Chemistry:Borate fluoride

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The borate fluorides or fluoroborates are compounds containing borate or complex borate ions along with fluoride ions that form salts with cations such as metals. They are in the broader category of mixed anion compounds. They are not to be confused with tetrafluoroborates (BF4) or the fluorooxoborates which have fluorine bonded to boron.

Examples

formula name mw system space group unit cell Å volume Å3 density comment references
Be2(BO3)(OH,F) · H2O Berborite trigonal P3 a = 4.434, c = 5.334 90.82 colourless

Uniaxial (-) nω = 1.580 nε = 1.485

Max birefringence δ = 0.095

[1]

γ‐Be2BO3F γ‐BBF 95.83 trigonal R32 a=4.4418 c=19.909 Z=3 340.17 1.946 Uniaxial (-) SHG 2.3 × KDP
NH4Be2BO3F2 ABBF 132.87 trigonal R32 a=4.4398 c=12.4697 Z=3 212.87 2.243 Uniaxial (-) no=1.49389 ne=1.41919 at 636 nm [2]
NaBe2BO3F2 sodium beryllium borate fluoride (NBBF) C2 a=12.643 b=8.729 c=7.591 β=113.6° 768 double layers of borate rings sandwiching barium atoms. Between pairs of double layers are sodium ions with fluoride. [3]
Mg2(BO3)(F,OH) Pertsevite-(F) orthorhombic Pna21 a = 20.49, b = 4.571, c = 11.89 Z=16 1,113.6 Density 3.12

transparent

Biaxial (+) nα = 1.609 nβ = 1.620 nγ = 1.642

2V: 65°

Max birefringence: δ = 0.033

[4]
Mg3(BO3)(F,OH)3 Fluoborite hexagonal a = 8.8, c = 3.1 208 colourless

Uniaxial (-) nω = 1.570 nε = 1.534

Max birefringence δ = 0.036

[5]
Mg3(OH)[B(OH)4]2(SO4)F sulfoborite orthorhombic Pnma a=10.132 b=12.537 c=7.775 987.6 Biaxial (-) nα = 1.527 nβ = 1.536 nγ = 1.551

2V 79°

Max birefringence δ = 0.024

[6]
Na6Mg3B10O18F6 monoclinic P21/c a=13.420 b=6.400 c=10.701 β=90.693° band gap 5.40 eV; birefringence Δn = 0.039 at 1064 nm [7]
Al6(BO3)5F3

Jeremejevite

hexagonal

P63/m

a = 8.5591, c = 8.1814

519

density 3.28

Uniaxial (-) nω = 1.653 nε = 1.640

Max birefringence δ = 0.013

[8][9]
Al8(BO3)4(B2O5)F8 704.7 tetragonal P42/mmc a=9.134 c=19.112 Z=4 1,595 density 2.935 colourless [8]
Na(Mg3)Al6(Si6O18)(BO3)3(OH)3F Fluor-dravite trigonal R3m a = 15.955, c = 7.153 Z=3 1,577 density 3.120

dark brown

Uniaxial (-) nω = 1.645(2) nε = 1.621(2)

Max birefringence δ = 0.024

[10]
Na(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3F Fluor-elbaite trigonal R3m a = 15.8933, c = 7.1222 1,558 blue green

Uniaxial (-)

[11]
K6B12O19F4 744.32 orthorhombic Pnma a =15.291 b =7.707 c =8.672 Z=2 1022.0 2.419 [12]
KBe2BO3F2 KBBF hexagonal R32 a=4.427 c=18.744 318.3 2.40 Be2BO6F2 rings SHG 1.2 × KDP; UV cutoff 147 nm [13]
Li3CaB2O5F 363.04 orthorhombic Pnma a=25.685 b=3.4697 c=5.4404 Z=2 484.84 2.487 colourless [14]
Li5Ca9(BO3)7F2 P1
NaCaBe2B2O6F [15]
KCaBe2B2O6F 467.64 P3_1c a=4.705 c=14.554 Z=2 279.1 2.783 [16]
Ca(Li2Al)Al6(Si6O18)(BO3)3(OH)3F Fluor-liddicoatite trigonal R3m a = 15.875, c = 7.126 Z=3 1,555 density 3.02

Uniaxial (-) nω = 1.637 nε = 1.621

Max birefringence δ = 0.016

[17]
CaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3F Fluor-uvite trigonal R3m a = 15.954, c = 7.214 Z=3 1,590 black

Uniaxial nω = 1.637 - 1.668 nε = 1.619 - 1.639

Max birefringence δ = 0.018 - 0.029

[18]
KCaBe2B2O6F
Sc2F2(B2O5) 229.54 orthorhombic Pbam a=9.667 b=14.199 c=4.0395 Z=4 554.4 2.750 colourless [19]
K11Sc5(B5O10)4F6 orthorhombic Fdd2 a 56.769 b 12.207 c 12.6088 transparent to <190 nm [20]
Na(Mn2+)3Al6(Si6O18)(BO3)3(OH)3F Fluor-tsilaisite trigonal R3m a = 15.9398, c = 7.1363 1,570 greenish yellow

Uniaxial (-)

[21]
NaFe3Al6Si6B3O30F [8]
Na(Fe2+3)Al6(Si6O18)(BO3)3(OH)3F Fluor-schorl trigonal R3m a = 16.005, c = 7.176 Z=3 1,591.9 black

Uniaxial (-) nω = 1.660 - 1.661 nε = 1.636 - 1.637

Max birefringence δ = 0.024

[22]
Na(Fe3+3)Al6(Si6O18)(BO3)3O3F Fluor-buergerite trigonal R3m a = 15.8692, c = 7.1882 1,568 density 3.311

brown

Uniaxial (-) nω = 1.735 nε = 1.655

Birefringence 0.080

[23]
Ca(Fe2+)3MgAl5(Si6O18)(BO3)3(OH)3F Fluor-feruvite [24]
KCaZn2(BO3)2F
Li6RbB2O6F 263.73 orthorhombic Pnma a=8.41 b=15.96 c=5.08 Z=2 682 2.568 [25]
RbBe2BO3F2 RBBF Trigonal R32 a=4.434 c=19.758 z=3 also contains BeO3F tetrahedra and BO3. It transmits radiation from 180 to 3500 nm. [26]
Rb18Mg6(B5O10)3(B7O14)2F monoclinic C2/c a=11.06 b=19.70 c=31.01 β=90.13° [27]
RbCaBe2B2O6F Trigonal R32 [28]
KSrBe2B2O6F [15]
LiSr3Be3B3O9F4 [29]
NaSr3Be3B3O9F4 [30]
K3Sr3Li2Al4B6O20F SHG 4 × KDP; 170 nm UV cutoff [8]
Ca(Y,REE,Ca,Na,Mn)15Fe2+(P,Si)Si6B3O34F14 Proshchenkoite-(Y) trigonal R3m a = 10.7527, c = 27.4002 2,743.6 brownish [31]
(Y,REE,Ca,Na)15(Al,Fe3+)(CaxAs3+1−x)(Si,As5+)Si6B3(O,F)48 Hundholmenite-(Y) trigonal R3m a = 10.675, c = 27.02 Z=3 2,667 density 5.206

brownish

Uniaxial (-)

[32]
(Na,Ca)3(Y,Ce)12Si6B2O27F14 Okanoganite-(Y) trigonal R3m a = 10.7108, c = 27.040 4.35 Tan coloured

Uniaxial (-) nω = 1.753 nε = 1.740

Max birefringence δ = 0.013

[33]
? Y5(SiO4,BO4)3(O,OH,F) Tritomite-(Y) ?hexagonal a = 9.32, c = 6.84 3.05-3.4 isotropic

n = 1.627 - 1.685

Cd8B5O15F 1212.25 cubic Fd3m a = 13.972 Z = 8 2,727 5.904 colourless [34]
CdZn2KB2O6F
Li3Cs6Al2B14O28F 1490.58 orthorhombic Pnma a=21.8412 b=19.8875 c=7.1577 Z=4 3109.1 3.184 [35]
CsBe2BO3F2 247.74 trigonal R32 a=4.4575 c=21.310 Z=3 366.7 3.366 colourless [36]
Cs18Mg6(B5O10)3(B7O14)2F monoclinic C2/c a=11.234 b=20.11 c=32.12 β=90.225° [27]
CsCaBe2B2O6F trigonal R32 [37]
BaBOF3 221.15 monoclinic P21/c a = 4.620 b = 15.186 c = 4.426 β = 92.045° Z=4 310.3 contains chains of -OB(F2)- and a double chain of BaF [38]
Ba5(BO3)3F [39]
Li2BaSc(BO3)2F 332.80 hexagonal P63/m a=4.895 c=14.346 297.7 3.713 [40]
LiBa12(BO3)7F4 I4/mcm
BaBe2BO3F3 271.16 hexagonal P63 a=7.628 c=13.990 Z=6 704.9 3.832 UV cutoff <185 nm; birefringence 0,081 at 200 nm [41]
NaBa12(BO3)7F4 I4/mcm
BaMgBe2(BO3)2F2 BMBBF 335.283 trigonal P3c1 a=4.5898 c=15.348 280.01 3.976 colourless [Be2B3O6F2]∞ [42]
Ba3.75MgB7O14F2.5 886.50 monoclinic C2/c a 16.611 b 13.677 c 15.141 β 121.239° Z=8 2941.0 4.004 transparent > 203 nm; birefringence 0.081@546 nm [43]
BaAl(BO3)F2 hexagonal P6 a=4.8879 c=9.403 Z=2 194.5 UV cutoff 165 nm [44]
K3Ba3Li2Al4B6O20F [8]
K5Ba10(BO3)8F trigonal R3c a = 15.293, c = 22.699 Z = 6 [45]
KBa7Mg2B14O28F5 monoclinic C2/c a = 16.638 b = 13.609 c = 15.214 β = 121.309° Z=4 2943.3 3.934 colourless [46]
BaCaBe2(BO3)2F2 BCBBF trigonal P3c1 a=4.6931 c=16.049 306.12 3.808 colourless [Be2B3O6F2]∞ [42]
Li2BaSc(BO3)2F hexagonal P63/m a=4.895 c=14.346 [47]
Ba3Zn(BO3)(B2O5)F 656.82 monoclinic P21/c a = 15.179 b = 7.0064 c = 8.763 β = 100.15° Z=4 917.4 4.755 colourless [48]
Ba4Zn2(BO3)2(B2O5)F2 937.34 monoclinic C2/c a=20.39 b=4.998 c=13.068 β = 192.59 Z=44 1,331 4.679 colourless [48]
BaZnBe2(BO3)2F2 376.35 trigonal P3 a = 4.5998, c = 7.7037 Z = 1 141.16 4.427 colourless [49]
Rb3Ba3Li2Al4B6O20F [8]
Ba1.09Pb0.91Be2(BO3)2F2 BPBBF trigonal P3m1 a = 4.7478 c = 8.386, Z = 1 163.70 UV absorption edge=279.1 nm; birefringence 0.054 at 546.1 nm; 2D [Be3B3O6F3]∞ layer [50]
LiBa2Pb(BO3)2F orthorhombic Pmmn a=5.487 b=15.96 c=4.034 [47]
KNa3Na6Ca2Ba6Mn6(Ti4+,Nb)6B12Si36O114(O,OH,F)11 Tienshanite hexagonal P6/m a = 16.785, c = 10.454 Z=1 2,551 pale olive green

Uniaxial (-) nω = 1.666 nε = 1.653

Max birefringence δ = 0.013

[51]
Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11 Laptevite-(Ce) trigonal R3m a = 10.804, c = 27.726 Z=3 2,803 density 4.61

dark brown

Uniaxial (-) nω = 1.741(3) nε = 1.720(3)

Max birefringence δ = 0.021

[52]
Ba(Y,Ce)6Si3B6O24F2 Cappelenite-(Y) trigonal P3 a = 10.67, c = 4.68 Z=1 461 4.407 greenish brown [53]
CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11 Arrheniusite-(Ce) trigonal R3m a = 10.8082, c = 27.5196 [54]
Gd4(BO2)O5F orthorhombic Pmmn a=15.746 b=3.8142 c=6.609 Z=2 396.9 6.45 colourless [55]
Gd2(BO3)F3
Gd3(BO3)2F3
Gd4[B4O11]F2
Eu5(BO3)3F orthorhombic Pnma a=7.225 b=14.124 c=9.859 Z=4 1006.1 6.306 yellow [56]
TlBe2BO3F2 Trigonal R32 a=4.4387 c=19.942 Z=3 340.27 4.673 colourless [57]
LiBa2Pb(BO3)2F orthorhombic Pmmn a=5.487 b=15.97 c=4.034 353.4 5.887 colourless [58]
(Ca,Ce,La,Th)15As5+(As3+0.5,Na0.5)Fe3+Si6B4O40F7 Vicanite-(Ce) trigonal R3m a=10.881 c=27.33 2,766 4.82 greenish yellow

Uniaxial (-) nω = 1.757 nε = 1.722

Max birefringence δ = 0.035

[59]

References

  1. ↑ "Berborite". https://www.mindat.org/min-629.html. 
  2. ↑ Peng, Guang; Ye, Ning; Lin, Zheshuai; Kang, Lei; Pan, Shilie; Zhang, Min; Lin, Chensheng; Long, Xifa et al. (2018-07-16). "NH 4 Be 2 BO 3 F 2 and γ-Be 2 BO 3 F: Overcoming the Layering Habit in KBe 2 BO 3 F 2 for the Next-Generation Deep-Ultraviolet Nonlinear Optical Materials" (in en). Angewandte Chemie 130 (29): 9106–9110. doi:10.1002/ange.201803721. Bibcode: 2018AngCh.130.9106P. http://doi.wiley.com/10.1002/ange.201803721. 
  3. ↑ Mei, Linfeng; Wang, Yebin; Chen, Chunagtian (January 1994). "Crystal structure of sodium beryllium borate fluoride". Materials Research Bulletin 29 (1): 81–87. doi:10.1016/0025-5408(94)90108-2. 
  4. ↑ "Pertsevite-(F)". https://www.mindat.org/min-25644.html. 
  5. ↑ "Fluoborite". https://www.mindat.org/min-1566.html. 
  6. ↑ "Sulfoborite". https://www.mindat.org/min-3823.html. 
  7. ↑ Cheng, Bingliang; Ma, Wenjuan; Tudi, Abudukadi; Liu, Changyou; Long, Xifa; Yang, Yun (2023-07-26). "Introduction of the [B–O/F Units Enhances the Band Gap and Birefringence from Na 6 Mg 3 B 10 O 18 F 6 to K 3 NaB 10 O 16 F 2"] (in en). Inorganic Chemistry 62 (31): 12187–12191. doi:10.1021/acs.inorgchem.3c01954. ISSN 0020-1669. PMID 37494127. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c01954. 
  8. ↑ 8.0 8.1 8.2 8.3 8.4 8.5 Wang, Ya; Han, Jian; Huang, Junben; Yang, Zhihua; Pan, Shilie (2020-01-06). "Al 8 (BO 3 ) 4 (B 2 O 5 )F 8 : A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups" (in en). Inorganic Chemistry 59 (1): 810–817. doi:10.1021/acs.inorgchem.9b03067. ISSN 0020-1669. PMID 31877030. https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.9b03067. 
  9. ↑ "Jeremejevite". https://www.mindat.org/min-2090.html. 
  10. ↑ "Fluor-dravite". https://www.mindat.org/min-39892.html. 
  11. ↑ "Fluor-elbaite". https://www.mindat.org/min-39706.html. 
  12. ↑ Huang, Shuzhao; Zhu, Liang; Kruglov, Ivan; Yang, Yun; Yang, Zhihua; Pan, Shilie (2023-05-09). "Two Ultraviolet Optical Crystals K 6 B 12 O 19 F 4 and K 12 B 28 O 48 : The Effects of Metal Cations Size and the F Ions on the Structure" (in en). Inorganic Chemistry 62 (20): 7599–7604. doi:10.1021/acs.inorgchem.3c00519. ISSN 0020-1669. PMID 37158437. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c00519. 
  13. ↑ Mei, L.; Huang, X.; Wang, Y.; Wu, Q.; Wu, B.; Chen, C. (January 1995). "Crystal structure of KBe 2 BO 3 F 2" (in en). Zeitschrift für Kristallographie 210 (2): 93–95. doi:10.1524/zkri.1995.210.2.93. ISSN 0044-2968. Bibcode: 1995ZK....210...93M. https://www.degruyter.com/document/doi/10.1524/zkri.1995.210.2.93/html. 
  14. ↑ Ding, Mengmeng; Xu, JingJing; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2020). "Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways" (in en). Dalton Transactions 49 (35): 12184–12188. doi:10.1039/D0DT02423F. ISSN 1477-9226. PMID 32930685. http://xlink.rsc.org/?DOI=D0DT02423F. 
  15. ↑ 15.0 15.1 Huang, Hongwei; Yao, Jiyong; Lin, Zheshuai; Wang, Xiaoyang; He, Ran; Yao, Wenjiao; Zhai, Naixia; Chen, Chuangtian (2011-12-27). "Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be 2 B 2 O 6 F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)" (in en). Chemistry of Materials 23 (24): 5457–5463. doi:10.1021/cm202870q. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm202870q. 
  16. ↑ Huang, Hongwei; Yao, Jiyong; Lin, Zheshuai; Wang, Xiaoyang; He, Ran; Yao, Wenjiao; Zhai, Naixia; Chen, Chuangtian (2011-12-27). "Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be 2 B 2 O 6 F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)" (in en). Chemistry of Materials 23 (24): 5457–5463. doi:10.1021/cm202870q. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm202870q. 
  17. ↑ "Fluor-liddicoatite". https://www.mindat.org/min-41296.html. 
  18. ↑ "Fluor-uvite". https://www.mindat.org/min-43562.html. 
  19. ↑ Tang, Ru-Ling; Xu, Wei; Xie, Wei-Jie; Hu, Chun-Li (2022). "Sc 2 F 2 (B 2 O 5 ): a deep ultraviolet scandium borate fluoride exhibiting large birefringence induced by the synergistic effect of B 2 O 5 and ScO n F 2 groups" (in en). Inorganic Chemistry Frontiers 9 (20): 5153–5160. doi:10.1039/D2QI01484J. ISSN 2052-1553. http://xlink.rsc.org/?DOI=D2QI01484J. 
  20. ↑ Zhang, Qianzhen; An, Ran; Tudi, Abudukadi; Yang, Zhihua; Long, Xifa; Yang, Yun (2023-09-04). "Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge" (in en). Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c02367. ISSN 0020-1669. PMID 37665686. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c02367. 
  21. ↑ "Fluor-tsilaisite". https://www.mindat.org/min-43353.html. 
  22. ↑ "Fluor-schorl". https://www.mindat.org/min-29118.html. 
  23. ↑ "Fluor-buergerite". https://www.mindat.org/min-818.html. 
  24. ↑ "Fluor-feruvite". https://www.mindat.org/min-41785.html. 
  25. ↑ Wu, Hongping; Yu, Hongwei; Bian, Qiang; Yang, Zhihua; Han, Shujuan; Pan, Shilie (2014-12-15). "Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method" (in en). Inorganic Chemistry 53 (24): 12686–12688. doi:10.1021/ic502625b. ISSN 0020-1669. PMID 25437774. https://pubs.acs.org/doi/10.1021/ic502625b. 
  26. ↑ Chen, Chuangtian; Luo, Siyang; Wang, Xiaoyang; Wang, Guiling; Wen, Xiaohong; Wu, Huaxing; Zhang, Xin; Xu, Zuyan (8 July 2009). "Deep UV nonlinear optical crystal:RbBe_2(BO_3)F_2". Journal of the Optical Society of America B 26 (8): 1519. doi:10.1364/JOSAB.26.001519. Bibcode: 2009JOSAB..26.1519C. 
  27. ↑ 27.0 27.1 Wang, Zheng; Zhang, Min; Su, Xin; Pan, Shilie; Yang, Zhihua; Zhang, Hui; Liu, Lu (2015-01-19). "Q 18 Mg 6 (B 5 O 10 ) 3 (B 7 O 14 ) 2 F (Q=Rb and Cs): New Borates Containing Two Large Isolated Polyborate Anions with Similar Topological Structures" (in en). Chemistry - A European Journal 21 (4): 1414–1419. doi:10.1002/chem.201404738. PMID 25414057. https://onlinelibrary.wiley.com/doi/10.1002/chem.201404738. 
  28. ↑ Liu, Lili; Yang, Yun; Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie; Wu, Kui (2016-08-25). "K 5 Ba 10 (BO 3 ) 8 F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure" (in en). The Journal of Physical Chemistry C 120 (33): 18763–18770. doi:10.1021/acs.jpcc.6b05489. ISSN 1932-7447. https://pubs.acs.org/doi/10.1021/acs.jpcc.6b05489. 
  29. ↑ Guo, Ruixin; Bai, Lei; Wu, Tong; Fan, Feidi; Liu, Lijuan; Wang, Xiaoyang (January 2023). "Growth and characterizations of a new nonlinear optical crystal for 266 nm laser generation: LiSr3Be3B3O9F4" (in en). Journal of Crystal Growth 602: 126971. doi:10.1016/j.jcrysgro.2022.126971. Bibcode: 2023JCrGr.60226971G. https://linkinghub.elsevier.com/retrieve/pii/S0022024822004535. 
  30. ↑ Liu, Lijuan; Wang, Lirong; Guo, Ruixin; Hou, Zhanyu; Fang, Zhi; Wang, Xiaoyang (July 2020). "NaSr3Be3B3O9F4 crystal growth and fourth harmonic generation at 266 nm" (in en). Journal of Crystal Growth 542: 125689. doi:10.1016/j.jcrysgro.2020.125689. Bibcode: 2020JCrGr.54225689L. https://linkinghub.elsevier.com/retrieve/pii/S0022024820302128. 
  31. ↑ "Proshchenkoite-(Y)". https://www.mindat.org/min-35971.html. 
  32. ↑ "Hundholmenite-(Y)". https://www.mindat.org/min-29098.html. 
  33. ↑ "Okanoganite-(Y)". https://www.mindat.org/min-2966.html. 
  34. ↑ Yang, Yun; Dong, Xiaoyu; Pan, Shilie (2016). "New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method" (in en). Dalton Transactions 45 (16): 7008–7013. doi:10.1039/C6DT00621C. ISSN 1477-9226. PMID 26988597. http://xlink.rsc.org/?DOI=C6DT00621C. 
  35. ↑ Li, Xingqi; Chu, Dongdong; Jin, Wenqi; Yang, Zhihua; Pan, Shilie; Mutailipu, Miriding (2022-08-08). "Rearrangement of [B 2 O 5 Dimers within [B 7 O 14 ] Clusters Enables Enhanced Optical Anisotropy in Li 3 Cs 6 Al 2 B 14 O 28 F"] (in en). Inorganic Chemistry 61 (31): 12067–12072. doi:10.1021/acs.inorgchem.2c02347. ISSN 0020-1669. PMID 35894746. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c02347. 
  36. ↑ McMillen, Colin D.; Hu, Jia; VanDerveer, Donald; Kolis, Joseph W. (2009-08-01). "Trigonal structures of A Be 2 BO 3 F 2 ( A = Rb, Cs, Tl) crystals". Acta Crystallographica Section B Structural Science 65 (4): 445–449. doi:10.1107/S0108768109024161. ISSN 0108-7681. PMID 19617679. http://scripts.iucr.org/cgi-bin/paper?S0108768109024161. 
  37. ↑ Liu, Lili; Yang, Yun; Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie; Wu, Kui (2016-08-25). "K 5 Ba 10 (BO 3 ) 8 F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure" (in en). The Journal of Physical Chemistry C 120 (33): 18763–18770. doi:10.1021/acs.jpcc.6b05489. ISSN 1932-7447. https://pubs.acs.org/doi/10.1021/acs.jpcc.6b05489. 
  38. ↑ Jiang, Dequan; Wang, Ying; Li, Hao; Yang, Zhihua; Pan, Shilie (2018). "BaBOF3 : a new aurivillius-like borate containing two types of F atoms". Dalton Transactions 47 (15): 5157–5160. doi:10.1039/C8DT00403J. PMID 29557465. 
  39. ↑ Rashchenko, Sergey V.; Bekker, Tatyana B.; Bakakin, Vladimir V.; Seryotkin, Yurii V.; Kokh, Alexander E.; Gille, Peter; Popov, Arthur I.; Fedorov, Pavel P. (4 July 2013). "A new mechanism of anionic substitution in fluoride borates". Journal of Applied Crystallography 46 (4): 1081–1084. doi:10.1107/S0021889813015756. 
  40. ↑ Chen, Yanna; Zhang, Min; Hu, Cong; Wu, Hongping; Yang, Zhihua; Pan, Shilie (2018-10-17). "Li 2 BaSc(BO 3 ) 2 F and LiBa 2 Pb(BO 3 ) 2 F with Layered Structures featuring Special Li−O/F Configurations" (in en). Chemistry - A European Journal 24 (58): 15477–15481. doi:10.1002/chem.201804126. PMID 30230058. http://doi.wiley.com/10.1002/chem.201804126. 
  41. ↑ Guo, Shu; Jiang, Xingxing; Liu, Lijuan; Xia, Mingjun; Fang, Zhi; Wang, Xiaoyang; Lin, Zheshuai; Chen, Chuangtian (2016-12-27). "BaBe 2 BO 3 F 3 : A KBBF-Type Deep-Ultraviolet Nonlinear Optical Material with Reinforced [Be 2 BO 3 F 2 ∞ Layers and Short Phase-Matching Wavelength"] (in en). Chemistry of Materials 28 (24): 8871–8875. doi:10.1021/acs.chemmater.6b04403. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.6b04403. 
  42. ↑ 42.0 42.1 Guo, Shu; Jiang, Xingxing; Xia, Mingjun; Liu, Lijuan; Fang, Zhi; Huang, Qian; Wu, Ruofei; Wang, Xiaoyang et al. (2017-10-02). "Structural Design of Two Fluorine–Beryllium Borates BaMBe2(BO3)2F2 (M = Mg, Ca) Containing Flexible Two-Dimensional [Be3B3O6F3∞ Single Layers without Structural Instability Problems"]. Inorganic Chemistry 56 (19): 11451–11454. doi:10.1021/acs.inorgchem.7b01627. ISSN 0020-1669. PMID 28885824. https://doi.org/10.1021/acs.inorgchem.7b01627. 
  43. ↑ Bai, Yunjie; Wang, Xinyue; Huang, Hongbo; Dou, Danyang; Chen, Cheng; Zhang, Bingbing; Wang, Ying (2023-09-08). "Ba 3.75 MgB 7 O 14 F 2.5 : A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence" (in en). Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c02532. ISSN 0020-1669. PMID 37681248. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c02532. 
  44. ↑ Hu, ζ G.; Maramatsu, κ.; Kanehisa, ν.; Yoshimura, M.; Mori, Y.; Sasaki, T.; Kai, Y. (December 2003). "Reinvestigation of the crystal structure of barium aluminum borate difluoride, BaAlBO3F2, a new nonlinear optical material". Zeitschrift für Kristallographie - New Crystal Structures 218 (JG): 1–2. doi:10.1524/ncrs.2003.218.jg.1. ISSN 2197-4578. https://www.degruyter.com/document/doi/10.1524/ncrs.2003.218.jg.1/html. 
  45. ↑ Liu, Lili; Yang, Yun; Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie; Wu, Kui (2016-08-25). "K 5 Ba 10 (BO 3 ) 8 F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure" (in en). The Journal of Physical Chemistry C 120 (33): 18763–18770. doi:10.1021/acs.jpcc.6b05489. ISSN 1932-7447. https://pubs.acs.org/doi/10.1021/acs.jpcc.6b05489. 
  46. ↑ Li, R. K.; Chen, Peng (2010-01-15). "KBa 7 Mg 2 B 14 O 28 F 5 , a new borate with an unusual heptaborate group and double perovskite unit". Acta Crystallographica Section C Crystal Structure Communications 66 (1): i7–i8. doi:10.1107/S0108270109054341. ISSN 0108-2701. PMID 20048410. http://scripts.iucr.org/cgi-bin/paper?S0108270109054341. 
  47. ↑ 47.0 47.1 Chen, Yanna; Zhang, Min; Hu, Cong; Wu, Hongping; Yang, Zhihua; Pan, Shilie (2018-10-17). "Li 2 BaSc(BO 3 ) 2 F and LiBa 2 Pb(BO 3 ) 2 F with Layered Structures featuring Special Li−O/F Configurations" (in en). Chemistry – A European Journal 24 (58): 15477–15481. doi:10.1002/chem.201804126. ISSN 0947-6539. PMID 30230058. https://onlinelibrary.wiley.com/doi/10.1002/chem.201804126. 
  48. ↑ 48.0 48.1 Mutailipu, Miriding; Su, Xin; Zhang, Min; Yang, Zhihua; Pan, Shilie (2017). "Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units" (in en). Inorganic Chemistry Frontiers 4 (2): 281–288. doi:10.1039/C6QI00467A. ISSN 2052-1553. http://xlink.rsc.org/?DOI=C6QI00467A. 
  49. ↑ Guo, Ruixin; Liu, Xiaomeng; Tao, Ce; Tang, Changcheng; Xia, Mingjun; Liu, Lijuan; Lin, Zheshuai; Wang, Xiaoyang (2021). "BaZnBe 2 (BO 3 ) 2 F 2 : a novel zinc-beryllium borate with SBBO-type structure overcoming the polymorphism problem" (in en). Dalton Transactions 50 (6): 2138–2142. doi:10.1039/D0DT04153J. ISSN 1477-9226. PMID 33491694. http://xlink.rsc.org/?DOI=D0DT04153J. 
  50. ↑ Guo, Ruixin; Guo, Shu; Xia, Mingjun; Liu, Lijuan; Li, Minjuan; Zhao, Sangen; Wang, Xiaoyang (2023-02-20). "Ba 1.09 Pb 0.91 Be 2 (BO 3 ) 2 F 2 : The First Pb-Containing Beryllium Borate Fluoride with Trigonal Prismatic PbO 6 and 2D [Be 3 B 3 O 6 F 3 ∞ Layers"] (in en). Inorganic Chemistry 62 (9): 3860–3865. doi:10.1021/acs.inorgchem.2c04122. ISSN 0020-1669. PMID 36802565. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c04122. 
  51. ↑ "Tienshanite". https://www.mindat.org/min-3958.html. 
  52. ↑ "Laptevite-(Ce)". https://www.mindat.org/min-42866.html. 
  53. ↑ "Cappelenite-(Y)". https://www.mindat.org/min-889.html. 
  54. ↑ "Arrheniusite-(Ce)". https://www.mindat.org/min-54242.html. 
  55. ↑ Höppe, Henning A. (1 November 2015). "Gd4(BO2)O5F – a gadolinium borate fluoride oxide comprising a linear BO2 moiety". Zeitschrift für Naturforschung B 70 (11): 769–774. doi:10.1515/znb-2015-0112. 
  56. ↑ Kazmierczak, Karolina; Höppe, Henning A. (June 2010). "Synthesis, Crystal Structure and Optical Spectra of Europium Borate Fluoride Eu5(BO3)3F" (in en). European Journal of Inorganic Chemistry 2010 (18): 2678–2681. doi:10.1002/ejic.201000105. http://doi.wiley.com/10.1002/ejic.201000105. 
  57. ↑ McMillen, Colin D.; Hu, Jia; VanDerveer, Donald; Kolis, Joseph W. (2009-08-01). "Trigonal structures of A Be 2 BO 3 F 2 ( A = Rb, Cs, Tl) crystals". Acta Crystallographica Section B Structural Science 65 (4): 445–449. doi:10.1107/S0108768109024161. ISSN 0108-7681. PMID 19617679. http://scripts.iucr.org/cgi-bin/paper?S0108768109024161. 
  58. ↑ Chen, Yanna; Zhang, Min; Hu, Cong; Wu, Hongping; Yang, Zhihua; Pan, Shilie (2018-10-17). "Li 2 BaSc(BO 3 ) 2 F and LiBa 2 Pb(BO 3 ) 2 F with Layered Structures featuring Special Li−O/F Configurations" (in en). Chemistry - A European Journal 24 (58): 15477–15481. doi:10.1002/chem.201804126. PMID 30230058. http://doi.wiley.com/10.1002/chem.201804126. 
  59. ↑ "Vicanite-(Ce)". https://www.mindat.org/min-7354.html. 
Salts and covalent derivatives of the fluoride ion
HF He
LiF BeF2 BF
BF3
B2F4 		CF4
other compounds 		NF3
FN3
N2F2
N2F4
NF5§ 		F2O
F2O2
other compounds 		F2 Ne
NaF MgF2 AlF
AlF3 		SiF4 P2F4
PF3
PF5 		S2F2
SF2
SF4
SF6 		ClF
ClF3
ClF5 		Ar
KF CaF
CaF2 		ScF3 TiF2
TiF3
TiF4 		VF2
VF3
VF4
VF5 		CrF2
CrF3
CrF4
CrF5
CrF6§ 		MnF2 FeF2
FeF3 		CoF2
CoF3 		NiF2 CuF
CuF2 		ZnF2 GaF2
GaF3 		GeF2
GeF4 		AsF3
AsF5 		Se2F2
SeF4
SeF6 		BrF
BrF3
BrF5 		KrF2
RbF SrF
SrF2 		YF3 ZrF3
ZrF4 		NbF4
NbF5 		MoF2
MoF3
MoF4
MoF5
MoF6 		TcF4
TcF6 		RuF3
RuF5
RuF6 		RhF3
RhF5
RhF6 		PdF2 AgF CdF2 InF
InF2
InF3 		SnF2
SnF4 		SbF3
SbF5 		Te3F2
TeF4
TeF6 		IF
IF3</br>IF5</br>IF7 		XeF2
XeF4
XeF6
CsF BaF2   HfF4 TaF5 WF2
WF3
WF4
WF5
WF6 		Re3F9
ReF4
ReF5
ReF6
ReF7 		OsF4
OsF5
OsF6 		IrF2
IrF3
IrF4
IrF5
IrF6 		PtF2
PtF4
PtF5
PtF6 		AuF
AuF3
Au2F10
AuF5•F2 		Hg2F2
HgF2
HgF4 		TlF PbF2
PbF4 		BiF3
BiF5 		PoF2
PoF4
PoF6 		AtF RnF2
FrF RaF2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
LaF3 CeF3
CeF4 		PrF3 NdF2,
NdF3 		PmF3 SmF2,
SmF3 		EuF2,
EuF3 		GdF3 TbF3 DyF2,
DyF3 		HoF3 ErF3 TmF2
TmF3 		YbF2
YbF3 		LuF3
AcF3 ThF4 PaF5 UF3
UF4
UF5
UF6 		NpF4
NpF6 		PuF3
PuF6 		AmF2
AmF3 		CmF3 BkF3 CfF3 EsF3 Fm Md No LrF3

§ means the substance has not been made.



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