Chemistry:Indium gallium nitride

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Short description: Chemical compound


InGaN blue LED (380–405 nm)
Spectrum of a white-light LED where GaN or InGaN blue source pumps Ce:YAG phosphor

Indium gallium nitride (InGaN, In
xGa
1-xN) is a semiconductor material made of a mix of gallium nitride (GaN) and indium nitride (InN). It is a ternary group III/group V direct bandgap semiconductor. Its bandgap can be tuned by varying the amount of indium in the alloy. InxGa1−xN has a direct bandgap span from the infrared (0.69 eV) for InN to the ultraviolet (3.4 eV) of GaN. The ratio of In/Ga is usually[clarification needed] between 0.02/0.98 and 0.3/0.7.[1]

Applications

LEDs

Indium gallium nitride is the light-emitting layer in modern blue and green LEDs and often grown on a GaN buffer on a transparent substrate as, e.g. sapphire or silicon carbide. It has a high heat capacity and its sensitivity to ionizing radiation is low (like other group III nitrides), making it also a potentially suitable material for solar photovoltaic devices, specifically for arrays for satellites.

It is theoretically predicted that spinodal decomposition of indium nitride should occur for compositions between 15% and 85%, leading to In-rich and Ga-rich InGaN regions or clusters. However, only a weak phase segregation has been observed in experimental local structure studies.[2] Other experimental results using cathodoluminescence and photoluminescence excitation on low In-content InGaN multi-quantum wells have demonstrated that providing correct material parameters of the InGaN/GaN alloys, theoretical approaches for AlGaN/GaN systems also apply to InGaN nanostructures.[3]

GaN is a defect-rich material with typical dislocation densities[4] exceeding 108 cm−2. Light emission from InGaN layers grown on such GaN buffers used in blue and green LEDs is expected to be attenuated because of non-radiative recombination at such defects.[5] Nevertheless, InGaN quantum wells, are efficient light emitters in green, blue, white and ultraviolet light-emitting diodes and diode lasers.[6][7][8] The indium-rich regions have a lower bandgap than the surrounding material and create regions of reduced potential energy for charge carriers. Electron-hole pairs are trapped there and recombine with emission of light, instead of diffusing to crystal defects where the recombination is non-radiative. Also, self-consistent computer simulations have shown that radiative recombination is focused where regions are rich of indium.[9]

The emitted wavelength, dependent on the material's band gap, can be controlled by the GaN/InN ratio, from near ultraviolet for 0.02In/0.98Ga through 390 nm for 0.1In/0.9Ga, violet-blue 420 nm for 0.2In/0.8Ga, to blue 440 nm for 0.3In/0.7Ga, to red for higher ratios and also by the thickness of the InGaN layers which are typically in the range of 2–3 nm[citation needed]. However, atomistic simulations results have shown that emission energies have a minor dependence on small variations of device dimensions.[10] Studies based on device simulation have shown that it could be possible to increase InGaN/GaN LED efficiency using band gap engineering, especially for green LEDs.[11]

Photovoltaics

The ability to perform bandgap engineering with InGaN over a range that provides a good spectral match to sunlight, makes InGaN suitable for solar photovoltaic cells.[12][13] It is possible to grow multiple layers with different bandgaps, as the material is relatively insensitive to defects introduced by a lattice mismatch between the layers. A two-layer multijunction cell with bandgaps of 1.1 eV and 1.7 eV can attain a theoretical 50% maximum efficiency, and by depositing multiple layers tuned to a wide range of bandgaps an efficiency up to 70% is theoretically expected.[14]

Significant photoresponse was obtained from experimental InGaN single-junction devices.[15][16] In addition to controlling the optical properties,[17] which results in band gap engineering, photovoltaic device performance can be improved by engineering the microstructure of the material to increase the optical path length and provide light trapping. Growing nanocolumns on the device can further result in resonant interaction with light,[18] and InGaN nanocolumns have been successfully deposited on SiO2 using plasma enhanced evaporation.[19] Nanorod growth may also be advantageous in the reduction of treading dislocations which may act as charge traps reducing solar cell efficiency [20]

Metal-modulated epitaxy allows controlled atomic layer-by-layer growth of thin films with almost ideal characteristics enabled by strain relaxation at the first atomic layer. The crystal's lattice structures match up, resembling a perfect crystal, with corresponding luminosity. The crystal had indium content ranging from x ~ 0.22 to 0.67. Significant improvement in the crystalline quality and optical properties began at x ~ 0.6. Films were grown at ~400 °C to facilitate indium incorporation and with precursor modulation to enhance surface morphology and metal adlayer diffusion. These findings should contribute to the development of growth techniques for nitride semiconductors under high lattice misfit conditions.[21][22]

Quantum heterostructures

Quantum heterostructures are often built from GaN with InGaN active layers. InGaN can be combined with other materials, e.g. GaN, AlGaN, on SiC, sapphire and even silicon.

Nanorods

InGaN nanorod LEDs are three-dimensional structures with a larger emitting surface, better efficiency and greater light emission compared to planar LEDs [citation needed].

Safety and toxicity

The toxicology of InGaN has not been fully investigated. The dust is an irritant to skin, eyes and lungs. The environment, health and safety aspects of indium gallium nitride sources (such as trimethylindium, trimethylgallium and ammonia) and industrial hygiene monitoring studies of standard MOVPE sources have been reported recently in a review.[23]

See also

References

  1. ↑ Linti, G.. "The Group 13 Metals Aluminium, Gallium, Indium and Thallium. Chemical Patterns and Peculiarities. Edited by Simon Aldridge and Anthony J. Downs.Angew. Chem". Angewandte Chemie International Edition 50: 11569. doi:10.1002/anie.201105633. 
  2. ↑ V. Kachkanov; K.P. O'Donnell; S. Pereira; R.W. Martin (2007). "Localization of excitation in InGaN epilayers". Phil. Mag. 87 (13): 1999–2017. doi:10.1080/14786430701342164. Bibcode: 2007PMag...87.1999K. https://hal.archives-ouvertes.fr/hal-00513828/file/PEER_stage2_10.1080%252F14786430701342164.pdf. 
  3. ↑ A. Reale1; A. Di Carlo; A. Vinattieri; M. Colocci; F. Rossi; N. Armani; C. Ferrari; G. Salviati et al. (2005). "Investigation of the recombination dynamics in low In-content InGaN MQWs by means of cathodoluminescence and photoluminescence excitation". Physica Status Solidi C 2 (2): 817–821. doi:10.1002/pssc.200460305. Bibcode: 2005PSSCR...2..817R. 
  4. ↑ Rak Jun Choi; Hyung Jae Lee; Yoon-bong Hahn; Hyung Koun Cho (2004). "Structural and optical properties of InGaN/GaN triangular-shape quantum wells with different threading dislocation densities". Korean Journal of Chemical Engineering 21: 292–295. doi:10.1007/BF02705411. 
  5. ↑ P. G. Eliseev. "Radiative processes in InGaN quantum wells". http://handle.dtic.mil/100.2/ADP012939. 
  6. ↑ Liang-Yi Chen; Ying-Yuan Huang; Chun-Hsiang Chang; Yu-Hsuan Sun; Yun-Wei Cheng; Min-Yung Ke; Cheng-Pin Chen; JianJang Huang (2010). "High performance InGaN/GaN nanorod light emitting diode arrays fabricated by nanosphere lithography and chemical mechanical polishing processes". Optics Express 18 (8): 7664–7669. doi:10.1364/OE.18.007664. PMID 20588606. Bibcode: 2010OExpr..18.7664C. 
  7. ↑ "Strong luminescence from strain relaxed InGaN/GaN nanotips for highly efficient light emitters". http://morkoc.vcu.edu/publications/160326InGaN-GaN-nanotips.pdf. 
  8. ↑ C Skierbiszewski1,2, P Perlin1,2, I Grzegory, Z R Wasilewski, M Siekacz, A Feduniewicz, P Wisniewski, J Borysiuk, P Prystawko, G Kamler, T Suski and S Porowski (2005). "High power blue–violet InGaN laser diodes grown on bulk GaN substrates by plasma-assisted molecular beam epitaxy". Semiconductor Science and Technology 20 (8): 809–813. doi:10.1088/0268-1242/20/8/030. Bibcode: 2005SeScT..20..809S. 
  9. ↑ Sacconi, F.; Auf der Maur, M.; Pecchia, A.; Lopez, M.; Di Carlo, A. (2012). "Optoelectronic properties of nanocolumnar InGaN/GaN quantum disk LEDs". Physica Status Solidi C 9 (5): 1315–1319. doi:10.1002/pssc.201100205. Bibcode: 2012PSSCR...9.1315S. 
  10. ↑ M. Lopez, F. Sacconi, M. Auf der Maur, A. Pecchia, A. Di Carlo. "Atomistic simulation of InGaN/GaN quantum disk LEDs" (2012). "Atomistic simulation of InGaN/GaN quantum disk LEDs". Optical and Quantum Electronics 44 (3): 89–94. doi:10.1007/s11082-012-9554-3. 
  11. ↑ M. Auf der Maur, K. Lorenz and A. Di Carlo. "Band gap engineering approaches to increase InGaN/GaN LED efficiency" (2012). "Band gap engineering approaches to increase InGaN/GaN LED efficiency". Physica Status Solidi C 44 (3–5): 83–88. doi:10.1007/s11082-011-9536-x. 
  12. ↑ McLaughlin, D.V.P.; Pearce, J.M. (2013). "Progress in Indium Gallium Nitride Materials for Solar Photovoltaic Energy Conversion". Metallurgical and Materials Transactions A 44 (4): 1947–1954. doi:10.1007/s11661-013-1622-1. Bibcode: 2013MMTA...44.1947M. https://digitalcommons.mtu.edu/cgi/viewcontent.cgi?article=1008&context=materials_fp. 
  13. ↑ Bhuiyan, A.; Sugita, K.; Hashimoto, A.; Yamamoto, A. (2012). "InGaN Solar Cells: Present State of the Art and Important Challenges". IEEE Journal of Photovoltaics 2 (3): 276–293. doi:10.1109/JPHOTOV.2012.2193384. 
  14. ↑ A nearly perfect solar cell, part 2 . Lbl.gov. Retrieved on 2011-11-07.
  15. ↑ Zeng, S. W. (2009). "Substantial photo-response of InGaN p–i–n homojunction solar cells". Semicond. Sci. Technol. 24 (5): 055009. doi:10.1088/0268-1242/24/5/055009. Bibcode: 2009SeScT..24e5009Z. 
  16. ↑ Sun, X. (2008). "Photoelectric characteristics of metal/InGaN/GaN heterojunction structure". J. Phys. D 41 (16): 165108. doi:10.1088/0022-3727/41/16/165108. Bibcode: 2008JPhD...41p5108S. 
  17. ↑ Dirk V. P. McLaughlin; J.M. Pearce (2012). "Analytical Model for the Optical Functions of Indium Gallium Nitride with Application to Thin Film Solar Photovoltaic Cells". Materials Science and Engineering: B 177 (2): 239–244. doi:10.1016/j.mseb.2011.12.008. 
  18. ↑ Cao, L.; White, J. S.; Park, J. S.; Schuller, J. A.; Clemens, B. M.; Brongersma, M. L. (2009). "Engineering light absorption in semiconductor nanowire devices". Nature Materials 8 (8): 643–647. doi:10.1038/nmat2477. PMID 19578337. Bibcode: 2009NatMa...8..643C. 
  19. ↑ S. Keating; M.G. Urquhart; D.V.P. McLaughlin; J.M. Pearce (2011). "Effects of Substrate Temperature on Indium Gallium Nitride Nanocolumn Crystal Growth". Crystal Growth & Design 11 (2): 565–568. doi:10.1021/cg101450n. http://qspace.library.queensu.ca/handle/1974/6430. 
  20. ↑ Cherns, D.; Webster, R. F.; Novikov, S. V.; Foxon, C. T.; Fischer, A. M.; Ponce, F. A.; Haigh, S. J. (2014). "Compositional variations in In0.5Ga0.5N nanorods grown by molecular beam epitaxy". Nanotechnology 25 (21): 215705. doi:10.1088/0957-4484/25/21/215705. PMID 24785272. Bibcode: 2014Nanot..25u5705C. 
  21. ↑ "Controlled atomic-layer crystal growth is 'breakthrough' for solar-cell efficiency". KurzweilAI. http://www.kurzweilai.net/controlled-atomic-layer-crystal-growth-is-breakthrough-for-solar-cell-efficiency. 
  22. ↑ Fischer, A. M.; Wei, Y. O.; Ponce, F. A.; Moseley, M.; Gunning, B.; Doolittle, W. A. (2013). "Highly luminescent, high-indium-content InGaN film with uniform composition and full misfit-strain relaxation". Applied Physics Letters 103 (13): 131101. doi:10.1063/1.4822122. Bibcode: 2013ApPhL.103m1101F. https://zenodo.org/record/895544. 
  23. ↑ D V Shenai-Khatkhate; R Goyette; R L DiCarlo; G Dripps (2004). "Environment, health and safety issues for sources used in MOVPE growth of compound semiconductors". Journal of Crystal Growth 1–4 (1–4): 816–821. doi:10.1016/j.jcrysgro.2004.09.007. Bibcode: 2004JCrGr.272..816S. 
Salts and covalent derivatives of the nitride ion
NH3 He(N2)11
Li3N Be3N2 BN β-C3N4
g-C3N4 		N2 NxOy NF3 Ne
Na3N Mg3N2 AlN Si3N4 PN
P3N5 		SxNy
SN
S4N4 		NCl3 Ar
K3N Ca3N2 ScN TiN VN CrN
Cr2N 		MnxNy FexNy CoN Ni3N CuN Zn3N2 GaN Ge3N4 As Se NBr3 Kr
Rb3N Sr3N2 YN ZrN NbN β-Mo2N Tc Ru Rh PdN Ag3N CdN InN Sn Sb Te NI3 Xe
Cs3N Ba3N2   Hf3N4 TaN WN Re Os Ir Pt Au Hg3N2 TlN Pb BiN Po At Rn
Fr3N Ra3N   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La CeN Pr Nd Pm Sm Eu GdN Tb Dy Ho Er Tm Yb Lu
Ac Th Pa UN Np Pu Am Cm Bk Cf Es Fm Md No Lr



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