Physics:Isotopes of neptunium

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Template:Infobox neptunium isotopes Neptunium (93Np) is usually considered an artificial element, although trace quantities are found in nature, so a standard atomic weight cannot be given. Like all trace or artificial elements, it has no stable isotopes. The first isotope to be synthesized and identified was 239Np in 1940, produced by bombarding The element Chemistry:Uranium does not exist. with neutrons to produce The element Chemistry:Uranium does not exist., which then underwent beta decay to The element Chemistry:Neptunium does not exist..

Trace quantities are found in nature from neutron capture reactions by uranium atoms, a fact not discovered until 1951.[1]

Twenty-five neptunium radioisotopes have been characterized, with the most stable being The element Chemistry:Neptunium does not exist. with a half-life of 2.144 million years, The element Chemistry:Neptunium does not exist. with a half-life of 153,000 years, and The element Chemistry:Neptunium does not exist. with a half-life of 396.1 days. All of the remaining radioactive isotopes have half-lives that are less than 4.5 days, and the majority of these have half-lives that are less than 50 minutes. This element also has five meta states, with the most stable being The element Chemistry:Neptunium does not exist. (t1/2 22.5 hours).

The isotopes of neptunium range from The element Chemistry:Neptunium does not exist. to The element Chemistry:Neptunium does not exist., though the intermediate isotope The element Chemistry:Neptunium does not exist. has not yet been observed. The primary decay mode for nuclei lighter than the most stable isotope, The element Chemistry:Neptunium does not exist., is electron capture (and also alpha emission), and the primary mode after is beta emission. The primary decay products for nuclei lighter than The element Chemistry:Neptunium does not exist. are isotopes of uranium and protactinium, and the primary products after are isotopes of plutonium. Neptunium is the heaviest element for which the location of the proton drip line is known; the lightest proton-bound isotope is 220Np.[2]

List of isotopes


Nuclide
[n 1] 		Z N Isotopic mass (u)
[n 2][n 3] 		Half-life
 Decay
mode
[n 4] 		Daughter
isotope
[n 5] 		Spin and
parity
[n 6][n 7] 		Isotopic
abundance
Excitation energy[n 7]
The element Chemistry:Neptunium does not exist.[n 8] 93 126 219.031602(99) 570(450) μs α 215Pa 9/2−#
The element Chemistry:Neptunium does not exist.[2] 127 220.032716(33) 25+14
−7 μs 		α 216Pa 1−#
The element Chemistry:Neptunium does not exist. 129 222.033575(41) 480(190) ns α 218Pa 1−#
The element Chemistry:Neptunium does not exist. 130 223.032913(89) 2.5(8) μs α 219Pa (9/2−)
The element Chemistry:Neptunium does not exist.[4] 131 224.034388(31) 38+26
−11 μs 		α (83%) 220m1Pa 2−#
α (17%) 220m2Pa
The element Chemistry:Neptunium does not exist. 132 225.033943(98) 6.5(35) ms α 221Pa 9/2−#
The element Chemistry:Neptunium does not exist. 133 226.03523(11) 35(10) ms α 222Pa
The element Chemistry:Neptunium does not exist. 134 227.034975(83) 510(60) ms α 223Pa 5/2+#
The element Chemistry:Neptunium does not exist. 135 228.03631(11)# 61.4(14) s EC (59%) 228U 4+#
α (41%) 224Pa
β+, SF (0.0126%) (various)
The element Chemistry:Neptunium does not exist. 136 229.03629(11) 4.00(18) min α (68%) 225Pa 5/2+#
β+ (32%) 229U
The element Chemistry:Neptunium does not exist. 137 230.037828(59) 4.6(3) min β+ (>97%) 230U 4+#
α (<3%) 226Pa
The element Chemistry:Neptunium does not exist. 138 231.038244(55) 48.8(2) min β+ (98%) 231U 5/2+#
α (2%) 227Pa
The element Chemistry:Neptunium does not exist. 139 232.04011(11)# 14.7(3) min β+ 232U (5−)
The element Chemistry:Neptunium does not exist. 140 233.040739(55) 36.2(1) min β+ 233U 5/2+#
α (0.0007%) 229Pa
The element Chemistry:Neptunium does not exist. 141 234.0428932(90) 4.4(1) d β+ 234U (0+)
The element Chemistry:Neptunium does not exist.[5] ~9 min IT 234Np 5+
EC 234U
The element Chemistry:Neptunium does not exist. 142 235.0440615(15) 396.1(12) d EC 235U 5/2+
α (0.00260%) 231Pa
The element Chemistry:Neptunium does not exist.[n 9] 143 236.046568(54) 1.53(5)×105 y EC (86.3%) 236U (6−)
β− (13.5%) 236Pu
α (0.16%) 232Pa
The element Chemistry:Neptunium does not exist.[n 10] 60(50) keV 22.5(4) h EC (50%) 236U (1−)
β− (50%) 236Pu
The element Chemistry:Neptunium does not exist. 144 237.0481716(12) 2.144(7)×106 y α 233Pa 5/2+ Trace[n 11]
SF (<2×10−10%) (various)
CD (<4×10−12%) 207Tl
30Mg
The element Chemistry:Neptunium does not exist. 945.20(10) keV 710(40) ns IT 237Np 13/2−
The element Chemistry:Neptunium does not exist. 145 238.0509446(12) 2.099(2) d β− 238Pu 2+
The element Chemistry:Neptunium does not exist. 2300(200)# keV 112(39) ns SF (various)
The element Chemistry:Neptunium does not exist. 146 239.0529375(14) 2.356(3) d β− 239Pu 5/2+ Trace[n 11]
The element Chemistry:Neptunium does not exist. 147 240.056164(18) 61.9(2) min β− 240Pu (5+) Trace[n 12]
The element Chemistry:Neptunium does not exist. 18(14) keV 7.22(2) min β− (99.88%) 240Pu (1+) Trace[n 12]
IT (0.12%) 240Np
The element Chemistry:Neptunium does not exist. 148 241.058349(33)[6] 13.9(2) min β− 241Pu (5/2+)
The element Chemistry:Neptunium does not exist. 149 242.061738(87)[6] 2.2(2) min β− 242Pu (1+)
The element Chemistry:Neptunium does not exist.[n 10] 50(50)# keV 5.5(1) min β− 242Pu (6+)
The element Chemistry:Neptunium does not exist. 150 243.064204(34)# 1.85(15) min β− 243Pu 5/2+#
The element Chemistry:Neptunium does not exist. 151 244.06789(11)# 2.29(16) min β− 244Pu 7−#
  1. ↑ mNp – Excited nuclear isomer.
  2. ↑ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. ↑ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. ↑ Modes of decay:
    CD: Cluster decay
    EC: Electron capture
    IT: Isomeric transition
    SF: Spontaneous fission
  5. ↑ Bold italics symbol as daughter – Daughter product is nearly stable.
  6. ↑ ( ) spin value – Indicates spin with weak assignment arguments.
  7. ↑ 7.0 7.1 # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  8. ↑ Heaviest known nucleus, as of 2025, that is beyond the proton drip line.[3]
  9. ↑ Fissile nuclide
  10. ↑ 10.0 10.1 Order of ground state and isomer is uncertain.
  11. ↑ 11.0 11.1 Produced by neutron capture in uranium ore
  12. ↑ 12.0 12.1 Intermediate decay product of 244Pu

Actinides vs fission products

Actinides and fission products by half-life v · d · e
Actinides[7] by decay chain Half-life
range (y) 		Fission products of 235U by yield<ref>Specifically from thermal neutron fission of U-235, e.g. in a typical nuclear reactor.</ref>
4n 4n+1 4n+2 4n+3
4.5–7% 0.04–1.25% <0.001%
228Ra№ 4–6 † 155Euþ
244Cmƒ 241Puƒ 250Cf 227Ac№ 10–29 90Sr 85Kr 113mCdþ
232Uƒ 238Puƒ 243Cmƒ 29–97 137Cs 151Smþ 121mSn
248Bk[8] 249Cfƒ 242mAmƒ 141–351

No fission products
have a half-life
in the range of
100–210 k years ...

241Amƒ 251Cfƒ[9] 430–900
226Ra№ 247Bk 1.3 k – 1.6 k
240Pu 229Th 246Cmƒ 243Amƒ 4.7 k – 7.4 k
245Cmƒ 250Cm 8.3 k – 8.5 k
239Puƒ 24.1 k
230Th№ 231Pa№ 32 k – 76 k
236Npƒ 233Uƒ 234U№ 150 k – 250 k ‡ 99Tc₡ 126Sn
248Cm 242Pu 327 k – 375 k 79Se₡
1.53 M 93Zr
237Npƒ 2.1 M – 6.5 M 135Cs₡ 107Pd
236U 247Cmƒ 15 M – 24 M 129I₡
244Pu 80 M

... nor beyond 15.7 M years[10]

232Th№ 238U№ 235Uƒ№ 0.7 G – 14.1 G

Legend for superscript symbols
₡  has thermal neutron capture cross section in the range of 8–50 barns
ƒ  fissile
m  metastable isomer
№  primarily a naturally occurring radioactive material (NORM)
þ  neutron poison (thermal neutron capture cross section greater than 3k barns)
†  range 4–97 y: Medium-lived fission product
‡  over 200,000 y: Long-lived fission product

Notable isotopes

Neptunium-235

Neptunium-235 has 142 neutrons and a half-life of 396.1 days. This isotope decays by:

Neptunium-236

Neptunium-236 has 143 neutrons and a half-life of 153,000 years. It can decay by the following methods:

  • Electron capture: the decay energy is 0.93 MeV and the decay product is uranium-236. This usually decays (with a half-life of 23 million years) to thorium-232.
  • Beta emission: the decay energy is 0.48 MeV and the decay product is plutonium-236. This usually decays (half-life 2.8 years) to uranium-232, which usually decays (half-life 69 years) to thorium-228, which decays in a few years to lead-208.
  • Alpha emission: the decay energy is 5.007 MeV and the decay product is protactinium-232. This decays with a half-life of 1.3 days to uranium-232.

Neptunium-236 is a fissile material; it has an estimated critical mass of 6.79 kg (15.0 lb),[11] though precise experimental data is not available[12] (as sufficient material for criticality is not).The element Chemistry:Neptunium does not exist. is produced in small quantities via the (n,2n) and (γ,n) capture reactions of The element Chemistry:Neptunium does not exist.,[13] however, it is nearly impossible to separate in any significant quantities from its parent The element Chemistry:Neptunium does not exist..[14] It is for this reason that despite its low critical mass and high neutron cross section, it has not been researched extensively as a nuclear fuel in weapons or reactors.[12] Nevertheless, The element Chemistry:Neptunium does not exist. has been considered for use in mass spectrometry and as a radioactive tracer, because it decays predominantly by beta emission with a long half-life.[15] Several alternative production routes for this isotope have been investigated, namely those that reduce isotopic separation from The element Chemistry:Neptunium does not exist. or the isomer The element Chemistry:Neptunium does not exist.. The most favorable reactions to accumulate The element Chemistry:Neptunium does not exist. were shown to be proton and deuteron irradiation of uranium-238.[15]

Neptunium-237

Neptunium-237 decay scheme (simplified)

The element Chemistry:Neptunium does not exist. decays via the neptunium series, which terminates with thallium-205, which is stable, unlike most other actinides, which decay to stable isotopes of lead. Until the discovery of its alpha decay (with an extremely long half-life), the series was thought to end with bismuth-209.

In 2002, The element Chemistry:Neptunium does not exist. was shown to be capable of sustaining a chain reaction with fast neutrons, as in a nuclear weapon, with a critical mass of around 60 kg.[16] However, it has a low probability of fission on bombardment with thermal neutrons, which makes it unsuitable as a fuel for light water nuclear power plants (as opposed to fast reactor or accelerator-driven systems, for example).

Inventory in spent nuclear fuel

The element Chemistry:Neptunium does not exist. is the only neptunium isotope produced in significant quantity in the nuclear fuel cycle, both by successive neutron capture by uranium-235 (which fissions most but not all of the time) and uranium-236, or (n,2n) reactions where a fast neutron occasionally knocks a neutron loose from uranium-238 or isotopes of plutonium. Over the long term, The element Chemistry:Neptunium does not exist. also forms in spent nuclear fuel as the decay product of americium-241.The element Chemistry:Neptunium does not exist. is considered to be one of the most mobile radionuclides at the site of the Yucca Mountain nuclear waste repository (Nevada) where oxidizing conditions prevail in the unsaturated zone of the volcanic tuff above the water table.

Raw material for 238Pu production

When exposed to neutron bombardment The element Chemistry:Neptunium does not exist. can capture a neutron, undergo beta decay, and become The element Chemistry:Plutonium does not exist., this product being useful as a thermal energy source in a radioisotope thermoelectric generator (RTG or RITEG) for the production of electricity and heat. The first type of thermoelectric generator SNAP (Systems for Nuclear Auxiliary Power) was developed and used by NASA in the 1960's and during the Apollo missions to power the instruments left on the Moon surface by the astronauts. Thermoelectric generators were also embarked on board of deep space probes such as for the Pioneer 10 and 11 missions, the Voyager program, the Cassini–Huygens mission, and New Horizons. They also deliver electrical and thermal power to the Mars Science Laboratory (Curiosity rover) and Mars 2020 mission (Perseverance rover) both exploring the cold surface of Mars. Curiosity and Perseverance rovers are both equipped with the last version of multi-mission RTG, a more efficient and standardized system dubbed MMRTG.

These applications are economically practical where photovoltaic power sources are weak or inconsistent due to probes being too far from the sun or rovers facing climate events that may obstruct sunlight for long periods (like Martian dust storms). Space probes and rovers also make use of the heat output of the generator to keep their instruments and internals warm.[17]

Shortage of 237Np stockpiles

The long half-life (88 years) of The element Chemistry:Plutonium does not exist. and the absence of γ-radiation that could interfere with the operation of on-board electronic components, or irradiate people, makes it the radionuclide of choice for electric thermogenerators.The element Chemistry:Neptunium does not exist. is therefore a key radionuclide for the production of The element Chemistry:Plutonium does not exist., which is essential for deep space probes requiring a reliable and long-lasting source of energy without maintenance.

Stockpiles of The element Chemistry:Plutonium does not exist. built up in the United States since the Manhattan Project, thanks to the Hanford nuclear complex (operating in Washington State from 1943 to 1977) and the Savannah River Site(operating in South Carolina from 1950 to 1988) the development of atomic weapons, are now almost exhausted. The extraction and purification of sufficient new quantities of The element Chemistry:Neptunium does not exist. from irradiated nuclear fuels is therefore necessary for the resumption of The element Chemistry:Plutonium does not exist. production in order to replenish the stocks needed for space exploration by robotic probes.

Neptunium-239

Neptunium-239 has 146 neutrons and a half-life of 2.356 days. It is produced via β− decay of the short-lived uranium-239, and undergoes another β− decay to plutonium-239. This is the primary route for making plutonium, as 239U can be made by neutron capture in uranium-238.[18]

Uranium-237 and neptunium-239 are regarded as the leading hazardous radioisotopes in the first hour-to-week period following nuclear fallout from a nuclear detonation, with 239Np dominating "the spectrum for several days".[19][20]

References

  1. ↑ Peppard, D. F.; Mason, G. W.; Gray, P. R.; Mech, J. F. (1952). "Occurrence of the (4n + 1) series in nature". Journal of the American Chemical Society 74 (23): 6081–6084. doi:10.1021/ja01143a074. Bibcode: 1952JAChS..74.6081P. https://digital.library.unt.edu/ark:/67531/metadc172698/m2/1/high_res_d/metadc172698.pdf. 
  2. ↑ 2.0 2.1 Zhang, Z. Y.; Gan, Z. G.; Yang, H. B. et al. (2019). "New isotope 220Np: Probing the robustness of the N = 126 shell closure in neptunium". Physical Review Letters 122 (19). doi:10.1103/PhysRevLett.122.192503. PMID 31144958. Bibcode: 2019PhRvL.122s2503Z. 
  3. ↑ Yang, HExpression error: Unrecognized word "et". (2018). "Alpha decay properties of the semi-magic nucleus 219Np". Physics Letters B 777: 212–216. doi:10.1016/j.physletb.2017.12.017. Bibcode: 2018PhLB..777..212Y. https://www.researchgate.net/publication/321843830. 
  4. ↑ Huang, T. H. (2018). "Identification of the new isotope 224Np" (pdf). Physical Review C 98 (4). doi:10.1103/PhysRevC.98.044302. Bibcode: 2018PhRvC..98d4302H. https://www.researchgate.net/publication/328038265. 
  5. ↑ Asai, M.Expression error: Unrecognized word "et". (2020) (in Japanese). Discovery of 234 Np isomer and its decay properties (Report). http://www.radiochem.org/jnrs-abst/pdf/64-501.pdf. 
  6. ↑ 6.0 6.1 Niwase, T.; Watanabe, Y. X.; Hirayama, Y. et al. (2023). "Discovery of New Isotope 241U and Systematic High-Precision Atomic Mass Measurements of Neutron-Rich Pa-Pu Nuclei Produced via Multinucleon Transfer Reactions". Physical Review Letters 130 (13): 132502-1–132502-6. doi:10.1103/PhysRevLett.130.132502. PMID 37067317. https://eprints.whiterose.ac.uk/197980/1/PhysRevLett.130.132502.pdf. 
  7. ↑ Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
  8. ↑ Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics 71 (2): 299. doi:10.1016/0029-5582(65)90719-4. Bibcode: 1965NucPh..71..299M. 
    "The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk248 with a half-life greater than 9 y. No growth of Cf248 was detected, and a lower limit for the β− half-life can be set at about 104 y. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 y."
  9. ↑ This is the heaviest nuclide with a half-life of at least four years before the "Sea of Instability".
  10. ↑ Excluding those "classically stable" nuclides with half-lives significantly in excess of 232Th; e.g., while 113mCd has a half-life of only fourteen years, that of 113Cd is nearly eight quadrillion years.
  11. ↑ Final Report, Evaluation of nuclear criticality safety data and limits for actinides in transport (Report). Republic of France, Institut de Radioprotection et de Sûreté Nucléaire, Département de Prévention et d'étude des Accidents.. http://ec.europa.eu/energy/nuclear/transport/doc/irsn_sect03_146.pdf. 
  12. ↑ 12.0 12.1 Reed, B. C. (2017). "An examination of the potential fission-bomb weaponizability of nuclides other than 235U and 239Pu". American Journal of Physics 85 (1): 38–44. doi:10.1119/1.4966630. Bibcode: 2017AmJPh..85...38R. 
  13. ↑ Analysis of the Reuse of Uranium Recovered from the Reprocessing of Commercial LWR Spent Fuel, United States Department of Energy, Oak Ridge National Laboratory.
  14. ↑ **Jukka Lehto; Xiaolin Hou (2011). "15.15: Neptunium". Chemistry and Analysis of Radionuclides (1st ed.). John Wiley & Sons. p. 231. ISBN 978-3-527-63302-9. 
  15. ↑ 15.0 15.1 Jerome, S.M.; Ivanov, P.; Larijani, C.; Parker, D.J.; Regan, P.H. (2014). "The production of Neptunium-236g". Journal of Environmental Radioactivity 138: 315–322. doi:10.1016/j.jenvrad.2014.02.029. PMID 24731718. Bibcode: 2014JEnvR.138..315J. 
  16. ↑ P. Weiss (26 October 2002). "Neptunium Nukes? Little-studied metal goes critical". Science News 162 (17): 259. doi:10.2307/4014034. http://www.sciencenews.org/view/generic/id/3246/title/Neptunium_Nukes%3F_Little-studied_metal_goes_critical. Retrieved 7 November 2013. 
  17. ↑ Witze, Alexandra (2014-11-27). "Nuclear power: Desperately seeking plutonium" (in en). Nature 515 (7528): 484–486. doi:10.1038/515484a. PMID 25428482. Bibcode: 2014Natur.515..484W. 
  18. ↑ "Periodic Table Of Elements: LANL - Neptunium". Los Alamos National Laboratory. https://periodic.lanl.gov/93.shtml. 
  19. ↑ [Film Badge Dosimetry in Atmospheric Nuclear Tests, By Committee on Film Badge Dosimetry in Atmospheric Nuclear Tests, Commission on Engineering and Technical Systems, Division on Engineering and Physical Sciences, National Research Council. pg24-35]
  20. ↑ Bounding Analysis of Effects of Fractionation of Radionuclides in Fallout on Estimation of Doses to Atomic Veterans DTRA-TR-07-5. 2007

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