Chemistry:Iodide hydride

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Iodide hydrides are mixed anion compounds containing hydride and iodide anions. Many iodide hydrides are cluster compounds, containing a hydrogen atom in a core, surrounded by a layer of metal atoms, encased in a shell of iodide.

List

formula system space group unit cell Å volume density comment reference
(DippNacnac)Mg(μ-H)(μ-I)Mg(MesNacnac)
KHI [1][2]
[LZnI(η2-H)]2 (L=1,3-bis(2,6-diisopropylphenyl)inidazole-2-ylidine [3]
Sr2H3I trigonal P3m1 a = 4.260 c = 7.749 Z=1 121.77 4.16 transparent [4]
YIH C=31.033 metallic [5]
YIH2 P3m1 a = 3.8579, c = 10.997 light green [5]
Nb6I11H D10/2h a = 11.317; b = 15.471 ; c = 13.431 [6]
Nb6I11H Im3m a = 11.317; b = 15.471 ; c = 13.431 black [6]
Nb6(H)I9S triclinic P1 a = 10.340, b = 11.554, c = 10.181, α = 104.31°, β = 113.50°, γ = 105.48° Z=2 [7][8]
HCsNb6I11 [9]
Ba2H3I trigonal P3m1 a= 4.519 c= 8.1184 transparent [10]
Ba5H2I4O2 orthorhombic Cmcm a =17.210, b = 14.525 c = 6.3903 Z=4 1597.44 5.11 transparent [4]
LaI2H hexagonal P63/mmc a=4.2158 c=15.508 [11][12]
NdI2H [13]
Gd2ICH0.73 P63mc a=3.8128 C=14.844 Z=2 8.071 [14]
Eu2H3I dark red [15]
Eu5H2O2I4 orthorhombic Cmcm a = 16.3697, b = 13.6954, c = 6.0436, Z = 4 dark red [15]
Tb2ICH [14]
DyI2H [13]
[(η5-C5H5)W(NO)IH]2 [16]
(η5-C5H5)W(NO)I(H)(P(OPh)3)
Ir(η2-H2)(H)2I(PiPr3)2 [17][18]
Ir(η2-H2)(H)2I(PiPr3)2•C10H8 triclinic P1 a=7.999 b=13.981 c=14.561 α=82.49° β=84.39° γ=71.70° Z=2 15K [18]

References

  1. ↑ Mills, R (November 2001). "Minimum heat of formation of potassium iodo hydride". International Journal of Hydrogen Energy 26 (11): 1199–1208. doi:10.1016/S0360-3199(01)00051-9. https://linkinghub.elsevier.com/retrieve/pii/S0360319901000519. 
  2. ↑ Mills, R (December 2000). "Synthesis and characterization of potassium iodo hydride" (in en). International Journal of Hydrogen Energy 25 (12): 1185–1203. doi:10.1016/S0360-3199(00)00037-9. https://linkinghub.elsevier.com/retrieve/pii/S0360319900000379. 
  3. ↑ Lummis, Paul Ashley (2015). Earth-Abundant Transition Metal Hydride Complexes for Dehydrocoupling and Hydrosilylation Catalysis. University of Alberta. 
  4. ↑ 4.0 4.1 Reckeweg, Olaf; DiSalvo, Francis J. (2011-01-01). "AlkalineEarthMetal-Hydride-Iodide Compounds: Syntheses andCrystal Structures of Sr 2 H 3 I and Ba 5 H 2 I 3.9(2) O 2" (in en). Zeitschrift für Naturforschung B 66 (1): 21–26. doi:10.1515/znb-2011-0104. ISSN 1865-7117. 
  5. ↑ 5.0 5.1 Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (August 2004). "YIH n : A New Family of Metal-rich Hydride Halides" (in en). Zeitschrift für anorganische und allgemeine Chemie 630 (10): 1401–1407. doi:10.1002/zaac.200400094. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200400094. 
  6. ↑ 6.0 6.1 Simon, Arndt (December 1967). "Beiträge zur Chemie der Elemente Niob und Tantal. LXV. HNb6J11 Eine Verbindung mit der komplexen Gruppe [HNb6J8]". Zeitschrift für anorganische und allgemeine Chemie 355 (5–6): 311–322. doi:10.1002/zaac.19673550511. 
  7. ↑ Meyer, H. Juergen; Corbett, John D. (October 1992). "Theoretical study of the electronic properties of niobium iodide sulfide (Nb6I9S) and its hydride (Nb6(H)I9S)" (in en). Inorganic Chemistry 31 (21): 4276–4280. doi:10.1021/ic00047a013. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic00047a013. 
  8. ↑ Meyer, H. Juergen; Corbett, John D. (March 1991). "Synthesis and structure of the novel chain compound niobium iodide sulfide (Nb6I9S) and its hydride" (in en). Inorganic Chemistry 30 (5): 963–967. doi:10.1021/ic00005a017. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic00005a017. 
  9. ↑ Simon, Arndt (March 1985). "Empty, filled, and condensed metal clusters" (in en). Journal of Solid State Chemistry 57 (1): 2–16. doi:10.1016/S0022-4596(85)80055-4. Bibcode: 1985JSSCh..57....2S. https://linkinghub.elsevier.com/retrieve/pii/S0022459685800554. 
  10. ↑ Reckeweg, Olaf; DiSalvo, Francis J. (2011-11-01). "Filling up another Gap: Synthesis and Crystal Structure of Ba 2 H 3 I" (in en). Zeitschrift für Naturforschung B 66 (11): 1087–1091. doi:10.1515/znb-2011-1101. ISSN 1865-7117. 
  11. ↑ Imoto, Hideo; Corbett, John D. (February 1981). "Lanthanum and neodymium diiodide hydride phases and their hydrogen dissociation pressures" (in en). Inorganic Chemistry 20 (2): 630–633. doi:10.1021/ic50216a062. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic50216a062. 
  12. ↑ Ryazanov, M; Simon, A; Mattausch, Hj; Kremer, R.K (July 2004). "The structural change of lanthanum diiodide upon hydrogenation" (in en). Journal of Alloys and Compounds 374 (1–2): 142–145. doi:10.1016/j.jallcom.2003.11.072. https://linkinghub.elsevier.com/retrieve/pii/S0925838803012921. 
  13. ↑ 13.0 13.1 Bochkarev, M. N.; Logunov, A. A.; Burin, M. E. (October 2007). "Synthesis and some properties of neodymium(III) and dysprosium(III) iodide hydrides LnI2H" (in en). Russian Chemical Bulletin 56 (10): 1953–1955. doi:10.1007/s11172-007-0303-x. ISSN 1066-5285. http://link.springer.com/10.1007/s11172-007-0303-x. 
  14. ↑ 14.0 14.1 Ruck, M.; Simon, A. (November 1992). "Ln2XCHy: Kondensierte Cluster mit zwei verschiedenen interstitiellen Atomen" (in de). Zeitschrift für anorganische und allgemeine Chemie 617 (11): 7–18. doi:10.1002/zaac.19926170102. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19926170102. 
  15. ↑ 15.0 15.1 Rudolph, Daniel; Wylezich, Thomas; Netzsch, Philip; Blaschkowski, Björn; Höppe, Henning A.; Goldner, Philippe; Kunkel, Nathalie; Hoslauer, Jean-Louis et al. (2023-10-07). "Synthesis and Crystal Structure of the Europium(II) Hydride Oxide Iodide Eu5H2O2I4 Showing Blue-Green Luminescence" (in en). International Journal of Molecular Sciences 24 (19): 14969. doi:10.3390/ijms241914969. ISSN 1422-0067. PMID 37834417. 
  16. ↑ Oxley, Jimmie Carol (20 April 1978). Nitrosyl Hydrides and Cations of Group VI Transition Metals. California State University Northridge. 
  17. ↑ Bau, Robert; Drabnis, Mary H. (June 1997). "Structures of transition metal hydrides determined by neutron diffraction" (in en). Inorganica Chimica Acta 259 (1–2): 27–50. doi:10.1016/S0020-1693(97)89125-6. https://linkinghub.elsevier.com/retrieve/pii/S0020169397891256. 
  18. ↑ 18.0 18.1 Eckert, Juergen; Jensen, Craig M.; Koetzle, Thomas F.; Husebo, Trang Le; Nicol, Jacqueline; Wu, Ping (July 1995). "Inelastic Neutron Scattering Studies of IrIH2(H2)(PPri3)2 and Neutron Diffraction Structure Determination of IrIH2(H2)(PPri3)2•C10H8: Implications on the Mechanism of the Interconversion of Dihydrogen and Hydride Ligands". Journal of the American Chemical Society 117 (27): 7271–7272. doi:10.1021/ja00132a038. 
HI He
LiI BeI2 BI3 CI4 NI3 I2O4,
I2O5,
I4O9 		IF,
IF3,
IF5,
IF7 		Ne
NaI MgI2 AlI3 SiI4 PI3,
P2I4 		S ICl,
ICl3 		Ar
KI CaI2 Sc TiI4 VI3 CrI3 MnI2 FeI2 CoI2 NiI2 CuI ZnI2 Ga2I6 GeI2,
GeI4 		AsI3 Se IBr Kr
RbI SrI2 YI3 ZrI4 NbI5 Mo Tc Ru Rh Pd AgI CdI2 InI3 SnI4,
SnI2 		SbI3 TeI4 I Xe
CsI BaI2   HfI4 TaI5 W Re Os Ir Pt AuI Hg2I2,
HgI2 		TlI PbI2 BiI3 Po AtI Rn
Fr RaI2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La Ce Pr Nd Pm SmI2 Eu Gd TbI3 Dy Ho Er Tm Yb Lu
Ac ThI4 Pa UI3,
UI4 		Np Pu Am Cm Bk Cf EsI3 Fm Md No Lr



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