Chemistry:Borate iodide
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Short description: Mixed anion compounds
The borate iodides are mixed anion compounds that contain both borate and iodide anions. They are in the borate halide family of compounds which also includes borate fluorides, borate chlorides, and borate bromides.
List
name | chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references |
---|---|---|---|---|---|---|---|---|---|
Cr3B7O13I | F4_3c | a = 12.171 Z=8 | 18029 | 4.17 | [1] | ||||
Mn3B7O13I | F4_3c | a = 12.32 Z=8 | 1870 | 4.09 | [1] | ||||
Fe3B7O13I | Pca21 | a = 8.654, c = 12.2336 Z=4 | 915.57 | 4.19 | [1] | ||||
Co3B7O13I | F4_3c | a = 12.119 Z=8 | 1779.9 | 4.38 | [1] | ||||
Ni3B7O13I | Pca21 | a = 08.511 c = 12.037 Z=4 | 871.9 | 4.47 | magnetoelectric, ferroelectric and ferroelastic | [1] | |||
Cu3B7O13I | F4_3c | a = 12.0203 Z=8 | 1736.8 | 4.60 | [1] | ||||
Ag4B4O7I2 | 840.52 | hexagonal | P6122 | a=8.9576 c=45.1956 Z=12 | 3140.6 | 5.33 | [2] | ||
tin iodide borate | Sn3[B3O7]I | orthorhombic | Pbca | a = 10.718, b = 8.523, and c = 20.168 Z = 8 | [3] | ||||
La[B5O8(OH)(H2O)2I] | 495.86 | monoclinic | P21/n | a=6.529 b=15.494 c=10.744 β=90.353 Z=4 | 1086.8 | 3.03 | colourless | [4] | |
La[B7O11(OH)(H2O)3I] | 581.48 | orthorhombic | P21/n | a=8.178 b=17.251 c=9.849 Z=4 | 1389.4 | 2.78 | colourless | [5] | |
Ce[B5O8(OH)(H2O)2I] | 497.07 | monoclinic | P21/n | a= 6.498 b=15.416 c=10.704 β=90.306 Z=4 | 1072.3 | 3.079 | colourless | [4] | |
Ce[B7O11(OH)(H2O)3I] | 582.69 | orthorhombic | P21/n | a=8.1641 b=17.205 c=9.816 Z=4 | 1378.8 | 2.807 | colourless | [5] | |
Pr[B5O8(OH)(H2O)2I] | 497.86 | monoclinic | P21/n | a= 6.488 b=15.392 c=10.686 β=90.254 Z=4 | 1067.0 | 3.099 | green | [4] | |
Pr[B7O11(OH)(H2O)3I] | 583.48 | orthorhombic | P21/n | a=8.1504 b=17.205 c=9.814 Z=4 | 1376.2 | 2.816 | light green | [5] | |
Nd[B5O8(OH)(H2O)2I] | 501.19 | monoclinic | P21/n | a=6.4763 b=15.350 c=10.6734 β=90.316 Z=4 | 1061.0 | 3.137 | purple | [4] | |
Nd[B7O11(OH)(H2O)3I] | 586.81 | orthorhombic | P21/n | a=8.1464 b=17.199 c=9.735 Z=4 | 1372.2 | 2.841 | purple | [5] | |
Sm[B7O11(OH)(H2O)3I] | 592.92 | orthorhombic | P21/n | a=8.102 b=17.158 c=9.733 Z=4 | 1352.9 | 2.911 | colourless | [5] | |
dilead borate iodide | Pb2BO3I | trigonal | P321 | NLO 10 × KDP | [6] | ||||
Pb2B5O9I | 739.35 | orthorhombic | Pnm2 | a=11.561 b=11.700 c=6.524 Z=4 | 882.5 | 5.565 | colourless or yellow | [7] | |
Pb6O4(BO3)I | 1492.85 | orthorhombic | Pmmn | a= 5.78 b=9.72 c=10.63 Z=2 | 597 | 8.302 | colourless | [8] | |
Pb10O4(BO3)3I3 | 2693.03 | monoclinic | Cc | a=16.6423 b=9.0277 c=16.9746 β=115.658 Z=4 | 2298.8 | 7.781 | colourless | [9] | |
tetrabismuth borate tetraoxy iodide | Bi4BO7I | 1085.6 | orthorhombic | Immm | a=3.959 b=13.453 c=3.969 Z=1 | 211.4 | 8.5279 | dark orange | [10] |
Pu[B7O11(OH)(H2O)2I] | 668.57 | monoclinic | P21/n | a=8.110 b=17.060 c=9.792 β=90.133 Z=4 | 1354.9 | 3.278 | pale blue | [4] |
References
- ↑ 1.0 1.1 1.2 1.3 1.4 1.5 Schnelle, Walter; Schmid, Hans (2015-05-20). "Magnetic and structural phase transitions of multiferroic boracites M 3 B 7 O 13 X ( M = 3 d transition metal Cr–Zn or Mg; X = halogen Cl , Br, I)" (in en). Physical Review B 91 (18): 184411. doi:10.1103/PhysRevB.91.184411. ISSN 1098-0121. Bibcode: 2015PhRvB..91r4411S. https://link.aps.org/doi/10.1103/PhysRevB.91.184411.
- ↑ Volkov, Sergey N.; Charkin, Dmitri O.; Arsent’ev, Maxim Yu.; Povolotskiy, Alexey V.; Stefanovich, Sergey Yu.; Ugolkov, Valery L.; Krzhizhanovskaya, Maria G.; Shilovskikh, Vladimir V. et al. (2020-03-02). "Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate Halides" (in en). Inorganic Chemistry 59 (5): 2655–2658. doi:10.1021/acs.inorgchem.0c00306. ISSN 0020-1669. PMID 32049501. https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.0c00306.
- ↑ Schönegger, Sandra; Pielnhofer, Florian; Saxer, Andreas; Wurst, Klaus; Huppertz, Hubert (2019-05-06). "Synthesis and Characterization of the Tin Iodide Borate Sn 3 [B 3 O 7 I"] (in en). Inorganic Chemistry 58 (9): 6088–6094. doi:10.1021/acs.inorgchem.9b00377. ISSN 0020-1669. PMID 30964677. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00377.
- ↑ 4.0 4.1 4.2 4.3 4.4 Polinski, Matthew J.; Wang, Shuao; Cross, Justin N.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2012-07-16). "Effects of Large Halides on the Structures of Lanthanide(III) and Plutonium(III) Borates" (in en). Inorganic Chemistry 51 (14): 7859–7866. doi:10.1021/ic3009317. ISSN 0020-1669. PMID 22734798. https://pubs.acs.org/doi/10.1021/ic3009317.
- ↑ 5.0 5.1 5.2 5.3 5.4 Polinski, Matthew J.; Alekseev, Evgeny V.; Darling, Victoria R.; Cross, Justin N.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-02-18). "A New Family of Lanthanide Borate Halides with Unusual Coordination and a New Neodymium-Containing Cationic Framework" (in en). Inorganic Chemistry 52 (4): 1965–1975. doi:10.1021/ic302309z. ISSN 0020-1669. PMID 23360290. https://pubs.acs.org/doi/10.1021/ic302309z.
- ↑ Yu, Hongwei; Koocher, Nathan Z.; Rondinelli, James M.; Halasyamani, P. Shiv (2018-05-22). "Pb 2 BO 3 I: A Borate Iodide with the Largest Second-Harmonic Generation (SHG) Response in the KBe 2 BO 3 F 2 (KBBF) Family of Nonlinear Optical (NLO) Materials" (in en). Angewandte Chemie International Edition 57 (21): 6100–6103. doi:10.1002/anie.201802079. PMID 29512313.
- ↑ Huang, Yi-Zhi; Wu, Li-Ming; Wu, Xin-Tao; Li, Long-Hua; Chen, Ling; Zhang, Yong-Fan (2010-09-22). "Pb 2 B 5 O 9 I: An Iodide Borate with Strong Second Harmonic Generation" (in en). Journal of the American Chemical Society 132 (37): 12788–12789. doi:10.1021/ja106066k. ISSN 0002-7863. PMID 20738133. https://pubs.acs.org/doi/10.1021/ja106066k.
- ↑ Li, Kuan; Yalikun, Alimujiang; Su, Zhi (2020). "[O 2 Pb 3 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains"] (in en). Dalton Transactions 49 (26): 8985–8990. doi:10.1039/D0DT01722A. ISSN 1477-9226. PMID 32558837. http://xlink.rsc.org/?DOI=D0DT01722A.
- ↑ Zhou, Jinjie; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wu, Yicheng (2019). "Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method" (in en). Dalton Transactions 48 (40): 14996–15001. doi:10.1039/C9DT02579K. ISSN 1477-9226. PMID 31369009. http://xlink.rsc.org/?DOI=C9DT02579K.
- ↑ Volkov, Sergey; Bubnova, Rimma; Krzhizhanovskaya, Maria; Galafutnik, Lydia (2020-12-01). "The first bismuth borate oxyiodide, Bi 4 BO 7 I: commensurate or incommensurate?". Acta Crystallographica Section B 76 (6): 992–1000. doi:10.1107/S2052520620012640. ISSN 2052-5206. PMID 33289711. Bibcode: 2020AcCrB..76..992V. https://scripts.iucr.org/cgi-bin/paper?S2052520620012640.
HI | He | ||||||||||||||||
LiI | BeI2 | BI3 | CI4 | NI3 | I2O4, I2O5, I4O9 |
IF, IF3, IF5, IF7 |
Ne | ||||||||||
NaI | MgI2 | AlI3 | SiI4 | PI3, P2I4 |
S | ICl, ICl3 |
Ar | ||||||||||
KI | CaI2 | Sc | TiI4 | VI3 | CrI3 | MnI2 | FeI2 | CoI2 | NiI2 | CuI | ZnI2 | Ga2I6 | GeI2, GeI4 |
AsI3 | Se | IBr | Kr |
RbI | SrI2 | YI3 | ZrI4 | NbI5 | Mo | Tc | Ru | Rh | Pd | AgI | CdI2 | InI3 | SnI4, SnI2 |
SbI3 | TeI4 | I | Xe |
CsI | BaI2 | HfI4 | TaI5 | W | Re | Os | Ir | Pt | AuI | Hg2I2, HgI2 |
TlI | PbI2 | BiI3 | Po | AtI | Rn | |
Fr | RaI2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
↓ | |||||||||||||||||
La | Ce | Pr | Nd | Pm | SmI2 | Eu | Gd | TbI3 | Dy | Ho | Er | Tm | Yb | Lu | |||
Ac | ThI4 | Pa | UI3, UI4 |
Np | Pu | Am | Cm | Bk | Cf | EsI3 | Fm | Md | No | Lr |
![]() | Original source: https://en.wikipedia.org/wiki/Borate iodide.
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