Chemistry:Americium nitride
From HandWiki
| Names | |
|---|---|
| Other names
Americium mononitride, azanylidyneamericium
| |
| Identifiers | |
3D model (JSmol)
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| Properties | |
| AmN | |
| Molar mass | 257 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Americium nitride is a binary inorganic compound of americium and nitride with the chemical formula AmN.[1]
Preparation
Americium can be obtained from the reaction of metallic americium with nitrogen or ammonia at 750–800°C:[2]
- 2Am + N
2 → 2AmN - 2Am + 2NH
3 → 2AmN + 3H
2[3]
- 2Am + N
It can also be obtained from the reaction of americium trihydride (AmH
3) with nitrogen at 750 °C:[4]
- AmH
3 + N
2 → AmN + NH
3
- AmH
Chemical properties
Americium nitride reacts with cadmium chloride to form americium trichloride:[5]
- 2 AmN + 3 CdCl
2 → 2 AmCl
3 + Cd
3N
2
References
- ↑ Itoh, Akinori; Akabori, Mitsuo; Takano, Masahide; Itonaga, Torn Ogawa Masami Numata Fumio (November 2002). "Fabrication of Amerieium-based Nitrides by Carbothermic Reduction Method" (in en). Journal of Nuclear Science and Technology 39 (sup3): 737–740. doi:10.1080/00223131.2002.10875572. ISSN 0022-3131. https://www.tandfonline.com/doi/abs/10.1080/00223131.2002.10875572. Retrieved 5 February 2024.
- ↑ (in en) Advanced Inorganic Chemistry Vol-1. Krishna Prakashan Media. p. 357. ISBN 978-81-87224-03-7. https://books.google.com/books?id=0uwDTrxyaB8C&dq=americium+nitride+AmN&pg=PA357. Retrieved 5 February 2024.
- ↑ Ahrland, S.; Bagnall, K. W.; Brown, D. (7 June 2016) (in en). The Chemistry of the Actinides: Comprehensive Inorganic Chemistry. Elsevier. p. 344. ISBN 978-1-4831-5934-8. https://books.google.com/books?id=awRPDAAAQBAJ&dq=americium+nitride+AmN&pg=PA344. Retrieved 5 February 2024.
- ↑ Morss, L. R.; Edelstein, Norman M.; Fuger, Jean (31 December 2007) (in en). The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5). Springer Science & Business Media. p. 1317. ISBN 978-1-4020-3598-2. https://books.google.com/books?id=KyHyM0ObXrAC&dq=americium+nitride+AmN&pg=PA1317. Retrieved 5 February 2024.
- ↑ Hayashi, Hirokazu; Takano, Masahide; Akabori, Mitsuo; Minato, Kazuo (29 May 2008). "Synthesis of americium trichloride by the reaction of americium nitride with cadmium chloride". Journal of Alloys and Compounds 456 (1): 243–246. doi:10.1016/j.jallcom.2007.02.011. ISSN 0925-8388. https://www.sciencedirect.com/science/article/abs/pii/S0925838807003817. Retrieved 5 February 2024.
Salts and covalent derivatives of the nitride ion
| NH3 | He(N2)11 | ||||||||||||||||
| Li3N | Be3N2 | BN | β-C3N4 g-C3N4 |
N2 | NxOy | NF3 | Ne | ||||||||||
| Na3N | Mg3N2 | AlN | Si3N4 | PN P3N5 |
SxNy SN S4N4 |
NCl3 | Ar | ||||||||||
| K3N | Ca3N2 | ScN | TiN | VN | CrN Cr2N |
MnxNy | FexNy | CoN | Ni3N | CuN | Zn3N2 | GaN | Ge3N4 | As | Se | NBr3 | Kr |
| Rb3N | Sr3N2 | YN | ZrN | NbN | β-Mo2N | Tc | Ru | Rh | PdN | Ag3N | CdN | InN | Sn | Sb | Te | NI3 | Xe |
| Cs3N | Ba3N2 | Hf3N4 | TaN | WN | Re | Os | Ir | Pt | Au | Hg3N2 | TlN | Pb | BiN | Po | At | Rn | |
| Fr3N | Ra3N | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La | CeN | Pr | Nd | Pm | Sm | Eu | GdN | Tb | Dy | Ho | Er | Tm | Yb | Lu | |||
| Ac | Th | Pa | UN | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||
 |  |
