Chemistry:Lutetium(III) acetate
 | This article needs attention from an expert in Chemicals. (April 2023) |
 Some white lutetium acetate powder.
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| Names | |
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| IUPAC names
Tetra-μ2-acetatodiaquadilutetium(III)
lutetium(3+);triacetate neodymium(3+) triacetate | |
Other names
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| Identifiers | |
3D model (JSmol)
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| EC Number |
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PubChem CID
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| Properties | |
| Lu(C2H3O2)3 | |
| Hazards | |
| GHS pictograms | 
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| GHS Signal word | Warning |
| Related compounds | |
Other anions
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Lutetium(III) oxide Lutetium(III) hydroxide Lutetium(III) carbonate |
Other cations
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Ytterbium(III) acetate Thulium(III) acetate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Lutetium(III) acetate is the acetate salt of lutetium with the chemical formula of Lu(CH3COO)3.
Preparation
Lutetium(III) acetate can be prepared through neutralisation, where a lutetium salt reacts with acetic acid to produce lutetium acetate and water:
- Lu2O3 + 6 CH3COOH → 2 Lu(CH3COO)3 + 3 H2O
- Lu(OH)3 + 3 CH3COOH → Lu(CH3COO)3 + 3 H2O
Lutetium(III) acetate also can be obtained by reacting lutetium oxide with gaseous acetic acid[1] or 50% acetic acid solution.[2]
Properties
Lutetium(III) acetate is a water-soluble salt that forms colorless crystals. It forms crystalline hydrates in the form of Lu(CH3COO)3•nH2O, where n = 1 or 4.[citation needed]
Lutetium(III) acetate reacts with ammonium fluoride to produce lutetium fluoride:
- Lu(CH3COO)3 + 3 NH4F → LuF3 + 3 CH3COONH4
The F− formed by the hydrolysis of fluoroborates (such as [BMIM]BF4)[3] can also precipitate with Lu3+.[4]
Reaction with phosphoric acid to produce lutetium phosphate:[5]
- Lu(CH3COO)3 + H3PO4 → LuPO4 + 3 CH3COOH
References
- ↑ Janina Wysocka-Lisek. Study of topochemical preparation of rare earth acetates(in Polish). Biuletyn Lubelskiego Towarzystwa Naukowego, Matematyka-Fizyka-Chemia, 1981. 23 (2): 145-149.
- ↑ Grählert, Xina; Starke, Graehlert (1992). "Preparation, thermogravimetric study and infrared spectra of rare earth acetates". Preparation, Thermogravimetric Study and Infrared Spectra of Rare Earth Acetates 34 (2): 219–229. https://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5616675.
- ↑ Note: The original text is "BMIM = 1-butyl-2-methylimidazolium", which is supposed to be 1-butyl-3-methylimidazolium
- ↑ Becerro, Ana I.; Gonzalez-Mancebo, Daniel; Ocaña, Manuel (January 2015). "Uniform, luminescent Eu:LuF3 nanoparticles". Journal of Nanoparticle Research 17 (1): 58. doi:10.1007/s11051-015-2874-z. Bibcode: 2015JNR....17...58B.
- ↑ Becerro, Ana I.; Ocaña, Manuel (2015). "Quick synthesis, functionalization and properties of uniform, luminescent LuPO 4 -based nanoparticles". RSC Advances 5 (44): 34517–34524. doi:10.1039/C5RA05305F. Bibcode: 2015RSCAd...534517B.
Acetyl halides and salts of the acetate ion
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| AcOH | He | ||||||||||||||||||
| LiOAc | Be(OAc)2 BeAcOH |
B(OAc)3 | AcOAc ROAc |
NH4OAc | AcOOH | FAc | Ne | ||||||||||||
| NaOAc | Mg(OAc)2 | Al(OAc)3 ALSOL Al(OAc)2OH Al2SO4(OAc)4 |
Si | P | S | ClAc | Ar | ||||||||||||
| KOAc | Ca(OAc)2 | Sc(OAc)3 | Ti(OAc)4 | VO(OAc)3 | Cr(OAc)2 Cr(OAc)3 |
Mn(OAc)2 Mn(OAc)3 |
Fe(OAc)2 Fe(OAc)3 |
Co(OAc)2, Co(OAc)3 |
Ni(OAc)2 | Cu(OAc)2 | Zn(OAc)2 | Ga(OAc)3 | Ge | As(OAc)3 | Se | BrAc | Kr | ||
| RbOAc | Sr(OAc)2 | Y(OAc)3 | Zr(OAc)4 | Nb | Mo(OAc)2 | Tc | Ru(OAc)2 Ru(OAc)3 Ru(OAc)4 |
Rh2(OAc)4 | Pd(OAc)2 | AgOAc | Cd(OAc)2 | In | Sn(OAc)2 Sn(OAc)4 |
Sb(OAc)3 | Te | IAc | Xe | ||
| CsOAc | Ba(OAc)2 | Hf | Ta | W | Re | Os | Ir | Pt(OAc)2 | Au | Hg2(OAc)2, Hg(OAc)2 |
TlOAc Tl(OAc)3 |
Pb(OAc)2 Pb(OAc)4 |
Bi(OAc)3 | Po | At | Rn | |||
| Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
| ↓ | |||||||||||||||||||
| La(OAc)3 | Ce(OAc)x | Pr | Nd | Pm | Sm(OAc)3 | Eu(OAc)3 | Gd(OAc)3 | Tb | Dy(OAc)3 | Ho(OAc)3 | Er | Tm | Yb(OAc)3 | Lu(OAc)3 | |||||
| Ac | Th | Pa | UO2(OAc)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||
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