Chemistry:Potassium hexafluororhenate
From HandWiki
| Names | |
|---|---|
| IUPAC name
dipotassium; hexafluoro rhenium(2-)
| |
| Other names
Potassium hexafluororhenate(IV), dipotassium hexafluororhenate
| |
| Identifiers | |
3D model (JSmol)
|
|
| |
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| Properties | |
| F6K2Re | |
| Molar mass | 378.394 g·mol−1 |
| Appearance | pale pink crystals |
| Density | 4.33 g/cm3[1] |
| Hazards | |
| GHS pictograms | |
| GHS Signal word | Warning |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Potassium hexafluororhenate is an inorganic chemical compound with the chemical formula K
2ReF
6.[2]
Synthesis
The compound can be prepared by reacting K
2ReI
6 with potassium fluoride, hydrogen iodide mixture.[3]
Also it can be formed by reacting K
2ReI
6 or K
2ReCl
6 with KHF2.[4]
Physical properties
The compound forms pale pink crystals of the trigonal system, space group P3m1.[5][1] The crystals are of K
2GeF
6-type.[6]
References
- ↑ 1.0 1.1 "K2ReF6: mp-7824". Materials Project. https://legacy.materialsproject.org/materials/mp-7824/.
- ↑ Burgess, J.; Morton, N.; Peacock, R.D. (March 1978). "Enthalpies of solution of potassium hexafluororhenate(IV) and of potassium hexafluororuthenate(IV); single ion hydration enthalpies of the hexafluororhenate(IV) and hexafluororuthenate(IV) anions". Journal of Fluorine Chemistry 11 (3–4): 197–202. doi:10.1016/s0022-1139(00)82440-9. Bibcode: 1978JFluC..11..197B. https://colab.ws/articles/10.1016%2Fs0022-1139%2800%2982440-9. Retrieved 28 August 2024.
- ↑ Macintyre, Jane E. (23 July 1992) (in en). Dictionary of Inorganic Compounds. CRC Press. p. 3230. ISBN 978-0-412-30120-9. https://books.google.com/books?id=9eJvoNCSCRMC&dq=Potassium+hexafluororhenate&pg=PA3230. Retrieved 28 August 2024.
- ↑ Kemmitt, R. D. W.; Peacock, R. D. (6 June 2016) (in en). The Chemistry of Manganese, Technetium and Rhenium: Pergamon Texts in Inorganic Chemistry. Elsevier. p. 969. ISBN 978-1-4831-3806-0. https://books.google.com/books?id=79U_DQAAQBAJ&dq=Potassium+hexafluororhenate&pg=PA969. Retrieved 28 August 2024.
- ↑ Donnay, Joseph Désiré Hubert (1973) (in en). Crystal Data: Inorganic compounds. National Bureau of Standards. p. H-62. https://books.google.com/books?id=5lVCBwmZsLYC&dq=Potassium+hexafluororhenate&pg=RA5-PA62. Retrieved 28 August 2024.
- ↑ Clark, G. R.; Russell, D. R. (15 March 1978). "Potassium hexafluororhenate(IV)" (in en). Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry 34 (3): 894–895. doi:10.1107/S0567740878004264. ISSN 0567-7408. Bibcode: 1978AcCrB..34..894C. https://journals.iucr.org/paper?S0567740878004264. Retrieved 28 August 2024.
