Chemistry:Cerium(III) acetate
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| Names | |
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| IUPAC name
Cerium(III) acetate
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| Other names
Cerium triacetate
Cerium acetate | |
| Identifiers | |
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3D model (JSmol)
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PubChem CID
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| Properties | |
| Ce(CH3COO)3 | |
| Molar mass | 317.26 |
| Appearance | white powder |
| Melting point | 308°C |
| Hazards | |
| GHS pictograms |  
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| GHS Signal word | Warning |
| H315, H319, H335, H410 | |
| P261, P264, P264+265Script error: No such module "Preview warning".Category:GHS errors, P271, P273, P280, P302+352, P304+340, P305+351+338, P305+354+338Script error: No such module "Preview warning".Category:GHS errors, P317Script error: No such module "Preview warning".Category:GHS errors, P319Script error: No such module "Preview warning".Category:GHS errors, P321, P332+317Script error: No such module "Preview warning".Category:GHS errors, P337+317Script error: No such module "Preview warning".Category:GHS errors, P362+364Script error: No such module "Preview warning".Category:GHS errors, P391, P403+233, P405, P501 | |
| Related compounds | |
Other cations
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Lanthanum(III) acetate Praseodymium(III) acetate Neodymium acetate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Cerium acetate is an inorganic compound with the chemical formula of Ce(CH3COO)3. It is a white powder that is soluble in water. Its 1.5 hydrate loses water at 133°C to obtain an amorphous anhydrous form, and the amorphous phase changes to crystal at 212°C, and phase changes again at 286°C.[2]
Preparation
Cerium acetate can be prepared by reacting cerium(III) carbonate and 50% acetic acid in an aqueous solution:[3]
- Ce2(CO3)3 + 6 CH3COOH → 2 Ce(CH3COO)3 + 3 H2O + 3 CO2↑
Properties
Cerium acetate is soluble in water and ethanol in its anhydrous form (its hydrate is insoluble in ethanol), easily soluble in pyridine, and insoluble in acetone.[4] Its thermal decomposition at 310 °C will generate basic cerium(III) acetate, which will be further decomposed to obtain Ce2O2CO3 (a basic carbonate), and continued heating generates CeO2 and CO.[2]
References
- ↑ "Cerium triacetate" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/10826#section=Safety-and-Hazards.
- ↑ 2.0 2.1 Arii T, Kishi A, Ogawa M, et al. Thermal decomposition of cerium (III) acetate hydrate by a three-dimensional thermal analysis [J]. Analytical sciences, 2001, 17(7): 875-880.
- ↑ 《无机化合物制备手册》.朱文祥 主编. 化学工业出版社.第十四章 碳族元素.P512.XIV-124 醋酸铈(III)
- ↑ 《无机化合物合成手册》.第二卷.日本化学会 编. 曹惠民 译. 化学工业出版社. 1988.7第一版.【1260】稀土元素的乙酸盐.P582
Acetyl halides and salts of the acetate ion
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| AcOH | He | ||||||||||||||||||
| LiOAc | Be(OAc)2 BeAcOH |
B(OAc)3 | AcOAc ROAc |
NH4OAc | AcOOH | FAc | Ne | ||||||||||||
| NaOAc | Mg(OAc)2 | Al(OAc)3 ALSOL Al(OAc)2OH Al2SO4(OAc)4 |
Si | P | S | ClAc | Ar | ||||||||||||
| KOAc | Ca(OAc)2 | Sc(OAc)3 | Ti(OAc)4 | VO(OAc)3 | Cr(OAc)2 Cr(OAc)3 |
Mn(OAc)2 Mn(OAc)3 |
Fe(OAc)2 Fe(OAc)3 |
Co(OAc)2, Co(OAc)3 |
Ni(OAc)2 | Cu(OAc)2 | Zn(OAc)2 | Ga(OAc)3 | Ge | As(OAc)3 | Se | BrAc | Kr | ||
| RbOAc | Sr(OAc)2 | Y(OAc)3 | Zr(OAc)4 | Nb | Mo(OAc)2 | Tc | Ru(OAc)2 Ru(OAc)3 Ru(OAc)4 |
Rh2(OAc)4 | Pd(OAc)2 | AgOAc | Cd(OAc)2 | In | Sn(OAc)2 Sn(OAc)4 |
Sb(OAc)3 | Te | IAc | Xe | ||
| CsOAc | Ba(OAc)2 | Hf | Ta | W | Re | Os | Ir | Pt(OAc)2 | Au | Hg2(OAc)2, Hg(OAc)2 |
TlOAc Tl(OAc)3 |
Pb(OAc)2 Pb(OAc)4 |
Bi(OAc)3 | Po | At | Rn | |||
| Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
| ↓ | |||||||||||||||||||
| La(OAc)3 | Ce(OAc)x | Pr | Nd | Pm | Sm(OAc)3 | Eu(OAc)3 | Gd(OAc)3 | Tb | Dy(OAc)3 | Ho(OAc)3 | Er | Tm | Yb(OAc)3 | Lu(OAc)3 | |||||
| Ac | Th | Pa | UO2(OAc)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||
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