Chemistry:Gadolinium acetate
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| Names | |
|---|---|
| Other names
Gadolinium ethanoate
| |
| Identifiers | |
| Properties | |
| Gd(CH3COO)3 | |
| Appearance | colorless crystal or white powder |
| Density | 1.611 g·cm−3 (hydrate) |
| 9.7 g[clarification needed] | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Gadolinium acetate is the acetate salt of the lanthanide element gadolinium, with the chemical formula Gd(CH3COO)3. It is a colorless crystal that is soluble in water and can form a hydrate.[1] Its tetrahydrate has ground state ferromagnetism.[2]
Preparation
The tetrahydrate of gadolinium acetate can be crystallized from aqueous solution by reaction of gadolinium oxide and acetic acid:[2]
- Gd2O3 + 6 HOAc + 5 H2O → [(Gd(OAc)3(H2O)2)2]·4H2O
Properties
The complex [Gd4(CH3COO)4(acac)8(H2O)4] can be obtained by the reflux reaction of gadolinium acetate and acetylacetone in the presence of triethylamine in methanol solution.[3]
References
- ↑ Справочник химика. 2 (3-е изд., испр ed.). Л.: Химия. 1971.
- ↑ 2.0 2.1 Stephan T. Hatscher, Werner Urland (2003). "Unexpected Appearance of Molecular Ferromagnetism in the Ordinary Acetate [Gd(OAc)3(H2O)22⋅4 H2O"]. Angewandte Chemie International Edition 42 (25): 2862–2864. doi:10.1002/anie.200250738. ISSN 1521-3773. PMID 12833342. https://www.onlinelibrary.wiley.com/doi/abs/10.1002/anie.200250738. Retrieved 2019-02-01.
- ↑ Fu-Sheng Guo, Ji-Dong Leng, Jun-Liang Liu, Zhao-Sha Meng, Ming-Liang Tong (2012-01-02). "Polynuclear and Polymeric Gadolinium Acetate Derivatives with Large Magnetocaloric Effect". Inorganic Chemistry 51 (1): 405–413. doi:10.1021/ic2018314. ISSN 0020-1669. PMID 22145780. https://doi.org/10.1021/ic2018314. Retrieved 2019-02-01.
Acetyl halides and salts of the acetate ion
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|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| AcOH | He | ||||||||||||||||||
| LiOAc | Be(OAc)2 BeAcOH |
B(OAc)3 | AcOAc ROAc |
NH4OAc | AcOOH | FAc | Ne | ||||||||||||
| NaOAc | Mg(OAc)2 | Al(OAc)3 ALSOL Al(OAc)2OH Al2SO4(OAc)4 |
Si | P | S | ClAc | Ar | ||||||||||||
| KOAc | Ca(OAc)2 | Sc(OAc)3 | Ti(OAc)4 | VO(OAc)3 | Cr(OAc)2 Cr(OAc)3 |
Mn(OAc)2 Mn(OAc)3 |
Fe(OAc)2 Fe(OAc)3 |
Co(OAc)2, Co(OAc)3 |
Ni(OAc)2 | Cu(OAc)2 | Zn(OAc)2 | Ga(OAc)3 | Ge | As(OAc)3 | Se | BrAc | Kr | ||
| RbOAc | Sr(OAc)2 | Y(OAc)3 | Zr(OAc)4 | Nb | Mo(OAc)2 | Tc | Ru(OAc)2 Ru(OAc)3 Ru(OAc)4 |
Rh2(OAc)4 | Pd(OAc)2 | AgOAc | Cd(OAc)2 | In | Sn(OAc)2 Sn(OAc)4 |
Sb(OAc)3 | Te | IAc | Xe | ||
| CsOAc | Ba(OAc)2 | Hf | Ta | W | Re | Os | Ir | Pt(OAc)2 | Au | Hg2(OAc)2, Hg(OAc)2 |
TlOAc Tl(OAc)3 |
Pb(OAc)2 Pb(OAc)4 |
Bi(OAc)3 | Po | At | Rn | |||
| Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
| ↓ | |||||||||||||||||||
| La(OAc)3 | Ce(OAc)x | Pr | Nd | Pm | Sm(OAc)3 | Eu(OAc)3 | Gd(OAc)3 | Tb | Dy(OAc)3 | Ho(OAc)3 | Er | Tm | Yb(OAc)3 | Lu(OAc)3 | |||||
| Ac | Th | Pa | UO2(OAc)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||
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