Chemistry:Beryl

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Short description: Gemstone: beryllium aluminium silicate
Beryl
Beryl09.jpg
Three varieties of beryl (left to right): morganite, aquamarine and emerald
General
CategoryCyclosilicate
Formula
(repeating unit)		Be
3Al
2Si
6O
18
Strunz classification9.CJ.05
Crystal systemHexagonal
Crystal classDihexagonal dipyramidal (6/mmm)
H-M symbol: (6/m 2/m 2/m)
Space groupP6/mcc
Unit cella = 9.21 Å, c = 9.19 Å; Z = 2
Identification
Formula mass537.50 g/mol
ColorGreen, blue, yellow, colorless, pink, and others
Crystal habitPrismatic to tabular crystals; radial, columnar; granular to compact massive
TwinningRare
CleavageImperfect on {0001}
FractureConchoidal to irregular
TenacityBrittle
Mohs scale hardness7.5–8.0
|re|er}}Vitreous to resinous
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity2.63–2.92
Optical propertiesUniaxial (−)
Refractive indexnω = 1.564–1.595
nε = 1.568–1.602
Birefringenceδ = 0.0040–0.0070
PleochroismWeak to distinct
Ultraviolet fluorescenceNone (some fracture filling materials used to improve emerald's clarity do fluoresce, but the stone itself does not). Morganite has weak violet fluorescence.
References[1][2][3][4](p112)

Beryl (/ˈbɛrəl/ BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18.[6] Well-known varieties of beryl include emerald and aquamarine. Naturally occurring, hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.[7]

Main beryl producing countries

Etymology

The word beryl – Middle English: beril – is borrowed, via Old French: beryl and Latin: beryllus, from Ancient Greek βήρυλλος bḗryllos, which referred to a 'precious blue-green color-of-sea-water stone';[1] from Prakrit veruḷiya, veḷuriya 'beryl'[8][lower-alpha 1] which is ultimately of Dravidian origin, maybe from the name of Belur or Velur, a town in Karnataka, southern India .[9] The term was later adopted for the mineral beryl more exclusively.

When the first eyeglasses were constructed in 13th-century Italy, the lenses were made of beryl (or of rock crystal) as glass could not be made clear enough. Consequently, glasses were named Brillen in German[10] (bril in Dutch and briller in Danish).

Deposits

Beryl is a common mineral, and it is widely distributed in nature. It is found most commonly in granitic pegmatites, but also occurs in mica schists, such as those of the Ural Mountains, and in limestone in Colombia.[11] It is less common in ordinary granite and is only infrequently found in nepheline syenite. Beryl is often associated with tin and tungsten ore bodies formed as high-temperature hydrothermal veins. In granitic pegmatites, beryl is found in association with quartz, potassium feldspar, albite, muscovite, biotite, and tourmaline. Beryl is sometimes found in metasomatic contacts of igneous intrusions with gneiss, schist, or carbonate rocks.[12] Common beryl, mined as beryllium ore, is found in small deposits in many countries, but the main producers are Russia, Brazil, and the United States.[11]

New England's pegmatites have produced some of the largest beryls found, including one massive crystal from the Bumpus Quarry in Albany, Maine with dimensions 5.5 by 1.2 m (18.0 by 3.9 ft) with a mass of around 18 tonnes (20 short tons); it is New Hampshire's state mineral. (As of 1999), the world's largest known naturally occurring crystal of any mineral is a crystal of beryl from Malakialina, Madagascar, 18 m (59 ft) long and 3.5 m (11 ft) in diameter, and weighing 380,000 kg (840,000 lb).[13]

Crystal habit and structure

Beryl crystal structure with view down C axis
Beryl crystal structure with view down C axis

Beryl belongs to the hexagonal crystal system. Normally beryl forms hexagonal columns but can also occur in massive habits. As a cyclosilicate beryl incorporates rings of silicate tetrahedra of Si
6O
18 that are arranged in columns along the C axis and as parallel layers perpendicular to the C axis, forming channels along the C axis.[7] These channels permit a variety of ions, neutral atoms, and molecules to be incorporated into the crystal thus disrupting the overall charge of the crystal permitting further substitutions in aluminium, silicon, and beryllium sites in the crystal structure.[7] These impurities give rise to the variety of colors of beryl that can be found. Increasing alkali content within the silicate ring channels causes increases to the refractive indices and birefringence.[14]

Human health impact

Main pages: Medicine:Acute beryllium poisoning and Medicine:Berylliosis

Beryl is a beryllium compound that is a known carcinogen with acute toxic effects leading to pneumonitis when inhaled.[15] Care must thus be used when mining, handling, and refining these gems.[16]

Varieties

Aquamarine and maxixe

Main page: Chemistry:Aquamarine (gem)
Aquamarine

Aquamarine (from Latin: aqua marina, "sea water"[17]) is a blue or cyan variety of beryl. It occurs at most localities which yield ordinary beryl. The gem-gravel placer deposits of Sri Lanka contain aquamarine. Green-yellow beryl, such as that occurring in Brazil, is sometimes called chrysolite aquamarine.[18] The deep blue version of aquamarine is called maxixe[19] (pronounced mah-she-she).[20] Its color results from a radiation-induced color center.[21]

Faceted aquamarine

The pale blue color of aquamarine is attributed to Fe2+. Fe3+ ions produce golden-yellow color, and when both Fe2+ and Fe3+ are present, the color is a darker blue as in maxixe.[22][23] Decoloration of maxixe by light or heat thus may be due to the charge transfer between Fe3+ and Fe2+.[24]

In the United States, aquamarines can be found at the summit of Mount Antero in the Sawatch Range in central Colorado, and in the New England and North Carolina pegmatites.[25] Aquamarines are also present in the state of Wyoming, aquamarine has been discovered in the Big Horn Mountains, near Powder River Pass.[26] Another location within the United States is the Sawtooth Range near Stanley, Idaho, although the minerals are within a wilderness area which prevents collecting.[27] In Brazil, there are mines in the states of Minas Gerais,[25] Espírito Santo, and Bahia, and minorly in Rio Grande do Norte.[28] The mines of Colombia, Madagascar, Russia,[25] Namibia,[29] Zambia,[30] Malawi, Tanzania, and Kenya[31] also produce aquamarine.

Emerald

Main page: Chemistry:Emerald
Rough emerald on matrix

Emerald is green beryl, colored by around 2% chromium and sometimes vanadium.[32][33] Most emeralds are highly included, so their brittleness (resistance to breakage) is classified as generally poor.[34]

The modern English word "emerald" comes via Middle English emeraude, imported from modern French via Old French ésmeraude and Medieval Latin [esmaraldus] error: {{lang}}: unrecognized private tag: medieval (help), from Latin smaragdus, from Greek σμάραγδος smaragdos meaning 'green gem'.[lower-alpha 2]

Faceted emerald, 1.07 carats (0.214 g), Colombia

Emeralds in antiquity were mined by the Egyptians and in what is now Austria, as well as Swat in contemporary Pakistan .[36] A rare type of emerald known as a trapiche emerald is occasionally found in the mines of Colombia. A trapiche emerald exhibits a "star" pattern; it has raylike spokes of dark carbon impurities that give the emerald a six-pointed radial pattern. It is named for the trapiche, a grinding wheel used to process sugarcane in the region. Colombian emeralds are generally the most prized due to their transparency and fire. Some of the rarest emeralds come from the two main emerald belts in the Eastern Ranges of the Colombian Andes: Muzo and Coscuez west of the Altiplano Cundiboyacense, and Chivor and Somondoco to the east. Fine emeralds are also found in other countries, such as Zambia, Brazil , Zimbabwe, Madagascar , Pakistan , India , Afghanistan and Russia . In the US, emeralds can be found in Hiddenite, North Carolina. In 1998, emeralds were discovered in Yukon.

Emerald is a rare and valuable gemstone and, as such, it has provided the incentive for developing synthetic emeralds. Both hydrothermal[37] and flux-growth synthetics have been produced. The first commercially successful emerald synthesis process was that of Carroll Chatham.[38] The other large producer of flux emeralds was Pierre Gilson Sr., which has been on the market since 1964. Gilson's emeralds are usually grown on natural colorless beryl seeds which become coated on both sides. Growth occurs at the rate of 1 millimetre (0.039 in) per month, a typical seven-month growth run producing emerald crystals of 7 mm of thickness.[39] The green color of emeralds is widely attributed to presence of Cr3+ ions.[40][22][23] Intensely green beryls from Brazil, Zimbabwe and elsewhere in which the color is attributed to vanadium have also been sold and certified as emeralds.[41][42][43]

Golden beryl and heliodor

Faceted golden beryl, 48.75 carats (9.750 g), Brazil

Golden beryl can range in colors from pale yellow to a brilliant gold. Unlike emerald, golden beryl generally has very few flaws. The term "golden beryl" is sometimes synonymous with heliodor (from Greek hēlios – ἥλιος "sun" + dōron – δῶρον "gift") but golden beryl refers to pure yellow or golden yellow shades, while heliodor refers to the greenish-yellow shades. The golden yellow color is attributed to Fe3+ ions.[32][40] Both golden beryl and heliodor are used as gems. Probably the largest cut golden beryl is the flawless 2,054-carat (410.8 g) stone on display in the Hall of Gems, Washington, D.C., United States.[44]

Goshenite

Main page: Chemistry:Goshenite (gem)
Goshenite
Faceted goshenite, 1.88 carats (0.376 g), Brazil

Colorless beryl is called goshenite. The name originates from Goshen, Massachusetts, where it was originally discovered. In the past, goshenite was used for manufacturing eyeglasses and lenses owing to its transparency. Nowadays, it is most commonly used for gemstone purposes.[45][46]

The gem value of goshenite is relatively low. However, goshenite can be colored yellow, green, pink, blue and in intermediate colors by irradiating it with high-energy particles. The resulting color depends on the content of Ca, Sc, Ti, V, Fe, and Co impurities.[40]

Morganite

Main page: Chemistry:Morganite (gem)
Morganite
Faceted morganite, 2.01 carats (0.402 g), Brazil

Morganite, also known as "pink beryl", "rose beryl", "pink emerald" (which is not a legal term according to the new Federal Trade Commission Guidelines and Regulations), and "cesian (or caesian) beryl", is a rare light pink to rose-colored gem-quality variety of beryl. Orange/yellow varieties of morganite can also be found, and color banding is common. It can be routinely heat treated to remove patches of yellow and is occasionally treated by irradiation to improve its color. The pink color of morganite is attributed to Mn2+ ions.[32]

Red beryl

Main page: Chemistry:Red beryl
Red beryl

Red variety of beryl (the "bixbite") was first described in 1904 for an occurrence, its type locality, at Maynard's Claim (Pismire Knolls), Thomas Range, Juab County, Utah.[47][48] The dark red color is attributed to Mn3+ ions.[32] Old synonym "bixbite" is deprecated from the CIBJO because of the possibility of confusion with the mineral bixbyite (both named after mineralogist Maynard Bixby).[49] Red "bixbite" beryl formerly was marketed as "red" or "scarlet emerald", but these terms involving "Emerald" terminology are now prohibited in the US.[50]

Faceted red beryl, 0.56 carats (0.112 g), Utah, US

Red beryl is very rare and has only been reported from a handful of North American locations: Wah Wah Mountains, Beaver County, Utah; Paramount Canyon, Round Mountain, Juab County, Utah; and Sierra County, New Mexico, although this locality does not often produce gem-grade stones.[47] The bulk of gem-grade red beryl comes from the Ruby-Violet Claim in the Wah Wah Mts. of midwestern Utah, discovered in 1958 by Lamar Hodges, of Fillmore, Utah, while he was prospecting for uranium.[51] Red beryl has been known to be confused with pezzottaite, a caesium analog of beryl, found in Madagascar and, more recently, Afghanistan; cut gems of the two varieties can be distinguished by their difference in refractive index, and the rough crystals easily by their differing crystal systems (pezzottaite trigonal, red beryl hexagonal). Synthetic red beryl is also produced.[52] Like emerald and unlike most other varieties of beryl, the red ones are usually highly included.

While gem beryls are ordinarily found in pegmatites and certain metamorphic stones, red beryl occurs in topaz-bearing rhyolites.[53] It is formed by crystallizing under low pressure and high temperature from a pneumatolytic phase along fractures or within near-surface miarolitic cavities of the rhyolite. Associated minerals include bixbyite, quartz, orthoclase, topaz, spessartine, pseudobrookite and hematite.[48]

Footnotes

  1. ↑ Compare veruḷiya and veḷuriya to the pseudo-Sanskritization वैडूर्य vaiḍūrya, meaning either "cat's eye" (gem), generic "jewel", or "lapis lazuli" (gem). The folk etymology explains the gem name as meaning "[brought] from [the city of] Vidūra".[8]
  2. ↑ The Greek σμάραγδος (smaragdos) is used in the Semitic languages as אזמרגד , izmargad, as a loan-word meaning a precious emerald-colored stone. Greek smaragdos was used to translate the native Hebrew word ברקת, bareket, for one of the twelve listed stones in the Hoshen pectoral pendant of the Kohen HaGadol. The word bareket is also used to mean "lightning flash". It may be related to Akkadian baraqtu, which means "emerald". In turn the semetic language words are possibly related to the Sanskrit word मरकत marakata, meaning "green".[35][unreliable source?]

See also

References

  1. ↑ 1.0 1.1 "Beryl". http://www.mindat.org/min-819.html. 
  2. ↑ "Beryl Mineral Data". http://www.webmineral.com/data/Beryl.shtml. 
  3. ↑ "Beryl". Mineral Data Publishing. 2001. http://rruff.geo.arizona.edu/doclib/hom/beryl.pdf. 
  4. ↑ Schumann, Walter (2009). Gemstones of the World. Sterling Publishing Co.. ISBN 978-1-402-76829-3. https://books.google.com/books?id=V9PqVxpxeiEC. Retrieved 2018-05-22. 
  5. ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W. 
  6. ↑ "Beryl". https://www.minerals.net/mineral/beryl.aspx. 
  7. ↑ 7.0 7.1 7.2 Klein, Cornelis; Dutrow, Barbara; Dana, James Dwight (2007). The Manual of Mineral Science (after James D. Dana) (23rd ed.). Hoboken, N.J.: J. Wiley. ISBN 978-0-471-72157-4. OCLC 76798190. 
  8. ↑ 8.0 8.1 Skeat, Walter W. (1993). The Concise Dictionary of English Etymology. Wordsworth Editions. p. 36. ISBN 978-1-85326-311-8. https://books.google.com/books?id=aDhGlKL3h00C&pg=PA36. 
  9. ↑ "beryl". beryl. http://www.merriam-webster.com/dictionary/beryl. Retrieved January 27, 2014. 
  10. ↑ Kluge, Alexander, ed (1975). "Brillen". Brillen (21 ed.). 
  11. ↑ 11.0 11.1 Klein, Cornelis; Hurlbut, Cornelius S. Jr. (1993). Manual of Mineralogy (after James D. Dana) (21st ed.). New York: Wiley. p. 472. ISBN 0-471-57452-X. 
  12. ↑ Nesse, William D. (2000). Introduction to mineralogy. New York: Oxford University Press. p. 301. ISBN 978-0-19-510691-6. 
  13. ↑ G. Cressey and I. F. Mercer, (1999) Crystals, London, Natural History Museum, page 58
  14. ↑ Deer, W.A.; Howie, R.A.; Zussman, J. (2013). An introduction to the rock-forming minerals (Third ed.). London, UK. ISBN 978-0-903-05627-4. OCLC 858884283. 
  15. ↑ "Concise International Chemical Assessment Document 32, Beryllium and Beryllium compounds". http://www.inchem.org/documents/cicads/cicads/cicad32.htm. 
  16. ↑ "Hazardous Substance Fact Sheet: Beryl". New Jersey Department of Health and Human Services. April 2020. https://nj.gov/health/eoh/rtkweb/documents/fs/3080.pdf. 
  17. ↑ "aquamarine". aquamarine. https://www.merriam-webster.com/dictionary/aquamarine. Retrieved 2017-02-05. 
  18. ↑ Owens, George (1957). "The Amateur Lapidary". Rocks & Minerals 32 (9–10): 471. doi:10.1080/00357529.1957.11766963. 
  19. ↑ Grande, Lance; Augustyn, Allison (2009-11-15) (in en). Gems and Gemstones: Timeless Natural Beauty of the Mineral World. University of Chicago Press. p. 125. ISBN 978-0-226-30511-0. https://books.google.com/books?id=RnE9Fa4pbn0C&q=aquamarine. 
  20. ↑ Bradshaw, John J. (September 1, 2018). "Maxixe Beryl". https://www.gemguide.com/maxixe-beryl/. 
  21. ↑ Watkins, M.  (2002). Rediscovering Colors: A Study in Pollyanna Realism. Netherlands: Springer. p. 21. ISBN 978-1-4020-0737-8. 
  22. ↑ 22.0 22.1 Viana, R.R.; da Costa, G.M.; de Grave, E.; Stern, W.B.; Jordt-Evangelista, H. (2002). "Characterization of beryl (aquamarine variety) by Mössbauer spectroscopy". Physics and Chemistry of Minerals 29 (1): 78. doi:10.1007/s002690100210. Bibcode: 2002PCM....29...78V. 
  23. ↑ 23.0 23.1 Blak, Ana Regina; Isotani, Sadao; Watanabe, Shigueo (1983). "Optical absorption and electron spin resonance in blue and green natural beryl: A reply". Physics and Chemistry of Minerals 9 (6): 279. doi:10.1007/BF00309581. Bibcode: 1983PCM.....9..279B. 
  24. ↑ Andersson, Lars Olov (15 July 2019). "Comments on Beryl Colors and on Other Observations Regarding Iron-containing Beryls". The Canadian Mineralogist 57 (4): 551–566. doi:10.3749/canmin.1900021. 
  25. ↑ 25.0 25.1 25.2 Sinkankas, John (1964). Mineralogy for amateurs.. Princeton, N.J.: Van Nostrand. pp. 507–509. ISBN 0-442-27624-9. 
  26. ↑ Fritsch, E.; Shigley, J.E. (1989). "Contribution to the identification of treated colored diamonds: diamonds with peculiar color-zoned pavilions". The Quarterly Journal of the Gemological Institute of America 25 (2): 95–101. 
  27. ↑ Kiilsgaard, T.H.; Freeman, V.L.; Coffman, J.S. (1970). "Mineral resources of the Sawtooth Primitive Area, Idaho". U.S. Geological Survey Bulletin 1319-D: D-108. doi:10.3133/b1319D. 
  28. ↑ Cassedanne, J.; Philippo, Simon (2015). Minerals and Gem deposits of the eastern Brazilian pegmatites. Musée national d'histoire naturelle Luxembourg. pp. 139–206. https://www.researchgate.net/publication/313250718. Retrieved 15 April 2022. 
  29. ↑ Klein & Hurlbut 1993, p. 472.
  30. ↑ Carranza, E. J. M.; Woldai, T.; Chikambwe, E. M. (March 2005). "Application of Data-Driven Evidential Belief Functions to Prospectivity Mapping for Aquamarine-Bearing Pegmatites, Lundazi District, Zambia". Natural Resources Research 14 (1): 47–63. doi:10.1007/s11053-005-4678-9. 
  31. ↑ Yager, T.R. (2007). Minerals Yearbook. U.S. Geological Survey. pp. 22.1, 27.1, 39.3. https://books.google.com/books?id=IiMtBJI6sG0C. Retrieved 15 April 2022. 
  32. ↑ 32.0 32.1 32.2 32.3 "Color in the beryl group". California Institute of Technology. http://minerals.caltech.edu/FILES/Visible/BERYL/Index.htm. 
  33. ↑ Hurlbut, Cornelius S. Jr.; Kammerling, Robert C. (1991). Gemology. New York: John Wiley & Sons. p. 203. ISBN 978-0-471-42224-2. 
  34. ↑ "Emerald Quality Factors". Gemological Institute of America. https://www.gia.edu/emerald-quality-factor. 
  35. ↑ Fernie, W.T., M.D. (1906). Precious Stones for Curative Wear. John Wright. & Co.. 
  36. ↑ Giuliani, G.; Chaussidon, M.; Schubnel, H.J.; Piat, D.H.; Rollion-Bard, C.; France-Lanord, C.; Giard, D.; de Narvaez, D. et al. (2000). "Oxygen isotopes and emerald trade routes since antiquity". Science 287 (5453): 631–633. doi:10.1126/science.287.5453.631. PMID 10649992. Bibcode: 2000Sci...287..631G. 
  37. ↑ Hosaka, M. (1991). "Hydrothermal growth of gem stones and their characterization". Progress in Crystal Growth and Characterization of Materials 21 (1–4): 71. doi:10.1016/0960-8974(91)90008-Z. 
  38. ↑ "Carroll Chatham". The Gemology Project. http://gemologyproject.com/wiki/index.php?title=Carroll_Chatham. 
  39. ↑ Nassau, K. (1980). Gems Made by Man. Gemological Institute of America. ISBN 978-0-873-11016-7. 
  40. ↑ 40.0 40.1 40.2 Ibragimova, E.M.; Mukhamedshina, N.M.; Islamov, A.Kh. (2009). "Correlations between admixtures and color centers created upon irradiation of natural beryl crystals". Inorganic Materials 45 (2): 162. doi:10.1134/S0020168509020101. 
  41. ↑ Thomas, Arthur (2008). Gemstones: Properties, Identification and Use. London: New Holland. pp. 77–78. ISBN 978-1-845-37602-4. 
  42. ↑ Behmenburg, Christa; Conklin, Lawrence; Giuliani, Gaston; Glas, Maximilian; Gray, Patricia; Gray, Michael (January 2002). Giuliani, Gaston; Jarnot, Miranda; Neumeier, Gunther et al.. eds. Emeralds of the World. ExtraLapis. 2. East Hampton, CT: Lapis International. pp. 75–77. ISBN 978-0-971-53711-8. 
  43. ↑ Deer, W.A.; Zussman, J.; Howie, R.A. (1997). Disilicates and Ring Silicates. Rock-forming Minerals. 1B (2 ed.). Bath: Geological Society of London. pp. 393–394. ISBN 978-1-897-79989-5. 
  44. ↑ Thomas, Arthur (2007). Gemstones. New Holland Publishers. p. 77. ISBN 978-1-845-37602-4. https://books.google.com/books?id=MPZK8ILOSR0C&pg=PA77. [yes|permanent dead link|dead link}}]
  45. ↑ "Goshenite, the colorless variety of beryl". Amethyst Galleries. http://www.galleries.com/minerals/gemstone/goshenit/goshenit.htm. 
  46. ↑ "Goshenite Gem". March 2, 2009. http://opticalmineralogy.com/the-silicates-mineral-class/goshenite-gem/. 
  47. ↑ 47.0 47.1 "Red Beryl". http://www.mindat.org/min-690.html. 
  48. ↑ 48.0 48.1 Ege, Carl (September 2002). "What gemstone is found in Utah that is rarer than diamond and more valuable than gold?". Survey Notes 34 (3). http://geology.utah.gov/surveynotes/gladasked/gladberyl.htm. Retrieved 2011-07-02. 
  49. ↑ "The Mineral Beryl". http://www.minerals.net/mineral/beryl.aspx. 
  50. ↑ 16 C.F.R. 23.26
  51. ↑ "Red Emerald History". http://www.redemerald.com/history.html. 
  52. ↑ "Bixbite". http://www.gemstoneslist.com/bixbite.html. 
  53. ↑ "Red beryl value, price, and jewelry information". International Gem Society. https://www.gemsociety.org/article/red-beryl-jewelry-and-gemstone-information/. 

Further reading

External links

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