Chemistry:Thulium nitride
From HandWiki
| Names | |
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| IUPAC name
azanylidynethulium
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| Other names
Thulium mononitride
Thulium(III) nitride | |
| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| EC Number |
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PubChem CID
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| Properties | |
| NTm | |
| Molar mass | 182.937 |
| Density | 9.321 g/cm3 |
| Related compounds | |
Other anions
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TmP TmAs |
Other cations
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ErN YbN |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Thulium nitride is a binary inorganic compound of thulium and nitrogen with the chemical formula TmN. It can be prepared by reacting thulium amalgam with nitrogen at high temperature.[1]
Physical properties
Thulium nitride crystallises cubic system with Fm3m space group. It has a sodium chloride structure.[2][3]
Chemical properties
It reacts with Tm2In at 1220 K to form (Tm3N)In.[4]
References
- ↑ B. Magyar. Preparation of rare earth nitrides from amalgams. Inorganic Chemistry. 1968 7 (7), 1457-1458 doi:10.1021/ic50065a041
- ↑ Panwar, Yeshvir Singh; Aynyas, Mahendra; Tejraj, M. K.; Sanyal, S. P. (2014). "Pressure Induced Structural and Electronic Properties of Thulium Nitride" (in en). Advanced Materials Research 1047: 147–150. doi:10.4028/www.scientific.net/AMR.1047.147. ISSN 1662-8985. https://www.scientific.net/AMR.1047.147.
- ↑ "Magnetic Characteristics of Gadolinium, Praseodymium, and Thulium Nitrides". https://pubs.aip.org/aip/jap/article-abstract/36/3/984/695732/Magnetic-Characteristics-of-Gadolinium.
- ↑ Martin Kirchner, Walter Schnelle, Frank R. Wagner, Rainer Niewa. Preparation, crystal structure and physical properties of ternary compounds (R3N)In, R=rare-earth metal. Solid State Sciences, 2003. 1247-1257. doi:10.1016/S1293-2558(03)00151-1
Salts and covalent derivatives of the nitride ion
| NH3 | He(N2)11 | ||||||||||||||||
| Li3N | Be3N2 | BN | β-C3N4 g-C3N4 |
N2 | NxOy | NF3 | Ne | ||||||||||
| Na3N | Mg3N2 | AlN | Si3N4 | PN P3N5 |
SxNy SN S4N4 |
NCl3 | Ar | ||||||||||
| K3N | Ca3N2 | ScN | TiN | VN | CrN Cr2N |
MnxNy | FexNy | CoN | Ni3N | CuN | Zn3N2 | GaN | Ge3N4 | As | Se | NBr3 | Kr |
| Rb3N | Sr3N2 | YN | ZrN | NbN | β-Mo2N | Tc | Ru | Rh | PdN | Ag3N | CdN | InN | Sn | Sb | Te | NI3 | Xe |
| Cs3N | Ba3N2 | Hf3N4 | TaN | WN | Re | Os | Ir | Pt | Au | Hg3N2 | TlN | Pb | BiN | Po | At | Rn | |
| Fr3N | Ra3N | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La | CeN | Pr | Nd | Pm | Sm | Eu | GdN | Tb | Dy | Ho | Er | Tm | Yb | Lu | |||
| Ac | Th | Pa | UN | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||
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