Chemistry:Polonium hexafluoride
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| Identifiers | |
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3D model (JSmol)
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| Properties | |
| PoF 6 | |
| Molar mass | 322.97 g/mol |
| Appearance | white solid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Polonium hexafluoride (PoF
6) is a possible chemical compound of polonium and fluorine and one of the seventeen known binary hexafluorides.[1]
Synthesis
The synthesis of PoF
6 via the reaction
- 210
Po + 3 F
2 → 210
PoF
6
was attempted in 1945, but the attempt was unsuccessful. The boiling point was predicted to be about −40 °C.[2]
208
PoF
6 was probably successfully synthesised via the same reaction in 1960 with the more stable isotope 208
Po,[1]:594 where a volatile polonium fluoride was produced,[3] but it was not fully characterized before it underwent radiolysis and decomposed to polonium tetrafluoride.[4][5]
References
- ↑ 1.0 1.1 Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils, ed., Inorganic Chemistry, San Diego/Berlin: Academic Press/De Gruyter, p. 594, ISBN 0-12-352651-5
- ↑ Summary of work to date on volatile neutron source, Monsanto Chemical Company, Unit 3 abstracts of progress reports, August 16–31, 1945; Abstract; PDF.
- ↑ Seppelt, Konrad (2015). "Molecular Hexafluorides". Chemical Reviews 115 (2): 1296–1306. doi:10.1021/cr5001783. PMID 25418862.
- ↑ Weinstock, B., Chernick, C.L.: The preparation of a volatile polonium fluoride. J. Am. Chem. Soc. 82, 4116–4117 (1960)
- ↑ Advances in Inorganic Chemistry and Radiochemistry. Academic Press. January 1962. ISBN 9780080578538. https://books.google.com/books?id=8qePsa3V8GQC&q=polonium+difluoride&pg=PA214.
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