Chemistry:Antimonide iodide
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Short description: Class of chemical compounds
Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictide halides. Related compounds include the antimonide chlorides, antimonide bromides, phosphide iodides, and arsenide iodides.
List
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
| Ge38Sb8I8 | cubic | Pm3n | a=10.8892 | clathrate; band gap 1.16 eV; thermal conductivity 7 mWcm−1K−1 | [1] | ||
| Cd4Sb2I3 | cubic | Pa3 | a=13.48 | [2] | |||
| Sn38Sb8I8 | cubic | Pm3n | a=12.0447 | clathrate; band gap 0.80 eV; thermal conductivity 12mWcm−1K−1 | [1] | ||
| La2SbI2 | rhombohedral | a=4.530 c=32.80 | [3] | ||||
| Hg5Sb2I6 | orthorhombic | Pc21n | a=8.108, b=10.702, c=21.295 | 1847.7 | 7.217 | Dark red | [4] |
| (Hg6Sb4)(CdI6) | rhombohedral | R3c | a = 13.3818, α = 90.93°, | 2395.3 | 7.111 | black | [5] |
| (Hg6Sb4)(CdI6)Hg0.6 | cubic | Pa3 | a=13.234 | 2317.7 | 7.604 | black; band gap 1.23; air stable | [6] |
| [Hg6Sb4I3](SnI3)Hg0.16 | cubic | P213 | a=13.285 Z=4 | [7] |
References
- ↑ 1.0 1.1 Kishimoto, Kengo; Arimura, Shuntaro; Koyanagi, Tsuyoshi (2006-05-29). "Preparation and thermoelectric properties of sintered iodine-containing clathrate compounds Ge38Sb8I8 and Sn38Sb8I8" (in en). Applied Physics Letters 88 (22): 222115. doi:10.1063/1.2209207. ISSN 0003-6951. Bibcode: 2006ApPhL..88v2115K. http://aip.scitation.org/doi/10.1063/1.2209207.
- ↑ Roy, Anand; Suchitra; Manjunath, K.; Ahmad, Tokeer; Waghmare, Umesh V.; Rao, C.N.R. (April 2017). "Electronic structure and properties of Cd 4 As 2 Br 3 and Cd 4 Sb 2 I 3 , analogues of CdSe and CdTe" (in en). Solid State Communications 255-256: 5–10. doi:10.1016/j.ssc.2017.03.001. Bibcode: 2017SSCom.255....5R. https://linkinghub.elsevier.com/retrieve/pii/S0038109817300765.
- ↑ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds" (in en). Zeitschrift für Naturforschung B 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-2007-1105/html.
- ↑ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (February 1994). "Synthesis and Crystal Structure of Hg5Sb2I6" (in de). Zeitschrift für anorganische und allgemeine Chemie 620 (2): 389–392. doi:10.1002/zaac.19946200232. ISSN 0044-2313.
- ↑ Zou, Jian-Ping; Li, Yan; Zhang; Guo; Liu, Xi; Wang, Ming-Sheng; Cai, Li-Zhen; Lu, Ying-Bing et al. (2007-09-01). "Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg 6 Sb 4 )(CdI 6 )" (in en). Inorganic Chemistry 46 (18): 7321–7325. doi:10.1021/ic0624165. ISSN 0020-1669. PMID 17665902. https://pubs.acs.org/doi/10.1021/ic0624165.
- ↑ Zou, Jian‐Ping; Li, Yan; Fu, Ming‐Lai; Guo, Guo‐Cong; Xu, Gang; Liu, Xue‐Hui; Zhou, Wei‐Wei; Huang, Jin‐Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 (MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)"] (in en). European Journal of Inorganic Chemistry 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200600894.
- ↑ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.
| HI | He | ||||||||||||||||
| LiI | BeI2 | BI3 | CI4 | NI3 | I2O4, I2O5, I4O9 |
IF, IF3, IF5, IF7 |
Ne | ||||||||||
| NaI | MgI2 | AlI3 | SiI4 | PI3, P2I4 |
S | ICl, ICl3 |
Ar | ||||||||||
| KI | CaI2 | Sc | TiI4 | VI3 | CrI3 | MnI2 | FeI2 | CoI2 | NiI2 | CuI | ZnI2 | Ga2I6 | GeI2, GeI4 |
AsI3 | Se | IBr | Kr |
| RbI | SrI2 | YI3 | ZrI4 | NbI5 | Mo | Tc | Ru | Rh | Pd | AgI | CdI2 | InI3 | SnI4, SnI2 |
SbI3 | TeI4 | I | Xe |
| CsI | BaI2 | HfI4 | TaI5 | W | Re | Os | Ir | Pt | AuI | Hg2I2, HgI2 |
TlI | PbI2 | BiI3 | Po | AtI | Rn | |
| Fr | RaI2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La | Ce | Pr | Nd | Pm | SmI2 | Eu | Gd | TbI3 | Dy | Ho | Er | Tm | Yb | Lu | |||
| Ac | ThI4 | Pa | UI3, UI4 |
Np | Pu | Am | Cm | Bk | Cf | EsI3 | Fm | Md | No | Lr | |||
 |  |
