Chemistry:Neptunium(III) iodide
From HandWiki
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3D model (JSmol)
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PubChem CID
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| Properties | |
| I3Np | |
| Molar mass | 618 g·mol−1 |
| Appearance | brown solid[1] |
| Density | 6.82 g·cm−3[2] |
| Melting point | 767 °C[1] |
| Structure | |
| orthorhombic | |
| Ccmm (No. 63) | |
a = 430 pm, b = 1403 pm, c = 995 pm
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| Related compounds | |
Other anions
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neptunium(III) fluoride neptunium(III) chloride neptunium(III) bromide |
Other cations
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uranium(III) iodide plutonium(III) iodide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Neptunium(III) iodide is the iodide of neptunium with the chemical formula NpI3.
Preparation
Neptunium(III) iodide can be produced by the reaction of neptunium dioxide and aluminium iodide:[3]
- 6 NpO
2 + 8 AlI
3 → 6 NpI
3 + 4 Al
2O
3 + 3 I
2
Properties
Neptunium(III) iodide is a hygroscopic brown solid with a melting point of 767 °C. It is orthorhombic (plutonium(III) bromide structure), space group Ccmm (No. 63), lattice parameters a = 430pm, b = 1403pm and c = 995pm.[4]
References
- ↑ 1.0 1.1 Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils, ed., Inorganic Chemistry, San Diego/Berlin: Academic Press/De Gruyter, p. 1969, ISBN 0-12-352651-5
- ↑ Gmelins Handbuch der anorganischen Chemie, System Nr. 71, Transurane, Teil C, S. 154–155.
- ↑ Georg Brauer (Hrsg.), unter Mitarbeit von Marianne Baudler u. a.: Handbuch der Präparativen Anorganischen Chemie. 3., umgearbeitete Auflage. Band II, Ferdinand Enke, Stuttgart 1978, ISBN 3-432-87813-3, S. 1269.
- ↑ C. Keller: Die Chemie des Neptuniums. In: Fortschr. chem. Forsch., 1969/70, 13/1, S. 69.
External reading
- Yoshida, Zenko; Johnson, Stephen G.; Kimura, Takaumi; Krsul, John R. (2006), Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean, eds., "Neptunium" (in en), The Chemistry of the Actinide and Transactinide Elements (Dordrecht: Springer Netherlands): pp. 699–812, doi:10.1007/1-4020-3598-5_6, ISBN 978-1-4020-3555-5, http://link.springer.com/10.1007/1-4020-3598-5_6, retrieved 2023-09-15
- Keller, C. (1969), "Die Chemie des Neptuniums" (in de), Anorganische Chemie, Fortschritte der Chemischen Forschung (Berlin/Heidelberg: Springer-Verlag) 13/1: pp. 1–124, doi:10.1007/bfb0051170, ISBN 978-3-540-04488-8, http://link.springer.com/10.1007/BFb0051170, retrieved 2023-09-15
| HI | He | ||||||||||||||||
| LiI | BeI2 | BI3 | CI4 | NI3 | I2O4, I2O5, I4O9 |
IF, IF3, IF5, IF7 |
Ne | ||||||||||
| NaI | MgI2 | AlI3 | SiI4 | PI3, P2I4 |
S | ICl, ICl3 |
Ar | ||||||||||
| KI | CaI2 | Sc | TiI4 | VI3 | CrI3 | MnI2 | FeI2 | CoI2 | NiI2 | CuI | ZnI2 | Ga2I6 | GeI2, GeI4 |
AsI3 | Se | IBr | Kr |
| RbI | SrI2 | YI3 | ZrI4 | NbI5 | Mo | Tc | Ru | Rh | Pd | AgI | CdI2 | InI3 | SnI4, SnI2 |
SbI3 | TeI4 | I | Xe |
| CsI | BaI2 | HfI4 | TaI5 | W | Re | Os | Ir | Pt | AuI | Hg2I2, HgI2 |
TlI | PbI2 | BiI3 | Po | AtI | Rn | |
| Fr | RaI2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La | Ce | Pr | Nd | Pm | SmI2 | Eu | Gd | TbI3 | Dy | Ho | Er | Tm | Yb | Lu | |||
| Ac | ThI4 | Pa | UI3, UI4 |
Np | Pu | Am | Cm | Bk | Cf | EsI3 | Fm | Md | No | Lr | |||
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