Chemistry:Borate iodide

Short description: Mixed anion compounds

The borate iodides are mixed anion compounds that contain both borate and iodide anions. They are in the borate halide family of compounds which also includes borate fluorides, borate chlorides, and borate bromides.

List

name	chem	mw	crystal system	space group	unit cell Å	volume	density	comment	references
	Cr₃B₇O₁₃I			F4_3c	a = 12.171 Z=8	18029	4.17		^[1]
	Mn₃B₇O₁₃I			F4_3c	a = 12.32 Z=8	1870	4.09		^[1]
	Fe₃B₇O₁₃I			Pca2₁	a = 8.654, c = 12.2336 Z=4	915.57	4.19		^[1]
	Co₃B₇O₁₃I			F4_3c	a = 12.119 Z=8	1779.9	4.38		^[1]
	Ni₃B₇O₁₃I			Pca2₁	a = 08.511 c = 12.037 Z=4	871.9	4.47	magnetoelectric, ferroelectric and ferroelastic	^[1]
	Cu₃B₇O₁₃I			F4_3c	a = 12.0203 Z=8	1736.8	4.60		^[1]
	Ag₄B₄O₇I₂	840.52	hexagonal	P6₁22	a=8.9576 c=45.1956 Z=12	3140.6	5.33		^[2]
tin iodide borate	Sn₃[B₃O₇]I		orthorhombic	Pbca	a = 10.718, b = 8.523, and c = 20.168 Z = 8				^[3]
	La[B₅O₈(OH)(H₂O)₂I]	495.86	monoclinic	P2₁/n	a=6.529 b=15.494 c=10.744 β=90.353 Z=4	1086.8	3.03	colourless	^[4]
	La[B₇O₁₁(OH)(H₂O)₃I]	581.48	orthorhombic	P2₁/n	a=8.178 b=17.251 c=9.849 Z=4	1389.4	2.78	colourless	^[5]
	Ce[B₅O₈(OH)(H₂O)₂I]	497.07	monoclinic	P2₁/n	a= 6.498 b=15.416 c=10.704 β=90.306 Z=4	1072.3	3.079	colourless	^[4]
	Ce[B₇O₁₁(OH)(H₂O)₃I]	582.69	orthorhombic	P2₁/n	a=8.1641 b=17.205 c=9.816 Z=4	1378.8	2.807	colourless	^[5]
	Pr[B₅O₈(OH)(H₂O)₂I]	497.86	monoclinic	P2₁/n	a= 6.488 b=15.392 c=10.686 β=90.254 Z=4	1067.0	3.099	green	^[4]
	Pr[B₇O₁₁(OH)(H₂O)₃I]	583.48	orthorhombic	P2₁/n	a=8.1504 b=17.205 c=9.814 Z=4	1376.2	2.816	light green	^[5]
	Nd[B₅O₈(OH)(H₂O)₂I]	501.19	monoclinic	P2₁/n	a=6.4763 b=15.350 c=10.6734 β=90.316 Z=4	1061.0	3.137	purple	^[4]
	Nd[B₇O₁₁(OH)(H₂O)₃I]	586.81	orthorhombic	P2₁/n	a=8.1464 b=17.199 c=9.735 Z=4	1372.2	2.841	purple	^[5]
	Sm[B₇O₁₁(OH)(H₂O)₃I]	592.92	orthorhombic	P2₁/n	a=8.102 b=17.158 c=9.733 Z=4	1352.9	2.911	colourless	^[5]
dilead borate iodide	Pb₂BO₃I		trigonal	P321				NLO 10 × KDP	^[6]
	Pb₂B₅O₉I	739.35	orthorhombic	Pnm2	a=11.561 b=11.700 c=6.524 Z=4	882.5	5.565	colourless or yellow	^[7]
	Pb₆O₄(BO₃)I	1492.85	orthorhombic	Pmmn	a= 5.78 b=9.72 c=10.63 Z=2	597	8.302	colourless	^[8]
	Pb₁₀O₄(BO₃)₃I₃	2693.03	monoclinic	Cc	a=16.6423 b=9.0277 c=16.9746 β=115.658 Z=4	2298.8	7.781	colourless	^[9]
tetrabismuth borate tetraoxy iodide	Bi₄BO₇I	1085.6	orthorhombic	Immm	a=3.959 b=13.453 c=3.969 Z=1	211.4	8.5279	dark orange	^[10]
	Pu[B₇O₁₁(OH)(H₂O)₂I]	668.57	monoclinic	P2₁/n	a=8.110 b=17.060 c=9.792 β=90.133 Z=4	1354.9	3.278	pale blue	^[4]

References

↑ ^1.0 ^1.1 ^1.2 ^1.3 ^1.4 ^1.5 Schnelle, Walter; Schmid, Hans (2015-05-20). "Magnetic and structural phase transitions of multiferroic boracites M 3 B 7 O 13 X ( M = 3 d transition metal Cr–Zn or Mg; X = halogen Cl , Br, I)" (in en). Physical Review B 91 (18): 184411. doi:10.1103/PhysRevB.91.184411. ISSN 1098-0121. Bibcode: 2015PhRvB..91r4411S. https://link.aps.org/doi/10.1103/PhysRevB.91.184411.
↑ Volkov, Sergey N.; Charkin, Dmitri O.; Arsent’ev, Maxim Yu.; Povolotskiy, Alexey V.; Stefanovich, Sergey Yu.; Ugolkov, Valery L.; Krzhizhanovskaya, Maria G.; Shilovskikh, Vladimir V. et al. (2020-03-02). "Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate Halides" (in en). Inorganic Chemistry 59 (5): 2655–2658. doi:10.1021/acs.inorgchem.0c00306. ISSN 0020-1669. PMID 32049501. https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.0c00306.
↑ Schönegger, Sandra; Pielnhofer, Florian; Saxer, Andreas; Wurst, Klaus; Huppertz, Hubert (2019-05-06). "Synthesis and Characterization of the Tin Iodide Borate Sn 3 [B 3 O 7 I"] (in en). Inorganic Chemistry 58 (9): 6088–6094. doi:10.1021/acs.inorgchem.9b00377. ISSN 0020-1669. PMID 30964677. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00377.
↑ ^4.0 ^4.1 ^4.2 ^4.3 ^4.4 Polinski, Matthew J.; Wang, Shuao; Cross, Justin N.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2012-07-16). "Effects of Large Halides on the Structures of Lanthanide(III) and Plutonium(III) Borates" (in en). Inorganic Chemistry 51 (14): 7859–7866. doi:10.1021/ic3009317. ISSN 0020-1669. PMID 22734798. https://pubs.acs.org/doi/10.1021/ic3009317.
↑ ^5.0 ^5.1 ^5.2 ^5.3 ^5.4 Polinski, Matthew J.; Alekseev, Evgeny V.; Darling, Victoria R.; Cross, Justin N.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-02-18). "A New Family of Lanthanide Borate Halides with Unusual Coordination and a New Neodymium-Containing Cationic Framework" (in en). Inorganic Chemistry 52 (4): 1965–1975. doi:10.1021/ic302309z. ISSN 0020-1669. PMID 23360290. https://pubs.acs.org/doi/10.1021/ic302309z.
↑ Yu, Hongwei; Koocher, Nathan Z.; Rondinelli, James M.; Halasyamani, P. Shiv (2018-05-22). "Pb 2 BO 3 I: A Borate Iodide with the Largest Second-Harmonic Generation (SHG) Response in the KBe 2 BO 3 F 2 (KBBF) Family of Nonlinear Optical (NLO) Materials" (in en). Angewandte Chemie International Edition 57 (21): 6100–6103. doi:10.1002/anie.201802079. PMID 29512313.
↑ Huang, Yi-Zhi; Wu, Li-Ming; Wu, Xin-Tao; Li, Long-Hua; Chen, Ling; Zhang, Yong-Fan (2010-09-22). "Pb 2 B 5 O 9 I: An Iodide Borate with Strong Second Harmonic Generation" (in en). Journal of the American Chemical Society 132 (37): 12788–12789. doi:10.1021/ja106066k. ISSN 0002-7863. PMID 20738133. https://pubs.acs.org/doi/10.1021/ja106066k.
↑ Li, Kuan; Yalikun, Alimujiang; Su, Zhi (2020). "[O 2 Pb 3 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains"] (in en). Dalton Transactions 49 (26): 8985–8990. doi:10.1039/D0DT01722A. ISSN 1477-9226. PMID 32558837. http://xlink.rsc.org/?DOI=D0DT01722A.
↑ Zhou, Jinjie; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wu, Yicheng (2019). "Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method" (in en). Dalton Transactions 48 (40): 14996–15001. doi:10.1039/C9DT02579K. ISSN 1477-9226. PMID 31369009. http://xlink.rsc.org/?DOI=C9DT02579K.
↑ Volkov, Sergey; Bubnova, Rimma; Krzhizhanovskaya, Maria; Galafutnik, Lydia (2020-12-01). "The first bismuth borate oxyiodide, Bi 4 BO 7 I: commensurate or incommensurate?". Acta Crystallographica Section B 76 (6): 992–1000. doi:10.1107/S2052520620012640. ISSN 2052-5206. PMID 33289711. Bibcode: 2020AcCrB..76..992V. https://scripts.iucr.org/cgi-bin/paper?S2052520620012640.

HI																	He
LiI	BeI₂											BI₃	CI₄	NI₃	I₂O₄, I₂O₅, I₄O₉	IF, IF₃, IF₅, IF₇	Ne
NaI	MgI₂											AlI₃	SiI₄	PI₃, P₂I₄	S	ICl, ICl₃	Ar
KI	CaI₂	Sc	TiI₄	VI₃	CrI₃	MnI₂	FeI₂	CoI₂	NiI₂	CuI	ZnI₂	Ga₂I₆	GeI₂, GeI₄	AsI₃	Se	IBr	Kr
RbI	SrI₂	YI₃	ZrI₄	NbI₅	Mo	Tc	Ru	Rh	Pd	AgI	CdI₂	InI₃	SnI₄, SnI₂	SbI₃	TeI₄	I	Xe
CsI	BaI₂		HfI₄	TaI₅	W	Re	Os	Ir	Pt	AuI	Hg₂I₂, HgI₂	TlI	PbI₂	BiI₃	Po	AtI	Rn
Fr	RaI₂		Rf	Db	Sg	Bh	Hs	Mt	Ds	Rg	Cn	Nh	Fl	Mc	Lv	Ts	Og
		↓
		La	Ce	Pr	Nd	Pm	SmI₂	Eu	Gd	TbI₃	Dy	Ho	Er	Tm	Yb	Lu
		Ac	ThI₄	Pa	UI₃, UI₄	Np	Pu	Am	Cm	Bk	Cf	EsI₃	Fm	Md	No	Lr

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Original source: https://en.wikipedia.org/wiki/Borate iodide. Read more

[:1-1] 1.0 ^1.1 ^1.2 ^1.3 ^1.4 ^1.5 Schnelle, Walter; Schmid, Hans (2015-05-20). "Magnetic and structural phase transitions of multiferroic boracites M 3 B 7 O 13 X ( M = 3 d transition metal Cr–Zn or Mg; X = halogen Cl , Br, I)" (in en). Physical Review B 91 (18): 184411. doi:10.1103/PhysRevB.91.184411. ISSN 1098-0121. Bibcode: 2015PhRvB..91r4411S. https://link.aps.org/doi/10.1103/PhysRevB.91.184411.

[:0-2] Volkov, Sergey N.; Charkin, Dmitri O.; Arsent’ev, Maxim Yu.; Povolotskiy, Alexey V.; Stefanovich, Sergey Yu.; Ugolkov, Valery L.; Krzhizhanovskaya, Maria G.; Shilovskikh, Vladimir V. et al. (2020-03-02). "Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate Halides" (in en). Inorganic Chemistry 59 (5): 2655–2658. doi:10.1021/acs.inorgchem.0c00306. ISSN 0020-1669. PMID 32049501. https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.0c00306.

[3] Schönegger, Sandra; Pielnhofer, Florian; Saxer, Andreas; Wurst, Klaus; Huppertz, Hubert (2019-05-06). "Synthesis and Characterization of the Tin Iodide Borate Sn 3 [B 3 O 7 I"] (in en). Inorganic Chemistry 58 (9): 6088–6094. doi:10.1021/acs.inorgchem.9b00377. ISSN 0020-1669. PMID 30964677. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00377.

[:7-4] 4.0 ^4.1 ^4.2 ^4.3 ^4.4 Polinski, Matthew J.; Wang, Shuao; Cross, Justin N.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2012-07-16). "Effects of Large Halides on the Structures of Lanthanide(III) and Plutonium(III) Borates" (in en). Inorganic Chemistry 51 (14): 7859–7866. doi:10.1021/ic3009317. ISSN 0020-1669. PMID 22734798. https://pubs.acs.org/doi/10.1021/ic3009317.

[:2-5] 5.0 ^5.1 ^5.2 ^5.3 ^5.4 Polinski, Matthew J.; Alekseev, Evgeny V.; Darling, Victoria R.; Cross, Justin N.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-02-18). "A New Family of Lanthanide Borate Halides with Unusual Coordination and a New Neodymium-Containing Cationic Framework" (in en). Inorganic Chemistry 52 (4): 1965–1975. doi:10.1021/ic302309z. ISSN 0020-1669. PMID 23360290. https://pubs.acs.org/doi/10.1021/ic302309z.

[6] Yu, Hongwei; Koocher, Nathan Z.; Rondinelli, James M.; Halasyamani, P. Shiv (2018-05-22). "Pb 2 BO 3 I: A Borate Iodide with the Largest Second-Harmonic Generation (SHG) Response in the KBe 2 BO 3 F 2 (KBBF) Family of Nonlinear Optical (NLO) Materials" (in en). Angewandte Chemie International Edition 57 (21): 6100–6103. doi:10.1002/anie.201802079. PMID 29512313.

[7] Huang, Yi-Zhi; Wu, Li-Ming; Wu, Xin-Tao; Li, Long-Hua; Chen, Ling; Zhang, Yong-Fan (2010-09-22). "Pb 2 B 5 O 9 I: An Iodide Borate with Strong Second Harmonic Generation" (in en). Journal of the American Chemical Society 132 (37): 12788–12789. doi:10.1021/ja106066k. ISSN 0002-7863. PMID 20738133. https://pubs.acs.org/doi/10.1021/ja106066k.

[8] Li, Kuan; Yalikun, Alimujiang; Su, Zhi (2020). "[O 2 Pb 3 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains"] (in en). Dalton Transactions 49 (26): 8985–8990. doi:10.1039/D0DT01722A. ISSN 1477-9226. PMID 32558837. http://xlink.rsc.org/?DOI=D0DT01722A.

[9] Zhou, Jinjie; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wu, Yicheng (2019). "Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method" (in en). Dalton Transactions 48 (40): 14996–15001. doi:10.1039/C9DT02579K. ISSN 1477-9226. PMID 31369009. http://xlink.rsc.org/?DOI=C9DT02579K.

[10] Volkov, Sergey; Bubnova, Rimma; Krzhizhanovskaya, Maria; Galafutnik, Lydia (2020-12-01). "The first bismuth borate oxyiodide, Bi 4 BO 7 I: commensurate or incommensurate?". Acta Crystallographica Section B 76 (6): 992–1000. doi:10.1107/S2052520620012640. ISSN 2052-5206. PMID 33289711. Bibcode: 2020AcCrB..76..992V. https://scripts.iucr.org/cgi-bin/paper?S2052520620012640.

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