Chemistry:Scandium acetate
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| Other names
Scandium(III) acetate
Scandium ethanoate Scandium(III) ethanoate | |
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3D model (JSmol)
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| Properties | |
| C6H9O6Sc | |
| Molar mass | 222.088 g·mol−1 |
| Appearance | white solid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Scandium acetate is a compound, with the chemical formula of Sc(CH3COO)3. It exists in the anhydrous and the hydrate forms. It can be obtained by reacting scandium hydroxide or scandium oxide with acetic acid.[1][2] It is a colorless, water-soluble solid. It decomposes into scandium oxide at high temperature. It can be used to prepare other scandium-containing materials.[3]
The structure of the anhydrous form was determined by X-ray crystallography. It consists of a chain of octahedral Sc(III) centers linked by bridging acetate ligands.[1]
References
- ↑ 1.0 1.1 Fuchs, Robert; Strähle, Joachim (1984). "Die Kristallstruktur von Sc(CH3COO)3, ein Metall(III)acetat mit Kettenstruktur". Zeitschrift für Naturforschung B 39 (12): 1662–1663. doi:10.1515/znb-1984-1206.
- ↑ Krasil'Nikov, V. N.; Gyrdasova, O. I.; Baklanova, I. V.; Perelyaeva, L. A.; Zhilina, E. F.; Vovkotrub, É. G. (2012). "Structure and luminescence properties of nanostructured solid-state solutions of Sc1−xEux(CH3CO2)3". Theoretical and Experimental Chemistry 48 (2): 113–117. doi:10.1007/s11237-012-9247-9.
- ↑ Xin, Chengrong; Zhang, Qilong; Yang, Hui (2013). "Synthesis and Properties Study of BaTi0.95Sc0.05O3−δ Nanopowders and Ceramics" (in Chinese). Piezoelectrics & Acoustooptics 35 (3): 412–415. http://qikan.cqvip.com/Qikan/Article/Detail?id=46179713.
Acetyl halides and salts of the acetate ion
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| AcOH | He | ||||||||||||||||||
| LiOAc | Be(OAc)2 BeAcOH |
B(OAc)3 | AcOAc ROAc |
NH4OAc | AcOOH | FAc | Ne | ||||||||||||
| NaOAc | Mg(OAc)2 | Al(OAc)3 ALSOL Al(OAc)2OH Al2SO4(OAc)4 |
Si | P | S | ClAc | Ar | ||||||||||||
| KOAc | Ca(OAc)2 | Sc(OAc)3 | Ti(OAc)4 | VO(OAc)3 | Cr(OAc)2 Cr(OAc)3 |
Mn(OAc)2 Mn(OAc)3 |
Fe(OAc)2 Fe(OAc)3 |
Co(OAc)2, Co(OAc)3 |
Ni(OAc)2 | Cu(OAc)2 | Zn(OAc)2 | Ga(OAc)3 | Ge | As(OAc)3 | Se | BrAc | Kr | ||
| RbOAc | Sr(OAc)2 | Y(OAc)3 | Zr(OAc)4 | Nb | Mo(OAc)2 | Tc | Ru(OAc)2 Ru(OAc)3 Ru(OAc)4 |
Rh2(OAc)4 | Pd(OAc)2 | AgOAc | Cd(OAc)2 | In | Sn(OAc)2 Sn(OAc)4 |
Sb(OAc)3 | Te | IAc | Xe | ||
| CsOAc | Ba(OAc)2 | Hf | Ta | W | Re | Os | Ir | Pt(OAc)2 | Au | Hg2(OAc)2, Hg(OAc)2 |
TlOAc Tl(OAc)3 |
Pb(OAc)2 Pb(OAc)4 |
Bi(OAc)3 | Po | At | Rn | |||
| Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
| ↓ | |||||||||||||||||||
| La(OAc)3 | Ce(OAc)x | Pr | Nd | Pm | Sm(OAc)3 | Eu(OAc)3 | Gd(OAc)3 | Tb | Dy(OAc)3 | Ho(OAc)3 | Er | Tm | Yb(OAc)3 | Lu(OAc)3 | |||||
| Ac | Th | Pa | UO2(OAc)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||
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