Chemistry:Indium(II) selenide

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Indium(II) selenide
Identifiers
3D model (JSmol)
ChemSpider
Properties
InSe
Molar mass 193.789 g·mol−1
Melting point 611 °C (1,132 °F; 884 K) [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Indium (II) selenide (InSe) is an inorganic compound composed of indium and selenium. It is a III-VI layered semiconductor. The solid has a structure consisting of two-dimensional layers bonded together only by van der Waals forces. Each layer has the atoms in the order Se-In-In-Se.[2]

Potential applications are for field effect transistors, optoelectronics, photovoltaic, non-linear optics, strain gauges,[2] and methanol gas sensors.[3]

Formation

Indium (II) selenide can be formed via a number of different methods. A method to make the bulk solid is be the Bridgman/Stockbarger method, in which the elements indium and selenium are heated to over 900°C in a sealed capsule, and then slowly cooled over about a month.[4] Another method is electrodeposition from a water solution of indium(I) sulfate and selenium dioxide.[5]

Properties

Diagram of polytopes of indium (II) selenide from Danil W. Boukhvalov et al

There are three polytopes or crystal forms. β, ε are hexagonal with unit cells spanning two layers. γ has rhombohedral crystal system, with the unit cell including four layers.[2]

β-Indium (II) selenide can be exfoliated into two-dimensional sheets using sticky tape. In a vacuum these form smooth layers. However when exposed to air, the layers become corrugated because of chemisorption of air molecules.[6] Exfoliation can also take place in isopropanol liquid.[7]

Indium (II) selenide is stable in ambient conditions of oxygen and water vapour, unlike many other semiconductors.[2]

polytope space group unit cell band gap eV
β P63/mmc a=4.005 c=16.660 Z=4 direct 1.28
γ P61 a=7.1286 Å, c=19.382 Å and Z=6 direct 1.29
ε indirect 1.4

Doping

The properties of Indium (II) selenide can be varied by way of altering the exact ratio of elements from 1:1, creating vacancies. It is hard to get an exact equality. The properties can be compensated by transition element doping. Other elements that can be included in small concentrations are boron,[8] silver,[9] cadmium,[10]

References

  1. Teena, M.; Kunjomana, A. G. (April 2018). "Crystal shape engineering and studies on the performance of vapour deposited InSe platelets". Journal of Materials Science: Materials in Electronics 29 (7): 5536–5547. doi:10.1007/s10854-018-8522-5. 
  2. 2.0 2.1 2.2 2.3 Politano, A.; Campi, D.; Cattelan, M.; Ben Amara, I.; Jaziri, S.; Mazzotti, A.; Barinov, A.; Gürbulak, B. et al. (December 2017). "Indium selenide: an insight into electronic band structure and surface excitations". Scientific Reports 7 (1): 3445. doi:10.1038/s41598-017-03186-x. open access
  3. Marvan, Petr; Mazánek, Vlastimil; Sofer, Zdeněk (2019). "Shear-force exfoliation of indium and gallium chalcogenides for selective gas sensing applications". Nanoscale 11 (10): 4310–4317. doi:10.1039/C8NR09294J. 
  4. Boukhvalov, Danil; Gürbulak, Bekir; Duman, Songül; Wang, Lin; Politano, Antonio; Caputi, Lorenzo; Chiarello, Gennaro; Cupolillo, Anna (5 November 2017). "The Advent of Indium Selenide: Synthesis, Electronic Properties, Ambient Stability and Applications". Nanomaterials 7 (11): 372. doi:10.3390/nano7110372. 
  5. Demir, Kübra Çınar; Demir, Emre; Yüksel, Seniye; Coşkun, Cevdet (December 2019). "Influence of deposition conditions on nanostructured InSe thin films". Current Applied Physics 19 (12): 1404–1413. doi:10.1016/j.cap.2019.09.008. 
  6. Dmitriev, A. I.; Vishnjak, V. V.; Lashkarev, G. V.; Karbovskyi, V. L.; Kovaljuk, Z. D.; Bahtinov, A. P. (March 2011). "Investigation of the morphology of the van der Waals surface of the InSe single crystal". Physics of the Solid State 53 (3): 622–633. doi:10.1134/S1063783411030085. 
  7. Petroni, Elisa; Lago, Emanuele; Bellani, Sebastiano; Boukhvalov, Danil W.; Politano, Antonio; Gürbulak, Bekir; Duman, Songül; Prato, Mirko et al. (June 2018). "Liquid-Phase Exfoliated Indium-Selenide Flakes and Their Application in Hydrogen Evolution Reaction". Small 14 (26): 1800749. doi:10.1002/smll.201800749. 
  8. Ertap, Hüseyin; Karabulut, Mevlut (5 December 2018). "Structural and electrical properties of boron doped InSe single crystals". Materials Research Express 6 (3): 035901. doi:10.1088/2053-1591/aaf2f6. 
  9. Gürbulak, Bekir; Şata, Mehmet; Dogan, Seydi; Duman, Songul; Ashkhasi, Afsoun; Keskenler, E. Fahri (November 2014). "Structural characterizations and optical properties of InSe and InSe:Ag semiconductors grown by Bridgman/Stockbarger technique". Physica E: Low-dimensional Systems and Nanostructures 64: 106–111. doi:10.1016/j.physe.2014.07.002. 
  10. Evtodiev, Igor (2009). "Excitonic absorption of the light in heterojunctions Bi 2 O 3-InSe". http://dspace.usm.md:8080/xmlui/handle/123456789/1763.