Chemistry:Arsenide iodide
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Short description: Class of chemical compounds
Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide bromides, phosphide iodides, and antimonide iodides.
List
formula | system | space group | unit cell Å | volume | density | comment | ref |
---|---|---|---|---|---|---|---|
Ca2AsI | trigonal | R3m | a=4.397, c = 22.29, Z = 3 | 3.76 | brown | [1][2] | |
Ca3AsI3 | cubic | I4132 | a=12.42 | 3.99 | colourless | [1] | |
Cu2P1.8As1.2I2 | monoclinic | P21/c | a = 15.477, b = 13.200, c = 15.421, β = 115.406°, Z = 16 | Cu exchangeable with Ag; band gap 1.2 eV | [3] | ||
Ge38As8I8 | cubic | P43m | a=10.611 | metallic; water and air stable | [4] | ||
Ag2P1.8As1.2I2 | monoclinic | P21/c | a = 15.84, b = 13.68, c = 15.58 and β = 117.63° Z=16 | [5] | |||
Sn24As19.3I8 | cubic | a=22.179 Z=8 | black | [6] | |||
Sn20.5□3.5As22I8 | cubic | a=22.1837 | low thermal conductivity | [7] | |||
Sn24AsxP19.3−xI8 x=0-16 | cubic | Pm3n | a = 10.9358—11.1495 | [8] | |||
Sn19.3Cu4.7As22I8 | cubic | Pm3n | a = 11.1736 Z = 1 | 1394.4 | 6.236 | clathrate; Zintl; diamagnetic | [9] |
Sn24–x–δInxAs22–yI8 | cubic | Pm3n | a = 11.088 (x = 0) to a = 11.343 (x = 10.7) | clathrate | [10] | ||
La2AsI2 | trigonal | P3m1 | a=4.3795 c=10.910 | 5.56 | [11] | ||
Hg4AsI5 | orthorhombic | Cmca | a=11.927 b=12.128 c=19.776 Z=8 | 2859.0 | 7.025 | red | [12] |
Hg4As2I3 | cubic | Pa3 | a=12.999 Z=8 | 2196 | 8.06 | black | [13] |
HgI2⋅As4S4 | monoclinic | P21/c | a=9.433 b=14.986 c=11.624 β=127.72° Z=4 | 1299 | 4.509 | orange; dec 212 °C | [14] |
Hg5AsS2I3 | monoclinic | C2/c | a=13.339 b=8.444 c=13.428 β=118.352 Z=4 | 1331.2 | 7.599 | black; dec 150 °C | [15] |
Hg3AsSe4I | hexagonal | P63mc | a = 7.6902, c = 9.968 Z=2 | red; air stable | [16] | ||
[Hg7As4](AgI3)2 | cubic | Pa | a = 13.138 Z = 4 | [17][18] | |||
(Hg2As)2(CdI4) | monoclinic | P21 | a=7.945, b=12.934, c=8.094, β=116.898° | 741.7 | [19] | ||
[Hg7As4I3](SnI3) | cubic | P213 | a = 13.110, Z = 4 | 2253.2 | 7.617 | black | [20] |
References
- ↑ 1.0 1.1 Hadenfeldt, C.; Fester, W. (July 1982). "Reindarstellung und thermische Stabilität von Calcium-phosphid- und -arsenidiodiden: Ca3PI3, Ca3AsI3, Ca2PI und Ca2AsI" (in de). Zeitschrift für anorganische und allgemeine Chemie 490 (1): 25–30. doi:10.1002/zaac.19824900105. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19824900105.
- ↑ Hadenfeldt, C.; Herdejürgen, H. (February 1987). "Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr" (in de). Zeitschrift für anorganische und allgemeine Chemie 545 (2): 177–183. doi:10.1002/zaac.19875450220. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19875450220.
- ↑ Jayasekera, Buddhimathie; Aitken, Jennifer A.; Heeg, Mary Jane; Brock, Stephanie L. (2003-02-01). "Toward an Arsenic Analogue of Hittorf's Phosphorus: Mixed Pnicogen Chains in Cu 2 P 1.8 As 1.2 I 2" (in en). Inorganic Chemistry 42 (3): 658–660. doi:10.1021/ic0258936. ISSN 0020-1669. PMID 12562174. https://pubs.acs.org/doi/10.1021/ic0258936.
- ↑ von Schnering, Hans-Georg; Menke, Heinz (January 1972). "Ge38P8I8 and Ge38As8I8, a New Class of Compounds with Clathrate Structure" (in en). Angewandte Chemie International Edition in English 11 (1): 43–44. doi:10.1002/anie.197200431. ISSN 0570-0833. https://onlinelibrary.wiley.com/doi/10.1002/anie.197200431.
- ↑ Jayasekera, Buddhimathie; Brock, Stephanie L. (2002). "Ag Ion-Exchange Reactions of Cu 2 P 3 I 2 and Cu 2 P 1.8 As 1.2 I 2" (in en). MRS Proceedings 755: DD6.12. doi:10.1557/PROC-755-DD6.12. ISSN 0272-9172. http://link.springer.com/10.1557/PROC-755-DD6.12.
- ↑ Shatruk, Mikhail M.; Kovnir, Kirill A.; Shevelkov, Andrei V.; Presniakov, Igor A.; Popovkin, Boris A. (1999-07-01). "First Tin Pnictide Halides Sn 24 P 19.3 I 8 and Sn 24 As 19.3 I 8 : Synthesis and the Clathrate-I Type of the Crystal Structure" (in en). Inorganic Chemistry 38 (15): 3455–3457. doi:10.1021/ic990153r. ISSN 0020-1669. PMID 11671088. https://pubs.acs.org/doi/10.1021/ic990153r.
- ↑ Zaikina, Julia V.; Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Prots, Yuri; Baitinger, Michael; Schnelle, Walter; Olenev, Andrei V. et al. (2007-06-15). "Sn20.5□3.5As22I8: A Largely Disordered Cationic Clathrate with a New Type of Superstructure and Abnormally Low Thermal Conductivity" (in en). Chemistry - A European Journal 13 (18): 5090–5099. doi:10.1002/chem.200601772. PMID 17385200. https://onlinelibrary.wiley.com/doi/10.1002/chem.200601772.
- ↑ Kelm, E. A.; Zaikina, Yu. V.; Dikarev, E. V.; Shevelkov, A. V. (April 2009). "Distribution of phosphorus and arsenic atoms in the solid solution Sn24As x P19.3-x I8 with the structure of clathrate-I" (in en). Russian Chemical Bulletin 58 (4): 746–750. doi:10.1007/s11172-009-0089-0. ISSN 1066-5285. http://link.springer.com/10.1007/s11172-009-0089-0.
- ↑ Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Schnelle, Walter; Grin, Yuri; Shevelkov, Andrei V. (2005-11-01). "Sn 19.3 Cu 4.7 As 22 I 8 : a New Clathrate-I Compound with Transition-Metal Atoms in the Cationic Framework" (in en). Inorganic Chemistry 44 (24): 8786–8793. doi:10.1021/ic051160k. ISSN 0020-1669. PMID 16296833. http://ematweb.cmi.ua.ac.be/emat/pdf/1331.pdf.
- ↑ Kelm, Evgeny A.; Olenev, Andrei V.; Bykov, Mikhail A.; Sobolev, Alexey V.; Presniakov, Igor A.; Kulbachinskii, Vladimir A.; Kytin, Vladimir G.; Shevelkov, Andrei V. (November 2011). "Synthesis, Crystal Structure, and Thermoelectric Properties of Clathrates in the Sn-In-As-I System" (in en). Zeitschrift für anorganische und allgemeine Chemie 637 (13): 2059–2067. doi:10.1002/zaac.201100287. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201100287.
- ↑ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds" (in en). Zeitschrift für Naturforschung B 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117.
- ↑ Oleneva, O. S.; Shestimerova, T. A.; Olenev, A. V.; Dikarev, E. V.; Shevelkov, A. V. (May 2006). "Synthesis and the crystal and electronic structure of Hg4AsI5" (in en). Russian Chemical Bulletin 55 (5): 762–765. doi:10.1007/s11172-006-0329-5. ISSN 1066-5285. http://link.springer.com/10.1007/s11172-006-0329-5.
- ↑ Labbé, Ph.; Ledésert, M.; Raveau, B.; Rebbah, A. (1989-08-01). "Crystal structure of Hg 4 As 2 I 3" (in en). Zeitschrift für Kristallographie - Crystalline Materials 187 (1–4): 117–124. doi:10.1524/zkri.1989.187.14.117. ISSN 2196-7105. https://www.degruyter.com/document/doi/10.1524/zkri.1989.187.14.117/html.
- ↑ Bräu, Michael F.; Pfitzner, Arno (2006-07-03). "HgI2⋅As4S4: An Adduct from HgI2 Molecules and Undistorted As4S4 Cages" (in en). Angewandte Chemie International Edition 45 (27): 4464–4467. doi:10.1002/anie.200600690. ISSN 1433-7851. PMID 16758498. https://onlinelibrary.wiley.com/doi/10.1002/anie.200600690.
- ↑ Liu, Yong; Zeng, Hui-Yi; Liu, Bin-Wen; Wang, Geng-E; Guo, Guo-Cong (May 2015). "Hg 5 AsS 2 I 3 – A Narrow-Band-Gap 2D Layered Compound with Different Trapped I – Anions" (in en). European Journal of Inorganic Chemistry 2015 (14): 2402–2406. doi:10.1002/ejic.201500150. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.201500150.
- ↑ Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure" (in en). Inorganic Chemistry 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388. https://pubs.acs.org/doi/10.1021/ic0003527.
- ↑ Olenev, Andrei V.; Baranov, Alexei I.; Oleneva, Olga S.; Vorontsov, Ivan I.; Antipin, Mikhail Yu.; Shevelkov, Andrei V. (March 2003). "Synthesis, Crystal and Electronic Structure of [Hg 7 As 4 (AgI 3 ) 2 , a Novel Supramolecular Complex with the Off-Plane AgI 3 2− Guest Anion"] (in en). European Journal of Inorganic Chemistry 2003 (6): 1053–1057. doi:10.1002/ejic.200390137. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200390137.
- ↑ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2 and [Hgn] (n = 2, 3) Cluster Groups"] (in en). Journal of Structural Chemistry 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. https://link.springer.com/10.1134/S0022476620020109.
- ↑ Zou, Jian-Ping; Wu, Dong-Sheng; Huang, Shu-Ping; Zhu, Jing; Guo, Guo-Cong; Huang, Jin-Shun (March 2007). "Synthesis, crystal and band structures, and properties of a new supramolecular complex (Hg2As)2(CdI4)" (in en). Journal of Solid State Chemistry 180 (3): 805–811. doi:10.1016/j.jssc.2006.11.018. Bibcode: 2007JSSCh.180..805Z. https://linkinghub.elsevier.com/retrieve/pii/S0022459606006049.
- ↑ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2000). "[Hg7As4I3](SnI3): Trapping the SnI31– Anion in the Cavities of the Unprecedented Mercury-Arsenic-Iodine Network". European Journal of Inorganic Chemistry 2000 (2): 265–270. doi:10.1002/(SICI)1099-0682(200002)2000:2<265::AID-EJIC265>3.0.CO;2-A.
HI | He | ||||||||||||||||
LiI | BeI2 | BI3 | CI4 | NI3 | I2O4, I2O5, I4O9 |
IF, IF3, IF5, IF7 |
Ne | ||||||||||
NaI | MgI2 | AlI3 | SiI4 | PI3, P2I4 |
S | ICl, ICl3 |
Ar | ||||||||||
KI | CaI2 | Sc | TiI4 | VI3 | CrI3 | MnI2 | FeI2 | CoI2 | NiI2 | CuI | ZnI2 | Ga2I6 | GeI2, GeI4 |
AsI3 | Se | IBr | Kr |
RbI | SrI2 | YI3 | ZrI4 | NbI5 | Mo | Tc | Ru | Rh | Pd | AgI | CdI2 | InI3 | SnI4, SnI2 |
SbI3 | TeI4 | I | Xe |
CsI | BaI2 | HfI4 | TaI5 | W | Re | Os | Ir | Pt | AuI | Hg2I2, HgI2 |
TlI | PbI2 | BiI3 | Po | AtI | Rn | |
Fr | RaI2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
↓ | |||||||||||||||||
La | Ce | Pr | Nd | Pm | SmI2 | Eu | Gd | TbI3 | Dy | Ho | Er | Tm | Yb | Lu | |||
Ac | ThI4 | Pa | UI3, UI4 |
Np | Pu | Am | Cm | Bk | Cf | EsI3 | Fm | Md | No | Lr |
![]() | Original source: https://en.wikipedia.org/wiki/Arsenide iodide.
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