Chemistry:Potassium hexafluororhenate

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Potassium hexafluororhenate
Names
IUPAC name
dipotassium; hexafluoro rhenium(2-)
Other names
Potassium hexafluororhenate(IV), dipotassium hexafluororhenate
Identifiers
3D model (JSmol)
Properties
F6K2Re
Molar mass 378.394 g·mol−1
Appearance pale pink crystals
Density 4.33 g/cm3[1]
Hazards
GHS pictograms GHS07: Harmful
GHS Signal word Warning
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Potassium hexafluororhenate is an inorganic chemical compound with the chemical formula K
2
ReF
6
.[2]

Synthesis

The compound can be prepared by reacting K
2
ReI
6
with potassium fluoride, hydrogen iodide mixture.[3]

Also it can be formed by reacting K
2
ReI
6
or K
2
ReCl
6
with KHF2.[4]

Physical properties

The compound forms pale pink crystals of the trigonal system, space group P3m1.[5][1] The crystals are of K
2
GeF
6
-type.[6]

References

  1. 1.0 1.1 "K2ReF6: mp-7824". Materials Project. https://legacy.materialsproject.org/materials/mp-7824/. 
  2. Burgess, J.; Morton, N.; Peacock, R.D. (March 1978). "Enthalpies of solution of potassium hexafluororhenate(IV) and of potassium hexafluororuthenate(IV); single ion hydration enthalpies of the hexafluororhenate(IV) and hexafluororuthenate(IV) anions". Journal of Fluorine Chemistry 11 (3–4): 197–202. doi:10.1016/s0022-1139(00)82440-9. Bibcode1978JFluC..11..197B. https://colab.ws/articles/10.1016%2Fs0022-1139%2800%2982440-9. Retrieved 28 August 2024. 
  3. Macintyre, Jane E. (23 July 1992) (in en). Dictionary of Inorganic Compounds. CRC Press. p. 3230. ISBN 978-0-412-30120-9. https://books.google.com/books?id=9eJvoNCSCRMC&dq=Potassium+hexafluororhenate&pg=PA3230. Retrieved 28 August 2024. 
  4. Kemmitt, R. D. W.; Peacock, R. D. (6 June 2016) (in en). The Chemistry of Manganese, Technetium and Rhenium: Pergamon Texts in Inorganic Chemistry. Elsevier. p. 969. ISBN 978-1-4831-3806-0. https://books.google.com/books?id=79U_DQAAQBAJ&dq=Potassium+hexafluororhenate&pg=PA969. Retrieved 28 August 2024. 
  5. Donnay, Joseph Désiré Hubert (1973) (in en). Crystal Data: Inorganic compounds. National Bureau of Standards. p. H-62. https://books.google.com/books?id=5lVCBwmZsLYC&dq=Potassium+hexafluororhenate&pg=RA5-PA62. Retrieved 28 August 2024. 
  6. Clark, G. R.; Russell, D. R. (15 March 1978). "Potassium hexafluororhenate(IV)" (in en). Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry 34 (3): 894–895. doi:10.1107/S0567740878004264. ISSN 0567-7408. Bibcode1978AcCrB..34..894C. https://journals.iucr.org/paper?S0567740878004264. Retrieved 28 August 2024.