubic
Pm3m (No. 221)
a = 4.115 Å
α = 90°, β = 90°, γ = 90°
Hazards
GHS pictograms GHS07: Harmful
GHS Signal word Warning
H302, H332
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Barium stannate (BSO)[4] is an oxide of barium and tin with the chemical formula BaSnO3. It is a wide band gap semiconductor with a perovskite crystal structure.[5][6][7] A trihydrate exists and is used in the production of ceramic insulation requiring dielectric properties.[1]

Preparation

Polycrystalline barium stannate can be prepared by a solid state reaction between barium carbonate and tin(IV) oxide.[8]

References

  1. 1.0 1.1 Perry, Dale L. (2016-04-19) (in en). Handbook of Inorganic Compounds. CRC Press. pp. 56-57. ISBN 978-1-4398-1462-8. https://books.google.com/books?id=SFD30BvPBhoC. 
  2. Deepa, A. S.; Vidya, S.; Manu, P. C.; Solomon, Sam; John, Annamma; Thomas, J. K. (2011-02-03). "Structural and optical characterization of BaSnO3 nanopowder synthesized through a novel combustion technique". Journal of Alloys and Compounds 509 (5): 1830–1835. doi:10.1016/j.jallcom.2010.10.056. ISSN 0925-8388. https://www.sciencedirect.com/science/article/pii/S092583881002565X. 
  3. "ECHA CHEM". https://chem.echa.europa.eu/100.031.392/harmonised/76814?searchText=12009-18-6. 
  4. (in en) Encyclopedia of Renewable Energy, Sustainability and the Environment. Elsevier. 2024-08-09. p. 782. ISBN 978-0-323-93941-6. https://books.google.com/books?id=s8IAEQAAQBAJ&pg=RA1-PA782. Retrieved 2025-10-06. 
  5. Wei, Xiaoyong; Yao, Xi (February 2007). "Preparation, structure and dielectric property of barium stannate titanate ceramics". Materials Science and Engineering: B 137 (1–3): 184–188. doi:10.1016/j.mseb.2006.11.012. 
  6. Luo, B.C.; Zhang, J.; Wang, J.; Ran, P.X. (March 2015). "Structural, electrical and optical properties of lanthanum-doped barium stannate". Ceramics International 41 (2): 2668–2672. doi:10.1016/j.ceramint.2014.10.080. 
  7. Li, Yuwei; Zhang, Lijun; Ma, Yanming; Singh, David J. (1 January 2015). "Tuning optical properties of transparent conducting barium stannate by dimensional reduction". APL Materials 3 (1): 011102. doi:10.1063/1.4906785. Bibcode2015APLM....3a1102L. 
  8. Phelan, D.; Han, F.; Lopez-Bezanilla, A.; Krogstad, M. J.; Gim, Y.; Rong, Y.; Zhang, Junjie; Parshall, D. et al. (2018-06-01). "Structural properties of barium stannate". Journal of Solid State Chemistry 262: 142–148. doi:10.1016/j.jssc.2018.01.019. ISSN 0022-4596. https://www.sciencedirect.com/science/article/pii/S0022459618300343.