Chemistry:Period 7 element
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A period 7 element is one of the chemical elements in the seventh row (or period) of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behavior of the elements as their atomic number increases: a new row is begun when chemical behavior begins to repeat, meaning that elements with similar behavior fall into the same vertical columns. The seventh period contains 32 elements, tied for the most with period 6, beginning with francium and ending with oganesson, the heaviest element currently discovered. As a rule, period 7 elements fill their 7s shells first, then their 5f, 6d, and 7p shells in that order, but there are exceptions, such as uranium.
Properties
All elements of period 7 are radioactive. This period contains the actinides, which includes plutonium, the naturally occurring element with the heaviest nucleus;[1] subsequent elements must be created artificially. While the first five of these synthetic elements (americium through einsteinium) are now available in macroscopic quantities, most are extremely rare, having only been prepared in microgram amounts or less. The later transactinide elements have only been identified in laboratories in batches of a few atoms at a time.
Although the rarity of many of these elements means that experimental results are not very extensive, their periodic and group trends are less well defined than other periods. Whilst francium and radium do show typical properties of their respective groups, actinides display a much greater variety of behavior and oxidation states than the lanthanides. These peculiarities are due to a variety of factors, including a large degree of spin–orbit coupling and relativistic effects, ultimately caused by the very high positive electrical charge from their massive atomic nuclei. Periodicity mostly holds throughout the 6d series and is predicted also for moscovium and livermorium, but the other four 7p elements, nihonium, flerovium, tennessine, and oganesson, are predicted to have very different properties from those expected for their groups.
Elements
Chemical element Block Electron configuration Occurrence 87 Fr Francium s-block [Rn] 7s1 From decay 88 Ra Radium s-block [Rn] 7s2 From decay 89 Ac Actinium f-block [Rn] 6d1 7s2 (*) From decay 90 Th Thorium f-block [Rn] 6d2 7s2 (*) Primordial 91 Pa Protactinium f-block [Rn] 5f2 6d1 7s2 (*) From decay 92 U Uranium f-block [Rn] 5f3 6d1 7s2 (*) Primordial 93 Np Neptunium f-block [Rn] 5f4 6d1 7s2 (*) From decay 94 Pu Plutonium f-block [Rn] 5f6 7s2 From decay 95 Am Americium f-block [Rn] 5f7 7s2 Synthetic 96 Cm Curium f-block [Rn] 5f7 6d1 7s2 (*) Synthetic 97 Bk Berkelium f-block [Rn] 5f9 7s2 Synthetic 98 Cf Californium f-block [Rn] 5f10 7s2 Synthetic 99 Es Einsteinium f-block [Rn] 5f11 7s2 Synthetic 100 Fm Fermium f-block [Rn] 5f12 7s2 Synthetic 101 Md Mendelevium f-block [Rn] 5f13 7s2 Synthetic 102 No Nobelium f-block [Rn] 5f14 7s2 Synthetic 103 Lr Lawrencium d-block [Rn] 5f14 7s2 7p1 (*) Synthetic 104 Rf Rutherfordium d-block [Rn] 5f14 6d2 7s2 Synthetic 105 Db Dubnium d-block [Rn] 5f14 6d3 7s2 Synthetic 106 Sg Seaborgium d-block [Rn] 5f14 6d4 7s2 Synthetic 107 Bh Bohrium d-block [Rn] 5f14 6d5 7s2 Synthetic 108 Hs Hassium d-block [Rn] 5f14 6d6 7s2 Synthetic 109 Mt Meitnerium d-block [Rn] 5f14 6d7 7s2 (?) Synthetic 110 Ds Darmstadtium d-block [Rn] 5f14 6d8 7s2 (?) Synthetic 111 Rg Roentgenium d-block [Rn] 5f14 6d9 7s2 (?) Synthetic 112 Cn Copernicium d-block [Rn] 5f14 6d10 7s2 (?) Synthetic 113 Nh Nihonium p-block [Rn] 5f14 6d10 7s2 7p1 (?) Synthetic 114 Fl Flerovium p-block [Rn] 5f14 6d10 7s2 7p2 (?) Synthetic 115 Mc Moscovium p-block [Rn] 5f14 6d10 7s2 7p3 (?) Synthetic 116 Lv Livermorium p-block [Rn] 5f14 6d10 7s2 7p4 (?) Synthetic 117 Ts Tennessine p-block [Rn] 5f14 6d10 7s2 7p5 (?) Synthetic 118 Og Oganesson p-block [Rn] 5f14 6d10 7s2 7p6 (?) Synthetic
(?) Prediction
(*) Exception to the Madelung rule.
In many periodic tables, the f-block is erroneously shifted one element to the right, so that lanthanum and actinium become d-block elements, and Ce–Lu and Th–Lr form the f-block tearing the d-block into two very uneven portions. This is a holdover from early erroneous measurements of electron configurations.[2] Lev Landau and Evgeny Lifshitz pointed out in 1948 that lutetium is not an f-block element,[3] and since then physical, chemical, and electronic evidence has overwhelmingly supported that the f-block contains the elements La–Yb and Ac–No,[2][4] as shown here and as supported by International Union of Pure and Applied Chemistry reports dating from 1988[4] and 2021.[5]
S-block
Francium and radium make up the s-block elements of the 7th period.
Francium (Fr, atomic number 87) is a highly radioactive metal that decays into astatine, radium, and radon. It is one of the two least electronegative elements, the other being caesium. As an alkali metal, it has one valence electron. Francium was discovered by Marguerite Perey in France (from which the element takes its name) in 1939.[6] It was the last element discovered in nature, rather than by synthesis.[note 1] Outside the laboratory, francium is extremely rare, with trace amounts found in uranium and thorium ores, where the isotope francium-223 continually forms and decays. As little as 20–30 g (one ounce) exists at any given time throughout Earth's crust; the other isotopes are entirely synthetic. The largest amount produced in the laboratory was a cluster of more than 300,000 atoms.[7]
Radium (Ra, atomic number 88) is an almost pure-white alkaline earth metal, but it readily oxidizes, reacting with nitrogen (rather than oxygen) on exposure to air, becoming black in color. All isotopes of radium are highly radioactive; the most stable isotope is radium-226, which has a half-life of 1601 years and decays into radon gas. Because of such instability, radium is luminescent, glowing a faint blue. Radium, in the form of radium chloride, was discovered by Marie and Pierre Curie in 1898. They extracted the radium compound from uraninite and published the discovery at the French Academy of Sciences five days later. Radium was isolated in its metallic state by Marie Curie and André-Louis Debierne through the electrolysis of radium chloride in 1910. Since its discovery, it has given names such as radium A and radium C2 to several isotopes of other elements that are decay products of radium-226. In nature, radium is found in uranium ores in trace amounts as small as a seventh of a gram per ton of uraninite. Radium is not necessary for living organisms, and adverse health effects are likely when it is incorporated into biochemical processes because of its radioactivity and chemical reactivity.
Actinides
The actinide or actinoid (IUPAC nomenclature) series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium.[9][10][11][12]
The actinide series is named after its first element actinium. All but one of the actinides are f-block elements, corresponding to the filling of the 5f electron shell; lawrencium, a d-block element, is also generally considered an actinide. In comparison with the lanthanides, also mostly f-block elements, the actinides show much more variable valence.
Of the actinides, thorium and uranium occur naturally in substantial, primordial, quantities. Radioactive decay of uranium produces transient amounts of actinium, protactinium and plutonium, and atoms of neptunium are occasionally produced from transmutation reactions in uranium ores. The other actinides are purely synthetic elements, though the first six actinides after plutonium would have been produced at Oklo (and long since decayed away), and curium almost certainly previously existed in nature as an extinct radionuclide.[9][13] Nuclear tests have released at least six actinides heavier than plutonium into the environment; analysis of debris from a 1952 hydrogen bomb explosion showed the presence of americium, curium, berkelium, californium, einsteinium and fermium.[14]
All actinides are radioactive and release energy upon radioactive decay; naturally occurring uranium and thorium, and synthetically produced plutonium are the most abundant actinides on Earth. These are used in nuclear reactors and nuclear weapons. Uranium and thorium also have diverse current or historical uses, and americium is used in the ionization chambers of most modern smoke detectors.
In presentations of the periodic table, the lanthanides and the actinides are customarily shown as two additional rows below the main body of the table,[9] with placeholders or else a selected single element of each series (either lanthanum or lutetium, and either actinium or lawrencium, respectively) shown in a single cell of the main table, between barium and hafnium, and radium and rutherfordium, respectively. This convention is entirely a matter of aesthetics and formatting practicality; a rarely used wide-formatted periodic table (32 columns) shows the lanthanide and actinide series in their proper columns, as parts of the table's sixth and seventh rows (periods).
Transactinides
Transactinide elements (also, transactinides, or super-heavy elements) are the chemical elements with atomic numbers greater than those of the actinides, the heaviest of which is lawrencium (103).[15][16] All transactinides of period 7 have been discovered, up to oganesson (element 118).
Transactinide elements are also transuranic elements, that is, have an atomic number greater than that of uranium (92), an actinide. The further distinction of having an atomic number greater than the actinides is significant in several ways:
- The transactinide elements all have electrons in the 6d subshell in their ground state (and thus are placed in the d-block).
- Even the longest-lasting isotopes of many transactinide elements have extremely short half-lives, measured in seconds or smaller units.
- The element naming controversy involved the first five or six transactinide elements. These elements thus used three-letter systematic names for many years after their discovery had been confirmed. (Usually, the three-letter symbols are replaced with two-letter symbols relatively shortly after a discovery has been confirmed.)
Transactinides are radioactive and have only been obtained synthetically in laboratories. None of these elements has ever been collected in a macroscopic sample. Transactinide elements are all named after nuclear physicists and chemists or important locations involved in the synthesis of the elements.
Chemistry Nobel Prize winner Glenn T. Seaborg, who first proposed the actinide concept which led to the acceptance of the actinide series, also proposed the existence of a transactinide series ranging from element 104 to 121 and a superactinide series approximately spanning elements 122 to 153. The transactinide seaborgium is named in his honor.
IUPAC defines an element to exist if its lifetime is longer than 10−14 seconds, the time needed for the nucleus to form an electronic cloud.[17]
Notes
- ↑ Some elements discovered through synthesis, such as technetium, have later been found in nature.
References
- ↑ "Periodic Table – Royal Society of Chemistry". https://www.rsc.org/periodic-table/.
- ↑ 2.0 2.1 William B. Jensen (1982). "The Positions of Lanthanum (Actinium) and Lutetium (Lawrencium) in the Periodic Table". J. Chem. Educ. 59 (8): 634–636. doi:10.1021/ed059p634. Bibcode: 1982JChEd..59..634J.
- ↑ L. D. Landau, E. M. Lifshitz (1958). Quantum Mechanics: Non-Relativistic Theory. 3 (1st ed.). Pergamon Press. pp. 256–7.
- ↑ 4.0 4.1 Fluck, E. (1988). "New Notations in the Periodic Table". Pure Appl. Chem. 60 (3): 431–436. doi:10.1351/pac198860030431. https://www.iupac.org/publications/pac/1988/pdf/6003x0431.pdf. Retrieved 24 March 2012.
- ↑ Scerri, Eric (18 January 2021). "Provisional Report on Discussions on Group 3 of the Periodic Table". Chemistry International 43 (1): 31–34. doi:10.1515/ci-2021-0115. https://iupac.org/wp-content/uploads/2021/04/ChemInt_Jan2021_PP.pdf. Retrieved 9 April 2021.
- ↑ "Francium | Radioactive, Alkali Metal, Rare | Britannica" (in en). https://www.britannica.com/science/francium.
- ↑ Luis A. Orozco (2003). "Francium". Chemical and Engineering News. http://pubs.acs.org/cen/80th/francium.html.
- ↑ The Manhattan Project. An Interactive History. US Department of Energy
- ↑ 9.0 9.1 9.2 Gray, Theodore (2009). The Elements: A Visual Exploration of Every Known Atom in the Universe. New York: Black Dog & Leventhal Publishers. p. 240. ISBN 978-1-57912-814-2. https://archive.org/details/elementsvisualex0000gray/page/240.
- ↑ Actinide element, Encyclopædia Britannica on-line
- ↑ Although "actinoid" (rather than "actinide") means "actinium-like" and therefore should exclude actinium, that element is usually included in the series.
- ↑ Connelly, Neil G. (2005). "Elements". Nomenclature of Inorganic Chemistry. London: Royal Society of Chemistry. p. 52. ISBN 978-0-85404-438-2. https://books.google.com/books?id=w1Kf1CakyZIC&pg=PA52.
- ↑ Greenwood, p. 1250
- ↑ Fields, P.; Studier, M.; Diamond, H.; Mech, J.; Inghram, M.; Pyle, G.; Stevens, C.; Fried, S. et al. (1956). "Transplutonium Elements in Thermonuclear Test Debris". Physical Review 102 (1): 180. doi:10.1103/PhysRev.102.180. Bibcode: 1956PhRv..102..180F.
- ↑ IUPAC Provisional Recommendations for the Nomenclature of Inorganic Chemistry (2004) (online draft of an updated version of the "Red Book" IR 3–6)
- ↑ Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean, eds (2006). The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer. ISBN 978-1-4020-3555-5.
- ↑ "Kernchemie". http://www.kernchemie.de/Transactinides/Transactinide-2/transactinide-2.html.
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