Chemistry:Titanium(IV) acetate
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3D model (JSmol)
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| Properties | |
| Ti(C2H3O2)4 | |
| Molar mass | 288.07 g/mol |
| Appearance | colorless |
| Melting point | 117 °C (243 °F; 390 K) |
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Other cations
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Zirconium(IV) acetate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Titanium(IV) acetate or titanium tetraacetate is a hypothetical coordination complex with the formula Ti(C2H3O2)4. It is discussed in archaic literature,[1] well before the advent of X-ray crystallography and an appreciation of the structural trends in metal carboxylate complexes.
Preparation
Titanium(IV) acetate can be prepared by reacting tetramethyltitanium with acetic acid.[2]
Related titanium acetates
Evidence for the composition much less the structure as a tetraacetate has not been presented.[3] Instead a variety of titanium oxo acetates have been prepared by reactions of titanium alkoxides and acetic acid.[4]
Uses
Species claimed to be titanium(IV) acetate have been used in the production of bismuth titanate ferroelectric thin films. Titanium(IV) acetate is used in the step of making the acetate-derived solutions. The acetate derived solutions were created by blending acetic acid and bismuth acetate together and adding titanium(IV) acetate.[5] "Titanium(IV) acetate" is a substitute for antimony potassium tartrate(emetic tartar) when making red and brown dyes.[6]
References
- ↑ Frederick Pearson Treadwell (1916) (in English). Qualitative analysis. J.Wiley & sons, Incorporated. pp. 538. https://books.google.com/books?id=svIZAAAAYAAJ. Retrieved 26 March 2021.
- ↑ K.-H. Thiele; M. Panse (1978). "Beiträge zur Chemie der Alkylverbindungen von Übergangsmetallen. XXVII. Darstellung von Titanacetaten aus Tetramethyl- und Tetrabenzyltitan". Z. anorg. allg. Chem. 441 (1): 23-28. doi:10.1002/zaac.19784410103.
- ↑ Pande, K. C.; Mehrotra, R. C. (1957). "Attempted Preparation of Titanium Tetra-Acetate". Journal für praktische Chemie 5 (1–2): 101–104. doi:10.1002/prac.19570050112.
- ↑ Gautier-Luneau, I.; Mosset, A.; Galy, J. (1987). "Structural Characterization of a Hexanuclear Titanium Acetate Complex, Ti6(μ3–O)2(μ2–O)2(μ2–OC2H5)2-μ-CH3COO)8(OC2H5)6, Built Up of Two Trinuclear, oxo-Centered, Units". Zeitschrift für Kristallographie 180 (1–4): 83–95. doi:10.1524/zkri.1987.180.1-4.83. Bibcode: 1987ZK....180...83G.
- ↑ (in English) Scientific and Technical Aerospace Reports. NASA, Office of Scientific and Technical Information. 1995. pp. 1198. https://books.google.com/books?id=62GCbS7Mu3kC. Retrieved 26 March 2021.
- ↑ The Year-book for Colorists and Dyers. the New York Public Library. 1905. pp. 413. https://books.google.com/books?id=VBFSAAAAYAAJ. Retrieved 26 March 2021.
Acetyl halides and salts of the acetate ion
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| AcOH | He | ||||||||||||||||||
| LiOAc | Be(OAc)2 BeAcOH |
B(OAc)3 | AcOAc ROAc |
NH4OAc | AcOOH | FAc | Ne | ||||||||||||
| NaOAc | Mg(OAc)2 | Al(OAc)3 ALSOL Al(OAc)2OH Al2SO4(OAc)4 |
Si | P | S | ClAc | Ar | ||||||||||||
| KOAc | Ca(OAc)2 | Sc(OAc)3 | Ti(OAc)4 | VO(OAc)3 | Cr(OAc)2 Cr(OAc)3 |
Mn(OAc)2 Mn(OAc)3 |
Fe(OAc)2 Fe(OAc)3 |
Co(OAc)2, Co(OAc)3 |
Ni(OAc)2 | Cu(OAc)2 | Zn(OAc)2 | Ga(OAc)3 | Ge | As(OAc)3 | Se | BrAc | Kr | ||
| RbOAc | Sr(OAc)2 | Y(OAc)3 | Zr(OAc)4 | Nb | Mo(OAc)2 | Tc | Ru(OAc)2 Ru(OAc)3 Ru(OAc)4 |
Rh2(OAc)4 | Pd(OAc)2 | AgOAc | Cd(OAc)2 | In | Sn(OAc)2 Sn(OAc)4 |
Sb(OAc)3 | Te | IAc | Xe | ||
| CsOAc | Ba(OAc)2 | Hf | Ta | W | Re | Os | Ir | Pt(OAc)2 | Au | Hg2(OAc)2, Hg(OAc)2 |
TlOAc Tl(OAc)3 |
Pb(OAc)2 Pb(OAc)4 |
Bi(OAc)3 | Po | At | Rn | |||
| Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
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| La(OAc)3 | Ce(OAc)x | Pr | Nd | Pm | Sm(OAc)3 | Eu(OAc)3 | Gd(OAc)3 | Tb | Dy(OAc)3 | Ho(OAc)3 | Er | Tm | Yb(OAc)3 | Lu(OAc)3 | |||||
| Ac | Th | Pa | UO2(OAc)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||
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