Chemistry:Phosphite fluoride

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Phosphite fluorides are mixed anion compounds containing phosphite and fluoride anions. They are not to be confused with phosphate fluorides or phosphide fluorides which have different numbers of oxygen atoms joined to the phosphorus.

Structures

Phosphite ions have three oxygen atoms that can form complexes with metal ions. The hydrogen atom is covalently attached to the phosphorus atom and does not participate in hydrogen bonding. Compared the four bonds from phosphate, this results in lower dimensional structures, one or two dimensional rather than three-dimensional solid networks. The fluoride ion acts as a "mineralizer" stabilising different structures to the simple phosphite salt structures.[1]

List

name formula system space group unit cell volume density comment ref
ethylenediammonium (C2H10N2)[VIII(HPO3)F3] orthorhombic P212121 a = 12.809 b = 9.518 c = 6.440 Z=4 785.2 2.115 green [2]
ethylenediammonium (C2H10N2)[CrIII(HPO3)F3] orthorhombic P212121 a = 12.801, b = 9.337 c = 6.508 Z = 4, 777.9 2.144 green [3]
Mn2(HPO3)F2 orthorhombic Pnma a = 7.5607 b = 10.2342 c = 5.5156 Z = 4 [4]
H3.2Mn3.4[C6N2H11]2{Al12(HPO3)15.0(HPO4)3.0F12}·14H2O hexagonal P63/m a=13.2544 c=15.6722 Z=6 2384.41 1.864 colourless [5]
Fe2(HPO3)F2 orthorhombic Pnma a = 7.346 b = 10.038 c = 5.495 Z = 4 405.16 [6]
Ethylenediammonium (μ3-hydrogen phosphito)-trifluoro-iron(iii) (C2N2H10)[Fe(HPO3)F3] orthorhombic P212121 a=12.906 b=9.528 c=6.438 Z=4 [7][1]
piperazin-diium (C4N2H12)[FeIIFeIII(HPO3)2F3] monoclinic P21/n a = 12.935 b = 6.4476 c = 15.693 β = 105.630° Z = 4 1260.4 2.196 brown [1][8]
piperazin-diium (C4N2H12) [FeII0.86FeIII1.14 (HPO3)1.39 (HPO4)0.47 (PO4)0.14F3] orthorhombic P212121 a=12.790 b=6.440 c=15.167 Z=4 1249.3 2.25 brown [9]
DETA |C4N3H14|[Fe3(HPO3)4F2(H2O)2] monoclinic C2/c a=12.877 b=12.170 c=12.159 β=93.99 Z=4 1900.9 2.326 light pink; 3D framework with 6, 8 and 10-membered rings [10]
(C6N2H16)0.5[FeII(HPO3)F] monoclinic P21/c a=5.607 b=21.276 c=11.652 β=93.74° [1][11]
[C6N2H14]2[FeIII2F2(HPO3)2(C2O4)2 [1]
N,N′-bis(2-aminoethyl)-1,3-propanediamine (C7N4H20) (H4baepn)0.5[FeIII2.3FeII1.7(H2O)2(HPO3)3.57(HPO4)0.13(PO4)0.3F4] monoclinic P21/c a = 13.6808 b = 12.6340 c = 12.7830 β = 116.983° Z=4 [12]
ethylene diamine (C2N2H10)[Fe0.44V0.56(HPO3)F3] orthorhombic P212121 a = 12.8494 b = 9.5430 c = 6.4372 brown; 1-D double chains [13][14]
ethylene diamine (C2N2H10)[Fe0.72V0.28(HPO3)F3] orthorhombic P212121 a = 12.8578 b = 9.5342, c = 6.4370 brown; 1-D double chains [14][13]
1,4-Diazoniobicyclo(2.2.2)octane (μ3-phosphito)-fluoro-(oxalato-O,O')-iron(iii) monohydrate [C6N2H14]2[FeIII2F2(HPO3)2(C2O4)2]·2 H2O monoclinic P21/n a=12.511 b=6.3728 c=33.153 β=90.953° Z=4 2643.0 1.875 brown [15]
(C6N2H16)0.5[CoII(HPO3)F] monoclinic P21/c a=5.5822 b=21.325 c=11.4910 β=93.464° [1][11]
N,N′-bis(2-aminoethyl)-1,3-propanediamine (C7N4H20) (H4baepn)0.5[FeIII2.0FeII0.71CoII1.29(H2O)2(HPO3)3.63(HPO4)0.38F4] monoclinic P21/c a = 13.6823 b = 12.6063 c = 12.7535 β = 116.988° Z = 4. [12]
N,N′-bis(2-aminoethyl)-1,3-propanediamine (C7N4H20) (H4baepn)0.5[FeIII2.0FeII0.62CoII1.38(H2O)2(HPO3)3.62(HPO4)0.38F4] [12]
3-picoline Hpic·Ga2(HPO3)3F(H2O)·2H2O monoclinic P21/c a = 11.3213 b = 15.8208 c = 9.6156 β = 104.485° Z = 4 1667.53 2.177 proton conductor [16]
diethylenetriamine (H3DETA)Ga3(HPO3)4F4 monoclinic C2/c a=12.741 b=12.068 c=11.988 β=94.902o Z=4 1836.6 [17][1]
bis(piperazine-1,4-diium) tetrakis(μ3-phosphito)-bis(μ2-fluoro)-bis(μ2-hydrogen phosphito)-tetrafluoro-tetra-gallium (C4N2H12)[Ga2F3(HPO3)2(H2PO3)] triclinic P1 a=7.1072 b=9.4094 c=11.7847 α=71.602° β=78.165° γ=70.296° [1][18]
(ethan-1,2-diammonium) (μ3-hydrogen phosphito)-trifluorogallium(III) (C2H10N2)[GaF3(HPO3)] orthorhombic P212121 a = 6.358 b = 9.423 c = 12.968 Z = 4 777.0 [19]
ethylene diamine (C2N2H10)[Ga0.98Cr0.02(HPO3)F3] orthorhombic P212121 a=12.9417 b=9.4027 c=6.3502 Z=4. [1][20]
2,2′-bipyridine Ga3F2(2,2′-bipy)2(HPO3)2(H1.5PO3)2 monoclinic C2/c a=17.633 b=9.883 c=16.793 β=109.88° Z=4 2752.1 [21]
1,2-diaminocyclohexane (DACH) Ga(HPO3)F3·(trans-C6N2H16) monoclinic P21/c a = 11.2635 b = 9.8212 c = 10.1458 β = 102.981° Z = 4 [22]
2-methyl piperazine Ga(HPO3)F2·(H2C5N2H12)0.5 trigonal R3 a = 18.315 c = 13.136 Z = 9 3815.9 [23]
N,N′-dimethyl piperazine Ga(HPO3)F2·(H2C6N2H14)0.5 trigonal R3 a=17.8476 c = 13.5159 Z = 18 3728.5 [23]
hexakis(4-(dimethylamino)pyridinium) hexakis(μ-hydrogen phosphonato)-hexakis(μ-phosphonato)-hexakis(μ-fluoro)-hexa-gallium (C7H11N2)6(HPO3)6(H2PO3)6F6Ga6 triclinic P1 a 9.9573(7)Å b 10.8486(6)Å c 19.2188(11)Å, α 93.803(5)° β 96.919(5)° γ 109.024(6)° [24]
(μ-fluoro)-(μ-phosphonato)-(4-(dimethylamino)pyridine)-gallium (C7H11N2)(HPO3)FGa trigonal R3 a=13.5471 c=32.687 [24]
tris(4-(dimethylamino)pyridinium) oxonium tris(μ-hydroxo)-tetradecakis(μ-phosphonato)-hexa-aqua-nona-gallium (C7H11N2)3(HPO3)14(H3O)(OH)3Ga9(H2O)6 trigonal P31c a=13.282 c=22.59 [24]
Propane-1,2-diaminium (μ3-hydrogen phosphito)-(μ2-hydrogen phosphito)-fluoro-indium [C3H12N2][InF(HPO3)2] triclinic P1 a=5.412 b=10.234 c=10.511 α=113.234° β=95.522° γ=92.534° 1D chain [25]
SbHPO3F monoclinic P21/c a=4.5655 b=13.1125 c=6.7048 β=98.650° Z=4 396.82 3.695 [26]

References

  1. ↑ 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 Rojo, Teofilo; Mesa, Jose Luis; Lago, Jorge; Bazan, Begoña; Pizarro, Jose Luis; Arriortua, Maria Isabel (2009). "Organically templated open-framework phosphites" (in en). Journal of Materials Chemistry 19 (23): 3793. doi:10.1039/b808795b. ISSN 0959-9428. https://xlink.rsc.org/?DOI=b808795b. 
  2. ↑ Fernández, Sergio; Mesa, José L.; Pizarro, José L.; Lezama, Luis; Arriortua, María I.; Rojo, Teófilo (2003-03-01). "Hydrothermal Synthesis, Crystal Structures, Spectroscopic, and Magnetic Properties of Two New Organically Templated Monodimensional Phosphite Compounds: (C 2 H 10 N 2 )[M(HPO 3 )F 3 , M = V(III) and Cr(III)"] (in en). Chemistry of Materials 15 (5): 1204–1209. doi:10.1021/cm021361b. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm021361b. 
  3. ↑ Fernández, Sergio; Mesa, José L.; Pizarro, José L.; Lezama, Luis; Arriortua, María I.; Rojo, Teófilo (2002-10-04). "(C2H10N2)[Cr(HPO3)F3: The First Organically Templated Fluorochromium(III) Phosphite"]. Angewandte Chemie International Edition 41 (19): 3683–3685. doi:10.1002/1521-3773(20021004)41:19<3683::AID-ANIE3683>3.0.CO;2-J. PMID 12370930. https://onlinelibrary.wiley.com/doi/10.1002/1521-3773(20021004)41:193.0.CO;2-J. 
  4. ↑ Orive, Joseba; Mesa, José L.; Balda, Rolindes; Fernández, Joaquı́n; Rodrı́guez Fernández, Jesús; Rojo, Teófilo; Arriortua, Marı́a I. (2011-12-19). "Enhancement of the Luminescent Properties of a New Red-Emitting Phosphor, Mn 2 (HPO 3 )F 2 , by Zn Substitution" (in en). Inorganic Chemistry 50 (24): 12463–12476. doi:10.1021/ic201226t. ISSN 0020-1669. PMID 22085224. https://pubs.acs.org/doi/10.1021/ic201226t. 
  5. ↑ Liu, Hao; Tian, Zhi-Jian; Gies, Hermann; Wei, Ying; Marler, Bernd; Wang, Lei; Wang, Ya-Song; Li, Da-Wei (2014-07-04). "Mn 2+ cation-directed ionothermal synthesis of an open-framework fluorinated aluminium phosphite–phosphate" (in en). RSC Advances 4 (55): 29310. doi:10.1039/C4RA05350H. ISSN 2046-2069. Bibcode: 2014RSCAd...429310L. https://xlink.rsc.org/?DOI=C4RA05350H. 
  6. ↑ Liu, Li; Wang, Xiaofeng; Xu, Lin; Liu, Xizheng; Liu, Lizhen; Bi, Bo; Pang, Wenqin (August 2009). "Synthesis, characterization and magnetic properties of a novel fluorinated iron phosphite Fe2(HPO3)F2 with infinite –Fe–F–Fe–O–Fe– linkage and –Fe–F–Fe– layer" (in en). Inorganica Chimica Acta 362 (10): 3881–3884. doi:10.1016/j.ica.2009.04.048. https://linkinghub.elsevier.com/retrieve/pii/S0020169309002904. 
  7. ↑ Fernández-Armas, Sergio; Mesa, José L.; Pizarro, José L.; Clemente-Juan, Juan Modesto; Coronado, Eugenio; Arriortua, María I.; Rojo, Teófilo (2006-04-17). "Parametrization of the Magnetic Behavior of the Triangular Spin Ladder Chains Organically Templated: (C 2 N 2 H 10 )[M(HPO 3 )F 3 (M III = Fe, Cr, and V). Crystal Structure and Thermal and Spectroscopic Properties of the Iron(III) Phase"] (in en). Inorganic Chemistry 45 (8): 3240–3248. doi:10.1021/ic051804o. ISSN 0020-1669. PMID 16602780. https://pubs.acs.org/doi/10.1021/ic051804o. 
  8. ↑ Fernández-Armas, Sergio; Mesa, José L.; Pizarro, José L.; Arriortua, María I.; Rojo, Teófilo (March 2007). "A new organically templated monodimensional mixed valence (FeII/FeIII) phosphite: (C4H12N2)[FeIIFeIII(HPO3)2F3"] (in en). Materials Research Bulletin 42 (3): 544–552. doi:10.1016/j.materresbull.2006.06.020. https://linkinghub.elsevier.com/retrieve/pii/S002554080600256X. 
  9. ↑ Fernández-Armas, Sergio; Mesa, José L.; Pizarro, José L.; Garitaonandia, José S.; Arriortua, María I.; Rojo, Teófilo (2004-02-13). "(C 4 N 2 H 12 )[Fe II 0.86 Fe III 1.14 (HPO 3 ) 1.39 (HPO 4 ) 0.47 (PO 4 ) 0.14 F 3 : A Fluoro–Phosphite–Hydrogenphosphate–Phosphate Iron( II , III ) Mixed-Valence Organically Templated Compound"] (in en). Angewandte Chemie International Edition 43 (8): 977–980. doi:10.1002/anie.200352219. ISSN 1433-7851. PMID 14966884. Bibcode: 2004ACIE...43..977F. https://onlinelibrary.wiley.com/doi/10.1002/anie.200352219. 
  10. ↑ Qiao, Jian; Zhang, Lirong; Yu, Yang; Li, Guanghua; Jiang, Tianchan; Huo, Qisheng; Liu, Yunling (July 2009). "Synthesis, characterization and magnetic property of a new 3D iron phosphite: |C4N3H14|[Fe3(HPO3)4F2(H2O)2 with intersecting channels"] (in en). Journal of Solid State Chemistry 182 (7): 1929–1934. doi:10.1016/j.jssc.2009.05.008. https://linkinghub.elsevier.com/retrieve/pii/S002245960900200X. 
  11. ↑ 11.0 11.1 Fernández-Armas, Sergio; Mesa, José L.; Pizarro, José L.; Chung, U-Chan; Arriortua, María I.; Rojo, Teófilo (November 2005). "Two new two-dimensional organically templated phosphite compounds: (C6H16N2)0.5[M(HPO3)F, M=Fe(II) and Co(II): Solvothermal synthesis, crystal structures, thermal, spectroscopic, and magnetic properties"] (in en). Journal of Solid State Chemistry 178 (11): 3554–3562. doi:10.1016/j.jssc.2005.09.032. https://linkinghub.elsevier.com/retrieve/pii/S0022459605004135. 
  12. ↑ 12.0 12.1 12.2 Orive, Joseba; Fernández de Luis, Roberto; Rodríguez Fernández, Jesús; Legarra, Estibaliz; Plazaola, Fernando; Arriortua, María I. (2014). "Fluorinated mixed valence Fe( ii )–Fe( iii ) phosphites with channels templated by linear tetramine chains. Structural and magnetic implications of partial replacement of Fe( ii ) by Co( ii )" (in en). CrystEngComm 16 (27): 6066–6079. doi:10.1039/C4CE00264D. ISSN 1466-8033. Bibcode: 2014CEG....16.6066O. https://xlink.rsc.org/?DOI=C4CE00264D. 
  13. ↑ 13.0 13.1 Cisneros, Jose L.; Fernández-Armas, Sergio; Mesa, José L.; Pizarro, José L.; Arriortúa, María I.; Rojo, Teófilo (October 2006). "(C2N2H10)[FexV1−x(HPO3)F3 (x=0.44, 0.72): Two new organically templated phosphites"] (in en). Materials Research Bulletin 41 (10): 1835–1844. doi:10.1016/j.materresbull.2006.03.014. https://linkinghub.elsevier.com/retrieve/pii/S0025540806001085. 
  14. ↑ 14.0 14.1 Cisneros, José L.; Fernández-Armas, Sergio; Mesa, José L.; Pizarro, José L.; Arriortúa, María I.; Rojo, Teófilo (November 2006). "Structural, thermal, spectroscopic and magnetic studies of the (C2N2H10)0.5[FexV1−x(HPO3)2 (x=0.26, 0.52, 0.74) solid solution"] (in en). Materials Research Bulletin 41 (11): 2168–2180. doi:10.1016/j.materresbull.2006.03.035. https://linkinghub.elsevier.com/retrieve/pii/S0025540806001243. 
  15. ↑ Mandal, Sukhendu; Natarajan, Srinivasan (2007-01-12). "Inorganic–Organic Hybrid Structures: Open-Framework Iron Phosphite–Oxalates of Varying Dimensionality" (in en). Chemistry – A European Journal 13 (3): 968–977. doi:10.1002/chem.200601026. ISSN 0947-6539. PMID 17066396. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.200601026. 
  16. ↑ Zhang, Yan; Ju, Jia; Li, Ting; Zhang, Ying; Lin, Zhien; Cai, Huaqiang (September 2019). "Organically templated metal phosphites: Ionothermal synthesis, crystal structure, and proton conduction" (in en). Inorganic Chemistry Communications 107. doi:10.1016/j.inoche.2019.107476. https://linkinghub.elsevier.com/retrieve/pii/S1387700319305325. 
  17. ↑ Wang, Li; Song, Tianyou; Fan, Yong; Wang, Ying; Xu, Jianing; Shi, Suhua; Zhu, Tao (March 2006). "Ga3(HPO3)4F4(H3DETA) (DETA=diethylenetriamine): A new open-framework fluorinated gallium phosphite with pentameric building unit" (in en). Journal of Solid State Chemistry 179 (3): 824–829. doi:10.1016/j.jssc.2005.12.005. https://linkinghub.elsevier.com/retrieve/pii/S0022459605005840. 
  18. ↑ Wang, Li; Song, Tianyou; Fan, Yong; Tian, Zhenfen; Wang, Ying; Shi, Suhua; Xu, Jianing (November 2006). "Synthesis and characterization of a new open-framework fluorinated gallium phosphite with three-dimensional intersecting channels" (in en). Journal of Solid State Chemistry 179 (11): 3400–3405. doi:10.1016/j.jssc.2006.07.028. Bibcode: 2006JSSCh.179.3400W. https://linkinghub.elsevier.com/retrieve/pii/S0022459606004166. 
  19. ↑ Duan, Xing-Chao (December 2010). "Crystal structure of (ethan-1,2-diammonium) (μ3-hydrogen phosphito)-trifluorogallium(III),(C2H10N2)[GaF3(HPO3)"]. Zeitschrift für Kristallographie - New Crystal Structures 225 (4): 787–788. doi:10.1524/ncrs.2010.0346. ISSN 2197-4578. https://www.degruyter.com/document/doi/10.1524/ncrs.2010.0346/html. 
  20. ↑ Fernández-Armas, Sergio; Mesa, José L; Pizarro, José L; Lezama, Luis; Arriortua, Marı́a I; Rojo, Teófilo (March 2004). "A new organically templated gallium(III)-doped chromium(III) fluorophosphite, (C2H10N2)[Ga0.98Cr0.02(HPO3)F3 hydrothermal synthesis, crystal structure and spectroscopic properties"] (in en). Journal of Solid State Chemistry 177 (3): 765–771. doi:10.1016/j.jssc.2003.09.008. https://linkinghub.elsevier.com/retrieve/pii/S002245960300519X. 
  21. ↑ Huang, Liangliang; Song, Tianyou; Shi, Suhua; Tian, Zhenfen; Wang, Li; Zhang, Lirong (June 2008). "Hydrothermal synthesis, characterization and fluorescence property of a novel layered fluorinated gallium phosphite with heptameric building unit" (in en). Journal of Solid State Chemistry 181 (6): 1279–1284. doi:10.1016/j.jssc.2008.01.040. Bibcode: 2008JSSCh.181.1279H. https://linkinghub.elsevier.com/retrieve/pii/S0022459608000728. 
  22. ↑ Huang, Liangliang; Song, Tianyou; Zhang, Lirong; Chen, Yanli; Jiang, Jinhua; Xu, Jianing; Wang, Li (2010). "Synthesis, crystal structure and characterization of a new layered gallium phosphite Ga(HPO3)F3·(trans-C6N2H16) with left- and right-handed helical chains" (in en). CrystEngComm 12 (7): 2198. doi:10.1039/b926096j. ISSN 1466-8033. Bibcode: 2010CEG....12.2198H. https://xlink.rsc.org/?DOI=b926096j. 
  23. ↑ 23.0 23.1 Huang, Liangliang; Fan, Yong; Ma, Hongwei; Li, Caixia; Wang, Li (September 2014). "Synthesis and characterizations of two NbO topological gallium phosphites with low framework density" (in en). Microporous and Mesoporous Materials 196: 321–326. doi:10.1016/j.micromeso.2014.05.040. Bibcode: 2014MicMM.196..321H. https://linkinghub.elsevier.com/retrieve/pii/S1387181114003126. 
  24. ↑ 24.0 24.1 24.2 Lin, Cong; Li, Jian; Wang, Yan; Xu, Diming; Liao, Fuhui; Lin, Jianhua; Pan, Feng; Sun, Junliang (2019-11-06). "DMAP-Induced Gallium Phosphites with Different Dimensionality" (in en). Crystal Growth & Design 19 (11): 6011–6016. doi:10.1021/acs.cgd.9b00725. ISSN 1528-7483. Bibcode: 2019CrGrD..19.6011L. https://pubs.acs.org/doi/10.1021/acs.cgd.9b00725. 
  25. ↑ Wang, Xuelei; Yan, Yan; Wu, Junbiao; Zhang, Chuanqi; Li, Jiyang (2014). "Solvothermal syntheses and structures of four indium–phosphite coordination polymers" (in en). CrystEngComm 16 (11): 2266. doi:10.1039/c3ce42059k. ISSN 1466-8033. Bibcode: 2014CEG....16.2266W. https://xlink.rsc.org/?DOI=c3ce42059k. 
  26. ↑ Long, Ying; Dong, Xuehua; Huang, Ling; Zeng, Hongmei; Lin, Zhien; Zou, Guohong (31 October 2022). "SbHPO 3 F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence". Inorganic Chemistry 61 (43): 16997–17001. doi:10.1021/acs.inorgchem.2c03266. PMID 36264600. 
Salts and covalent derivatives of the fluoride ion
HF He
LiF BeF2 BF
BF3
B2F4 		CF4
other compounds 		NF3
FN3
N2F2
N2F4
NF5§ 		F2O
F2O2
other compounds 		F2 Ne
NaF MgF2 AlF
AlF3 		SiF4 P2F4
PF3
PF5 		S2F2
SF2
SF4
SF6 		ClF
ClF3
ClF5 		Ar
KF CaF
CaF2 		ScF3 TiF2
TiF3
TiF4 		VF2
VF3
VF4
VF5 		CrF2
CrF3
CrF4
CrF5
CrF6§ 		MnF2 FeF2
FeF3 		CoF2
CoF3 		NiF2 CuF
CuF2 		ZnF2 GaF2
GaF3 		GeF2
GeF4 		AsF3
AsF5 		Se2F2
SeF4
SeF6 		BrF
BrF3
BrF5 		KrF2
RbF SrF
SrF2 		YF3 ZrF3
ZrF4 		NbF4
NbF5 		MoF2
MoF3
MoF4
MoF5
MoF6 		TcF4
TcF6 		RuF3
RuF5
RuF6 		RhF3
RhF5
RhF6 		PdF2 AgF CdF2 InF
InF2
InF3 		SnF2
SnF4 		SbF3
SbF5 		Te3F2
TeF4
TeF6 		IF
IF3</br>IF5</br>IF7 		XeF2
XeF4
XeF6
CsF BaF2   HfF4 TaF5 WF2
WF3
WF4
WF5
WF6 		Re3F9
ReF4
ReF5
ReF6
ReF7 		OsF4
OsF5
OsF6 		IrF2
IrF3
IrF4
IrF5
IrF6 		PtF2
PtF4
PtF5
PtF6 		AuF
AuF3
Au2F10
AuF5•F2 		Hg2F2
HgF2
HgF4 		TlF PbF2
PbF4 		BiF3
BiF5 		PoF2
PoF4
PoF6 		AtF RnF2
FrF RaF2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
LaF3 CeF3
CeF4 		PrF3 NdF2,
NdF3 		PmF3 SmF2,
SmF3 		EuF2,
EuF3 		GdF3 TbF3 DyF2,
DyF3 		HoF3 ErF3 TmF2
TmF3 		YbF2
YbF3 		LuF3
AcF3 ThF4 PaF5 UF3
UF4
UF5
UF6 		NpF4
NpF6 		PuF3
PuF6 		AmF2
AmF3 		CmF3 BkF3 CfF3 EsF3 Fm Md No LrF3

§ means the substance has not been made.



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