Chemistry:Thulium(III) acetate
From HandWiki
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| Names | |
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| Other names
Thulium acetate
Thulium triacetate | |
| Identifiers | |
3D model (JSmol)
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PubChem CID
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| Properties | |
| Tm(CH3COO)3 | |
| Appearance | crystals |
| soluble | |
| Hazards | |
| GHS pictograms | 
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| GHS Signal word | Warning |
| H315, H319, H335 | |
| P261, P264, P264+265Script error: No such module "Preview warning".Category:GHS errors, P271, P280, P302+352, P304+340, P305+351+338, P319Script error: No such module "Preview warning".Category:GHS errors, P321, P332+317Script error: No such module "Preview warning".Category:GHS errors, P337+317Script error: No such module "Preview warning".Category:GHS errors, P362+364Script error: No such module "Preview warning".Category:GHS errors, P403+233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Thulium(III) acetate is the acetate salt of thulium, with the chemical formula of Tm(CH3COO)3. It can exist in the tetrahydrate or the anhydrous form.[2]
Properties
Thulium(III) acetate reacts with iron acetylacetonate at 300 °C, which can form the hexagonal crystal TmFeO3.[3]
Reacting thulium(III) acetate with trifluoroacetic acid will produce thulium trifluoroacetate:[4]
- Tm(CH3COO)3 + 3 CF3COOH → Tm(CF3COO)3 + 3 CH3COOH
References
- ↑ "Thulium acetate" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/170163#section=Safety-and-Hazards.
- ↑ K. I. Petrov, M. G. Zaitseva, L. M. Sukova (1971-08-01). "Spectroscopic study of thulium acetate tetrahydrate single crystals" (in en). Journal of Applied Spectroscopy 15 (2): 1058–1060. doi:10.1007/BF00607309. ISSN 1573-8647. Bibcode: 1971JApSp..15.1058P.
- ↑ Masashi Inoue, Toshihiro Nishikawa, Tomohiro Nakamura, Tomoyuki Inui (1997). "Glycothermal Reaction of Rare-Earth Acetate and Iron Acetylacetonate: Formation of Hexagonal ReFeO3" (in en). Journal of the American Ceramic Society 80 (8): 2157–2160. doi:10.1111/j.1151-2916.1997.tb03103.x. ISSN 1551-2916.
- ↑ S. I. Gutnikov, E. V. Karpova, M. A. Zakharov, A. I. Boltalin (2006-04-01). "Thulium(III) trifluoroacetates Tm(CF3COO)3 · 3H2O and Tm2(CF3COO)6 · 2CF3COOH · 3H2O: Synthesis and crystal structure" (in en). Russian Journal of Inorganic Chemistry 51 (4): 541–548. doi:10.1134/S0036023606040061. ISSN 1531-8613.
External reading
- Mondry, A., & Bukietyńska, K. (2003). The power and limits of the Judd—Ofelt theory: a case of Pr3+ and Tm3+ acetates and dipicolinates. Molecular Physics, 101(7), 923-934.
Acetyl halides and salts of the acetate ion
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| AcOH | He | ||||||||||||||||||
| LiOAc | Be(OAc)2 BeAcOH |
B(OAc)3 | AcOAc ROAc |
NH4OAc | AcOOH | FAc | Ne | ||||||||||||
| NaOAc | Mg(OAc)2 | Al(OAc)3 ALSOL Al(OAc)2OH Al2SO4(OAc)4 |
Si | P | S | ClAc | Ar | ||||||||||||
| KOAc | Ca(OAc)2 | Sc(OAc)3 | Ti(OAc)4 | VO(OAc)3 | Cr(OAc)2 Cr(OAc)3 |
Mn(OAc)2 Mn(OAc)3 |
Fe(OAc)2 Fe(OAc)3 |
Co(OAc)2, Co(OAc)3 |
Ni(OAc)2 | Cu(OAc)2 | Zn(OAc)2 | Ga(OAc)3 | Ge | As(OAc)3 | Se | BrAc | Kr | ||
| RbOAc | Sr(OAc)2 | Y(OAc)3 | Zr(OAc)4 | Nb | Mo(OAc)2 | Tc | Ru(OAc)2 Ru(OAc)3 Ru(OAc)4 |
Rh2(OAc)4 | Pd(OAc)2 | AgOAc | Cd(OAc)2 | In | Sn(OAc)2 Sn(OAc)4 |
Sb(OAc)3 | Te | IAc | Xe | ||
| CsOAc | Ba(OAc)2 | Hf | Ta | W | Re | Os | Ir | Pt(OAc)2 | Au | Hg2(OAc)2, Hg(OAc)2 |
TlOAc Tl(OAc)3 |
Pb(OAc)2 Pb(OAc)4 |
Bi(OAc)3 | Po | At | Rn | |||
| Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
| ↓ | |||||||||||||||||||
| La(OAc)3 | Ce(OAc)x | Pr | Nd | Pm | Sm(OAc)3 | Eu(OAc)3 | Gd(OAc)3 | Tb | Dy(OAc)3 | Ho(OAc)3 | Er | Tm | Yb(OAc)3 | Lu(OAc)3 | |||||
| Ac | Th | Pa | UO2(OAc)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||
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