Chemistry:Semiheavy water

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Short description: Chemical compound
Semiheavy water
Spacefill model of water
Semiheavy water.svg
Names
IUPAC name
(O-2H1)Water
Other names
Deuterium hydrogen monoxide
Deuterium hydrogen oxide, Water-d1 , Water-d
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
115
Properties
H2HO (also HDO)
Molar mass 19.0214 g mol−1
Appearance Very pale blue, transparent liquid, very similar to regular water
Density 1.054 g cm−3
Melting point 3.81 °C (38.86 °F; 276.96 K)
Boiling point 101.42 °C (214.56 °F; 374.57 K)
miscible
log P −0.65
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Semiheavy water is the result of replacing one of the protium in light water with deuterium.[1] It exists whenever there is water with light hydrogen (protium, 1H) and deuterium (D or 2H) in the mix. This is because hydrogen atoms (hydrogen-1 and deuterium) are rapidly exchanged between water molecules. Water containing 50% H and 50% D in its hydrogen contains about 50% HDO and 25% each of H2O and D2O, in dynamic equilibrium.[2] In regular water, about 1 molecule in 3,200 is HDO (one hydrogen in 6,400 is D). By comparison, heavy water D2O[3] occurs at a proportion of about 1 molecule in 41 million (i.e., one in 6,4002). This makes semiheavy water far more common than "normal" heavy water.

The freezing point of semiheavy water is close to the freezing point of heavy water at 3.8°C compared to the 3.82°C of heavy water

References

  1. "Neutronic Investigation of Semi-Heavy Water Application in Hplwr New Flow Pattern" (in en). CNL Nuclear Review: 1–5. 2016-09-28. doi:10.12943/CNR.2016.00019. 
  2. "Revealing water's secrets: deuterium depleted water". Chemistry Central Journal 7 (1): 103. June 2013. doi:10.1186/1752-153X-7-103. PMID 23773696. 
  3. "Heavy water | chemical compound" (in en). https://www.britannica.com/science/heavy-water. 

Further reading

  • "Energy relaxation versus spectral diffusion of the OH-stretching vibration of HOD in liquid-to-supercritical deuterated water". The Journal of Chemical Physics 123 (16): 161105. October 2005. doi:10.1063/1.2110087. PMID 16268674.