Chemistry:Decene
Names | |
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Preferred IUPAC name
Dec-1-ene | |
Other names
Alpha Olefin C10; Decylene; α-Decene; 1-decene
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Identifiers | |
3D model (JSmol)
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ChEBI | |
ChEMBL | |
ChemSpider | |
EC Number |
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PubChem CID
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RTECS number |
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UNII | |
UN number | 3295, 1993 |
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Properties | |
C10H20 | |
Molar mass | 140.270 g·mol−1 |
Density | 0.74 g/cm3[1] |
Melting point | −66.3 °C (−87.3 °F; 206.8 K)[1] |
Boiling point | 172 °C (342 °F; 445 K)[1] |
Hazards | |
GHS pictograms | |
GHS Signal word | Danger |
H226, H304, H410 | |
P210, P233, P240, P241, P242, P243, P273, P280, P301+310, P303+361+353, P331, P370+378, P391, P403+235, P405, P501 | |
Related compounds | |
Related Alkenes
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Octene Nonene Undecene Dodecene |
Related compounds
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Decane Decanol |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
verify (what is ?) | |
Infobox references | |
Decene /dɛkiːn/ is an organic compound with the chemical formula C
10H
20. Decene contains a chain of ten carbon atoms with one double bond, making it an alkene. There are many isomers of decene depending on the position and geometry of the double bond. Dec-1-ene is the only isomer of industrial importance. As an alpha olefin, it is used as a comonomer in copolymers and is an intermediate in the production of epoxides, amines, oxo alcohols, synthetic lubricants, synthetic fatty acids and alkylated aromatics.[2]
The industrial processes used in the production of dec-1-ene are oligomerization of ethylene by the Ziegler process or by the cracking of petrochemical waxes.[3]
In ethenolysis, methyl oleate, the methyl ester of oleic acid, converts to 1-decene and methyl 9-decenoate:[4]
- [math]\displaystyle{ \overset{\text{methyl oleate}}{\ce{CH3(CH2)7CH=CH(CH2)7CO2Me}} + {\color{red}\ce{CH2=CH2}} \longrightarrow \overset{\text{1-decene}}{\ce{CH3(CH2)7CH=}{\color{red}\ce{CH2}}} + \overset{\text{9-decenoate}}{\ce{MeO2C(CH2)7CH=}{\color{red}\ce{CH2}}} }[/math]
Dec-1-ene has been isolated from the leaves and rhizome of the plant Farfugium japonicum and has been detected as the initial product in the microbial degradation of n-decane.
References
- ↑ 1.0 1.1 1.2 Record in the GESTIS Substance Database of the Institute for Occupational Safety and Health
- ↑ http://www.ineosoligomers.com/media/files/lao/LAO%20C10%20Data%20Sheet.pdf 1-Decene (Alpha Olefin C10)], ineosoligomers.com
- ↑ Alfa Olefins , SIDS Initial Assessment Report
- ↑ Marinescu, Smaranda C.; Schrock, Richard R.; Müller, Peter; Hoveyda, Amir H. (2009). "Ethenolysis Reactions Catalyzed by Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum". J. Am. Chem. Soc. 131 (31): 10840–10841. doi:10.1021/ja904786y. PMID 19618951.
External links
- Entry C872059 in Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD), http://webbook.nist.gov
Original source: https://en.wikipedia.org/wiki/Decene.
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