Chemistry:Selenite fluoride

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Short description: Class of chemical compounds

A selenite fluoride is a chemical compound or salt that contains fluoride and selenite anions (F− and SeO2−3). These are mixed anion compounds. Some have third anions, including nitrate (NO−3), molybdate (MoO2−4), oxalate (C2O2−4), selenate (SeO2−4), silicate (SiO2−4) and tellurate (TeO2−4).

Naming

A selenite fluoride compound may also be called a fluoride oxoselenate(IV) using IUPAC naming for inorganic compounds.

Production

Rare earth selenite fluorides can be produced by dissolving the rare earth selenate into molten lithium fluoride at over 800°C, whereupon the selenate loses oxygen to become selenite, and crystals of the selenite fluoride can form.[1] Another similar method involves heating the rare earth oxide, with a rare earth fluoride and selenium dioxide with a caesium bromide flux. If glass or silica containers are used, they are eaten away by the molten flux and silicates are formed some of which may be fluoride selenite silicate compounds.[2]

Related

Related to these are the selenite chlorides and selenite bromides by varying the halogenide. Similar compounds by varying the chalcogen also include the sulfite fluorides and tellurite fluorides.

List

name formula ratio

SeO3:F

mw system space group unit cell Å volume density optical references
scandium selenite fluoride ScSeO3F 1:1 triclinic P1 <13 −173°C a=6.2769 b=6.5578 c=4.0627 α=95.478 β=95.332 γ=92.363 Z=2 3.830 [3]
monoclinic P21/m >13 a=4.0643 b =6.6109 c=6.32.35 β=93.298° Z=2 [2]
Na3Ti3O3(SeO3)4F 4:1 hexagonal P63 a =12.8439 c =5.2339 SHG 6 × KDP [4]
dimanganese difluoride selenite Mn2SeO3F2 1:2 274.83 orthorhombic Pnma a = 7.50848 b = 10.350 and c = 5.47697 Z=4 pink [5]
ferric difluoride selenite FeSeO3F 1:1 201.81 monoclinic P21/n a=4.9559 b=5.2023 c=12.040 β=97.87 Z=4 307.50 4.359 yellow [6]
ammonium diferric trifluoride diselenite NH4Fe2F3(SeO3)2 2:3 [7]
piperizinium [C4N2H12]Fe4F6(SeO3)4 2:3 933.40 monoclinic C2/c a=15.168 b=7.3973 c=16.127 β=90.044 Z=5 1928.9 3.14 brown [7]
diethylenetriamine [C4N3H14]Fe4F6(SeO3)4 2:3 [7]
dicobalt difluoride selenite Co2SeO3F2 1:2 282.82 orthorhombic Pnma a = 7.2655 b = 10.001 c = 5.3564 Z=4 389.22 4.826 pink [8]
Ni2(SeO3)F2 1:2 282.3 orthorhombic Pnma a=7.1727 b=9.9377 c=5.2364 373.25 yellow [9]
dicopper difluoride selenite Cu2(SeO3)F2 1:2 292.05 orthorhombic Pnma a = 7.066 b = 9.590 c = 5.563 Z=4 377.0 5.146 light green [10]
dizinc difluoride selenite Zn2(SeO3)F2 1:2 295.70 orthorhombic Pnma a=7.276 b=10.042 c=5.256 Z=4 384.0 5.114 colourless [11]
triethylenediamin-di-ium digallium hexafluoride selenite C6H14N2Ga2F6SeO3 1:6 494.59 Monoclinic P21/c a=12.616 b=7.2700 c=13.605 β=104.746 Z=4 1206.8 2.722 colourless [12]
ethelenediamin-di-ium gallium trifluoride selenite C2H10N2GaF3SeO3 1:3 315.80 monoclinic P21/c a=9.1107 b=8.0382 c=10.8302 β=90.045 Z=4 793.1 2.2355 colourless [12]
piperizin-di-ium gallium fluoride oxalate selenite hydrate H2pipGaFSeO3[C2O4]H2O 1:1 409.87 triclinic P1 a=6.377 b=9.2820 c=11.4112 α=66.53 β=77.44 γ=71.89 585.47 2.325 colourless [12]
(C4H15N3)2Ga4F2(SeO3)6(C2O4).4H2O 6:2 1467.11 triclinic P1 a=8.9941 b=9.4963 c=11.2959 α=77.13 β=68.073 γ=83.776 Z=1 872.17 2.793 colourless [12]
Sr(VO2F)(SeO3) 316.52 orthorhombic Pbca a=9.7816 b=8.0278 c=12.927 Z=8 1015.07 4.142 yellow [13]
yttrium selenite fluoride YSeO3F 1:1 monoclinic P21/c <319 a=6.5765 b=6.8971 c=7.1728 β=99.036 Z=4 [14][3][15]
monoclinc P 21/m >319 600° a=6.5840 b=6.9809 c=4.3434 β =95.032 Z=2 3.922 [3]
Ag3Ti3O3(SeO3)4F 1042.15 hexagonal P63 a=12.8975 c=5.2180 Z=2 751.70 4.604 colourless SHG 2×KDP [16]
Ag2ZrF2(SeO3)2 598.88 orthorhombic Cmca a=7.3640 b=31.451 c=6.2719 1452.6 5.477 colopurless [16]
dicadmium difluoride selenite Cd2(SeO3)F2 1:2 389.76 orthorhombic Pnma a=7.803 b=10.566 c=5.729 Z=4 472.4 5.480 colourless [11]
ethelenediamin-di-ium indium trifluoride selenite C2H10N2InF3SeO3 360.90 monoclinic P21/c a=9.3066 b=8.3012 c=11.2923 Z=4 871.68 2.750 colourless [12]
caesium triscandium hexafluoride diselenite CsSc3F6[SeO3]2 2:6 trigonal P3m1 a = 5.6534 c = 10.6987 Z = 1 [17]
Cs(TiOF)3(SeO3)2 2:3 635.53 hexagonal P63mc a=7.2420 c=11.8152 Z=2 536.65 3.933 Colourless SHG 5xKDP [18]
caesium triiron hexafluoride diselenite CsFe3(SeO3)2F6 2:6 trigonal P3m1 a=5.459 c=10.537 Z=1 271.9 cyan [19]
Ba(VO2F)(SeO3) 366.24 orthorhombic Pbca a=10.0539 b=8.3967 c=13.174 1112.18 4.375 yellow [13]
lanthanum selenite fluoride LaSeO3F 1:1 monoclinic P21/c a = 18.198 b = 7.1575 c = 8.464 β = 96.89 Z = 12 [1][20]
cerium selenite fluoride CeSeO3F 1:1 [14]
tetrapraseodymium selenate diselenite hexafluoride Pr4(SeO3)2(SeO4)F6 2:6 monoclinic C2/c a = 22.305 b = 7.1054 c = 8.356 β = 98.05° Z = 4 [21]
tripraseodymium fluoride tetraselenite Pr3F[SeO3]4 pale green [22]
Pr5F[SiO4]2[SeO3]3 3:1 triclinic P1 a = 7.0114 b = 9.8268 c = 12.8679 α = 70.552 β = 76.904 γ = 69.417° Z = 2 5.511 pale green [22]
trineodymium fluoride tetraselenite Nd3(SeO3)4F hexagonal P63mc a=10.515 c=7.1211 [23]
trisamarium fluoride tetraselenite Sm3(SeO3)4F hexagonal P63mc a=10.474 c=7.0224 [23]
trigadolinium tetraselenite fluoride Gd3(SeO3)4F 4:1 hexagonal P63mc a = 10.443 b = 6.9432 Z=2 [24][1]
tridysprosium tetraselenite fluoride Dy3(SeO3)4F 4:1 1014.34 hexagonal P63mc a=10.360 c=6.8647 Z=2 [1]
holmium selenite fluoride HoSeO3F 1:1 monoclinic P21/c a=6.5784 b=6.8873 c=7.1825 β =99.213 Z=4 6.43 [15]
Ho3F[SeO3]4 4:1 hexagonal P63mc a = 10.3024 c = 6.8037 Z = 2 [25]
erbium selenite fluoride ErSeO3F 1:1 monoclinic P21/c a=6.5553 b=6.8741 c=7.1516 β =99.020 Z=4 6.54 [15]
Er3F[SiO4][SeO3]2 2:1 orthorhombic Pnna a = 5.8692 b = 15.2931 c = 10.2967 Z = 4 pink [22][26]
thulium selenite fluoride TmSeO3F 1:1 monoclinic P21/c a=6.5342 b=68607 c=7.1213 β =98,828 Z=4 6.63 [15]
ytterbium selenite fluoride YbSeO3F 1:1 monoclinic P21/c a=6.5146 b=6.8475 c=7.0924 β =98.637 Z=4 6.77 [15]
Lutetium selenite fluoride LuF[SeO3] 1:1 monoclinic P21/c −173°C: a=6.4839 b=6.8128 c=7.0581 β=98.657 Z=4 308.23 6.916 [14]
triclinic P1 a=6.4486 b=6.8441 c=4.2798 α=94.063 β=98.657 γ=91.895 Z=2 187.04 5.698 [14]
monoclinic P21/m 173°C: a=6.4734 b=6.8702 c=4.2843 β=95.602 Z=2 189.63 5.621 [14]
trilutetium fluoride tetraselenite Lu3F(SeO3)4 4:1 1051.75 trigonal P63 a=9.883 c=7.066 Z=2 597.7 5.844 colourless SHG 2.5×KDP [27]
PbVO2(SeO3)F 1:1 436.09 orthorhombic Pbca a=9.812 b=8.147 c=13.026 Z=8 1041.3 5.563 yellow [28]
cadmium lead fluoride nitrate selenite PbCdF(SeO3)(NO3) 1:1 orthorhombic Pca21 a=11.121 b=10.366 c=5.3950 Z=4 621.9 5.634 SHG 2.6×KDP band gap 4.42 eV [29]
bismuth selenite fluoride BiFSeO3 1:1 354.94 orthorhombic Pca21 a=6.6774 b=6.8872 c=7.4702 Z=4 343.54 6.862 colourless SHG 13.5×KDP [30]
tribismuth triselenite pyroselenite fluoride Bi3(SeO3)3(Se2O5)F 3:1 monoclinic F21 SHG 3×KDP [31]
dibismuth potassium pentafluoride selenite KBi2SeO3F5 1:5 679.02 orthorhombic Pbcm a=4.553 b=17.80 c=8.80 Z=4 712.9 6.326 white band gap 4.08 eV [32]
dibismuth rubidium pentafluoride selenite RbBi2SeO3F5 1:5 725.39 Triclinic P1 a=8.842 b=8.917 c=9.63 α=88.28 β=89.82 γ=89.76 Z=4 758.9 6.349 white band gap 4.18 eV [32]
RbBi(SeO3)F2 1:2 459.41 orthorhombic Pnma a=13.251 b=6.073 c=6.780 Z=4 545.6 [33]
Bi4TiO2F4(SeO3)4 4:4 1499.66 monoclinic P21/c a=7.0237 b=6.6824 c=17.3240 β=106.637 Z=2 779.07 6.393 colourless [34]
Bi4NbO3F3(SeO3)4 4:3 1541.67 monoclinic P21/c a=7.0448 b=6.6814 c=17.4051 β=106.931 Z=2 783.73 6.533 colourless [34]
Bi4TeO4F2(TeO3)2(SeO3)2 2:2 1670.64 monoclinic P21/c a=7.0304 b=6.6782 c=17.355 β=106.155 Z=2 782.66 7.089 colourless [34]
Bi2F2(MoO4)(SeO3) 1:2 742.86 monoclinic P21/c a=7.1005 b=9.660 c=12.972 β=12.091 Z=4 753.82 6.546 colourless [34]
Bi2ZrO2F2(SeO3)2 2:2 833.10 triclinic P1 a=5.8047 b=6.3469 c=6.7419 α=77.665 β=71.365 γ=72.795 Z=1 222.87 6.207 colourless [34]
PbBi(SeO3)2F 2:1 orthorhombic Pca21 a=12.9672 b=4.5022 c=11.8221 SHG 10.5×KDP; band gap 3.75 eV [35]

SHG=second harmonic generator

References

  1. ↑ 1.0 1.1 1.2 1.3 Krügermann, Ina; Wickleder, Mathias S. (August 2002). "Syntheses and Crystal Structures of Er2(SeO3)3 and Dy3(SeO3)4F" (in en). Journal of Solid State Chemistry 167 (1): 113–118. doi:10.1006/jssc.2002.9629. Bibcode: 2002JSSCh.167..113K. 
  2. ↑ 2.0 2.1 Greiner, Stefan; Chou, Sheng-Chun; Schleid, Thomas (February 2017). "Two anionically derivatized scandium oxoselenates(IV): ScF[SeO3] and Sc2O2[SeO3]" (in en). Journal of Solid State Chemistry 246: 160–166. doi:10.1016/j.jssc.2016.11.011. Bibcode: 2017JSSCh.246..160G. 
  3. ↑ 3.0 3.1 3.2 Chou, Sheng-Chun; Greiner, Stefan; Magdysyuk, Oxana V.; Dinnebier, Robert E.; Schleid, Thomas (December 2014). "Theoretical and Experimental Analysis of Structural Phase Transitions for ScF[SeO 3 ] and YF[SeO 3 ]: Structural Phase Transitions for ScF[SeO 3 ] and YF[SeO 3 ]" (in en). Zeitschrift für anorganische und allgemeine Chemie 640 (15): 3203–3211. doi:10.1002/zaac.201400287. 
  4. ↑ Yan, Sheng-Nan; Wang, Xiao-Xue; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2022-01-24). "Na 3 Ti 3 O 3 (SeO 3 ) 4 F: A Phase-Matchable Nonlinear-Optical Crystal with Enlarged Second-Harmonic-Generation Intensity and Band Gap" (in en). Inorganic Chemistry 61 (5): 2686–2694. doi:10.1021/acs.inorgchem.1c03738. ISSN 0020-1669. PMID 35068146. https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c03738. 
  5. ↑ Orive, Joseba; Balda, Rolindes; Fernández, Joaquín; Lezama, Luis; Arriortua, María I. (2013). "Low temperature red luminescence of a fluorinated Mn-doped zinc selenite" (in en). Dalton Transactions 42 (34): 12481–94. doi:10.1039/c3dt51224j. ISSN 1477-9226. PMID 23863913. http://xlink.rsc.org/?DOI=c3dt51224j. 
  6. ↑ Hu, Shichao; Johnsson, Mats; Law, Joseph M.; Bettis, Jerry L.; Whangbo, Myung-Hwan; Kremer, Reinhard K. (2014-04-21). "Crystal Structure and Magnetic Properties of FeSeO 3 F—Alternating Antiferromagnetic S = 5/2 chains" (in en). Inorganic Chemistry 53 (8): 4250–4256. doi:10.1021/ic5003995. ISSN 0020-1669. PMID 24684563. 
  7. ↑ 7.0 7.1 7.2 Choudhury, Amitava; Udaya Kumar; D C. N. R. Rao (2 January 2002). "Three-Dimensional Organically Templated Open-Framework Transition Metal Selenites". Angewandte Chemie International Edition 41 (1): 158–161. doi:10.1002/1521-3773(20020104)41:1<158::AID-ANIE158>3.0.CO;2-#. PMID 12491471. 
  8. ↑ Lipp, Christian; Schleid, Thomas (June 2008). "Er3F[SiO4][SeO3]2: An ErF3-Derivative with Two Different Kinds of Complex Oxoanions" (in de). Zeitschrift für anorganische und allgemeine Chemie 634 (6–7): 1025–1029. doi:10.1002/zaac.200700583. 
  9. ↑ Zhu, Tianyu; Mentré, Olivier; Yang, Haoming; Jin, Yong; Zhang, Xinan; Arévalo-López, Ángel; Ritter, Clemens; Choi, Kwang-Yong et al. (2021). "Cycloidal Magnetic Order Promoted by Labile Mixed Anionic Paths in M 2 (SeO 3 )F 2 (M = Mn 2+ , Ni 2+ )". Inorganic Chemistry 60 (16): 12001–12008. doi:10.1021/acs.inorgchem.1c01074. PMID 34309359. https://hal.archives-ouvertes.fr/hal-03300303. 
  10. ↑ Mitoudi-Vagourdi, Eleni; Papawassiliou, Wassilios; Müllner, Silvia; Jaworski, Aleksander; Pell, Andrew J.; Lemmens, Peter; Kremer, Reinhard K.; Johnsson, Mats (2018-04-16). "Synthesis and Physical Properties of the Oxofluoride Cu 2 (SeO 3 )F 2" (in en). Inorganic Chemistry 57 (8): 4640–4648. doi:10.1021/acs.inorgchem.8b00372. ISSN 0020-1669. PMID 29613786. 
  11. ↑ 11.0 11.1 You, Fengguang; Gong, Pifu; Liang, Fei; Jiang, Xingxing; Tu, Heng; Zhao, Ying; Hu, Zhanggui; Lin, Zheshuai (2019). "M 2 (SeO 3 )F 2 (M = Zn, Cd): understanding the structure directing effect of [SeO 3 2− groups on constructing ordered oxyfluorides"] (in en). CrystEngComm 21 (15): 2485–2489. doi:10.1039/C9CE00279K. ISSN 1466-8033. http://xlink.rsc.org/?DOI=C9CE00279K. 
  12. ↑ 12.0 12.1 12.2 12.3 12.4 Feng, Mei-Ling; Li, Xiu-Ling; Mao, Jiang-Gao (April 2007). "New Organically Templated Gallium and Indium Selenites or Selenates with One-, Two-, and Three-Dimensional Structures" (in en). Crystal Growth & Design 7 (4): 770–777. doi:10.1021/cg060824d. ISSN 1528-7483. 
  13. ↑ 13.0 13.1 Liang, Ming-Li; Ma, Yun-Xiang; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2018). "A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron" (in en). Dalton Transactions 47 (5): 1513–1519. doi:10.1039/C7DT04442A. ISSN 1477-9226. PMID 29313546. http://xlink.rsc.org/?DOI=C7DT04442A. 
  14. ↑ 14.0 14.1 14.2 14.3 14.4 Lipp, Christian; Dinnebier, Robert E.; Schleid, Thomas (2013-10-07). "LuF[SeO 3 ]: The Structural Chameleon of Lanthanoid Fluoride Oxoselenates(IV)" (in en). Inorganic Chemistry 52 (19): 10788–10794. doi:10.1021/ic4006289. ISSN 0020-1669. PMID 24024560. 
  15. ↑ 15.0 15.1 15.2 15.3 15.4 Lipp, Christian; Schleid, Thomas (2009-04-01). "Die Selten-Erd-Metall(III)-Fluorid-Oxoselenate(IV) MF[SeO3] (M = Y, Ho–Lu) imYF[SeO3]-Typ/ The Rare-Earth Metal(III) Fluoride Oxoselenates(IV) MF[SeO3] (M = Y, Ho–Lu) with YF[SeO3]-type Structure". Zeitschrift für Naturforschung B 64 (4): 375–382. doi:10.1515/znb-2009-0403. ISSN 1865-7117. 
  16. ↑ 16.0 16.1 Qian, Qian; Kong, Fang; Mao, Jiang-Gao (2016). "A series of new silver selenites with d 0 -TM cations" (in en). RSC Advances 6 (83): 79681–79687. doi:10.1039/C6RA17867G. ISSN 2046-2069. Bibcode: 2016RSCAd...679681Q. http://xlink.rsc.org/?DOI=C6RA17867G. 
  17. ↑ Greiner, Stefan; Schleid, Thomas (2017-09-04). "CsSc 3 F 6 [SeO 3 ] 2 : A New Rare-Earth Metal(III) Fluoride Oxoselenate(IV) With Sections Of The ReO 3 -Type Structure: CsSc 3 F 6 [SeO 3 ] 2 : A New Rare-Earth Metal(III) Fluoride Oxoselenate(IV) With Sections Of The ReO 3 -Type Structure" (in en). Zeitschrift für anorganische und allgemeine Chemie 643 (16): 1057–1062. doi:10.1002/zaac.201700158. 
  18. ↑ Cao, Xue-Li; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2015-04-20). "Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra" (in en). Inorganic Chemistry 54 (8): 3875–3882. doi:10.1021/acs.inorgchem.5b00052. ISSN 0020-1669. PMID 25835387. 
  19. ↑ Lu, Hongcheng; Kageyama, Hiroshi (2018-05-21). "CsFe 3 (SeO 3 ) 2 F 6 with S = 5/2 Cube Tile Lattice" (in en). Inorganic Chemistry 57 (10): 6186–6190. doi:10.1021/acs.inorgchem.8b00859. ISSN 0020-1669. PMID 29741890. 
  20. ↑ Wickleder, Mathias S. (2000). "Wasserfreie Selenite des Lanthans: Synthese und Kristallstruktur von La2(SeO3)3 und LaFSeO3" (in de). Zeitschrift für anorganische und allgemeine Chemie 626 (2): 547–551. doi:10.1002/(SICI)1521-3749(200002)626:2<547::AID-ZAAC547>3.0.CO;2-V. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3749%28200002%29626%3A2%3C547%3A%3AAID-ZAAC547%3E3.0.CO%3B2-V. 
  21. ↑ Krügermann, Ina; Wickleder, Mathias S. (2002). "Pr4(SeO3)2(SeO4)F6 und NaSm(SeO3)(SeO4): Selenit-Selenate der Selten-Erd-Elemente" (in de). Zeitschrift für anorganische und allgemeine Chemie 628 (1): 147–151. doi:10.1002/1521-3749(200201)628:1<147::AID-ZAAC147>3.0.CO;2-8. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/1521-3749%28200201%29628%3A1%3C147%3A%3AAID-ZAAC147%3E3.0.CO%3B2-8. 
  22. ↑ 22.0 22.1 22.2 Lipp, Christian; Burns, Peter C.; Schleid, Thomas (April 2012). "Pr5F[SiO4]2[SeO3]3: Another Complex Fluoride Oxosilicate Oxoselenate(IV)" (in en). Zeitschrift für anorganische und allgemeine Chemie 638 (5): 779–784. doi:10.1002/zaac.201100493. 
  23. ↑ 23.0 23.1 Wickleder, M. S. (2005-08-02) (in en). Handbook on the Physics and Chemistry of Rare Earths. Elsevier. pp. 83. ISBN 978-0-08-046102-1. https://books.google.com/books?id=Q8oPxFJlfp0C&pg=PA83. 
  24. ↑ Wickleder, Mathias S.; Göhausen, Ina (2000). "Gd3(SeO3)4F: Ein Fluoridselenit mit μ3-SeO32–und μ3-F–-überkappten Gd3-Ringen" (in en). Zeitschrift für anorganische und allgemeine Chemie 626 (8): 1725–1727. doi:10.1002/1521-3749(200008)626:8<1725::AID-ZAAC1725>3.0.CO;2-Q. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/1521-3749%28200008%29626%3A8%3C1725%3A%3AAID-ZAAC1725%3E3.0.CO%3B2-Q. 
  25. ↑ Lipp, Christian; Schleid, Thomas (August 2008). "HoF[SeO 3 ] und Ho 3 F[SeO 3 ] 4 : Zwei fluorid-derivatisierte Oxoselenate(IV) des Holmiums" (in en). Zeitschrift für anorganische und allgemeine Chemie 634 (10): 1662–1668. doi:10.1002/zaac.200800099. 
  26. ↑ Lipp, Christian; Schleid, Thomas (June 2008). "Er3F[SiO4][SeO3]2: An ErF3-Derivative with Two Different Kinds of Complex Oxoanions" (in de). Zeitschrift für anorganische und allgemeine Chemie 634 (6–7): 1025–1029. doi:10.1002/zaac.200700583. 
  27. ↑ Wu, Chao; Li, Longhua; Lin, Lin; Huang, Zhipeng; Humphrey, Mark G.; Zhang, Chi (2020-04-14). "Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution" (in en). Chemistry of Materials 32 (7): 3043–3053. doi:10.1021/acs.chemmater.0c00034. ISSN 0897-4756. 
  28. ↑ Cao, Xue-Li; Kong, Fang; Hu, Chun-Li; Xu, Xiang; Mao, Jiang-Gao (2014-08-18). "Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons" (in en). Inorganic Chemistry 53 (16): 8816–8824. doi:10.1021/ic501548m. ISSN 0020-1669. PMID 25102013. 
  29. ↑ Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units" (in en). Inorganic Chemistry 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. 
  30. ↑ Liang, Ming-Li; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2016-08-03). "BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution" (in en). Journal of the American Chemical Society 138 (30): 9433–9436. doi:10.1021/jacs.6b06680. ISSN 0002-7863. PMID 27428359. 
  31. ↑ Chung, Jee Yoon; Jo, Hongil; Yeon, Seongbeom; Byun, Hye Ryung; You, Tae-Soo; Jang, Joon I.; Ok, Kang Min (2020-07-01). "Bi3(SeO3)3(Se2O5)F: A Polar Bismuth Selenite Fluoride with Polyhedra of Highly Distortive Lone Pair Cations and Strong Second-Harmonic Generation Response" (in en). Chemistry of Materials 32 (17): 7318–7326. doi:10.1021/acs.chemmater.0c02167. ISSN 0897-4756. https://figshare.com/articles/journal_contribution/12656887. 
  32. ↑ 32.0 32.1 Shi, Shuangshuang; Luo, Min; Lin, Chensheng; Ye, Ning (2018). "A cation size effect on the framework structures in ABi 2 SeO 3 F 5 (A = K and Rb): first examples of alkali metal bismuth selenite fluorides" (in en). Dalton Transactions 47 (18): 6598–6604. doi:10.1039/C8DT00450A. ISSN 1477-9226. PMID 29700544. http://xlink.rsc.org/?DOI=C8DT00450A. 
  33. ↑ Shang, Meng; Halasyamani, P. Shiv (February 2020). "Mixed lone-pair and mixed anion compounds: Pb3(SeO3)(HSeO3)Br3, Pb3(SeO3)(OH)Br3, CdPb8(SeO3)4Cl4Br6 and RbBi(SeO3)F2" (in en). Journal of Solid State Chemistry 282: 121121. doi:10.1016/j.jssc.2019.121121. Bibcode: 2020JSSCh.28221121S. 
  34. ↑ 34.0 34.1 34.2 34.3 34.4 Gong, Ya-Ping; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2019-03-07). "Exploration of New Birefringent Crystals in Bismuth d 0 Transition Metal Selenites" (in en). Chemistry – A European Journal 25 (14): 3685–3694. doi:10.1002/chem.201806328. ISSN 0947-6539. PMID 30637825. 
  35. ↑ Jia, Ying-Jie; Zhang, Xingyu; Chen, Yi-Gang; Jiang, Xingxing; Song, Jia-Neng; Lin, Zheshuai; Zhang, Xian-Ming (2022-10-03). "PbBi(SeO 3 ) 2 F and Pb 2 Bi(SeO 3 ) 2 Cl 3 : Coexistence of Three Kinds of Stereochemically Active Lone-Pair Cations Exhibiting Excellent Nonlinear Optical Properties" (in en). Inorganic Chemistry 61 (39): 15368–15376. doi:10.1021/acs.inorgchem.2c01802. ISSN 0020-1669. PMID 36121404. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c01802. 
Salts and covalent derivatives of the fluoride ion
HF He
LiF BeF2 BF
BF3
B2F4 		CF4
other compounds 		NF3
FN3
N2F2
N2F4
NF5§ 		F2O
F2O2
other compounds 		F2 Ne
NaF MgF2 AlF
AlF3 		SiF4 P2F4
PF3
PF5 		S2F2
SF2
SF4
SF6 		ClF
ClF3
ClF5 		Ar
KF CaF
CaF2 		ScF3 TiF2
TiF3
TiF4 		VF2
VF3
VF4
VF5 		CrF2
CrF3
CrF4
CrF5
CrF6§ 		MnF2 FeF2
FeF3 		CoF2
CoF3 		NiF2 CuF
CuF2 		ZnF2 GaF2
GaF3 		GeF2
GeF4 		AsF3
AsF5 		Se2F2
SeF4
SeF6 		BrF
BrF3
BrF5 		KrF2
RbF SrF
SrF2 		YF3 ZrF3
ZrF4 		NbF4
NbF5 		MoF2
MoF3
MoF4
MoF5
MoF6 		TcF4
TcF6 		RuF3
RuF5
RuF6 		RhF3
RhF5
RhF6 		PdF2 AgF CdF2 InF
InF2
InF3 		SnF2
SnF4 		SbF3
SbF5 		Te3F2
TeF4
TeF6 		IF
IF3</br>IF5</br>IF7 		XeF2
XeF4
XeF6
CsF BaF2   HfF4 TaF5 WF2
WF3
WF4
WF5
WF6 		Re3F9
ReF4
ReF5
ReF6
ReF7 		OsF4
OsF5
OsF6 		IrF2
IrF3
IrF4
IrF5
IrF6 		PtF2
PtF4
PtF5
PtF6 		AuF
AuF3
Au2F10
AuF5•F2 		Hg2F2
HgF2
HgF4 		TlF PbF2
PbF4 		BiF3
BiF5 		PoF2
PoF4
PoF6 		AtF RnF2
FrF RaF2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
LaF3 CeF3
CeF4 		PrF3 NdF2,
NdF3 		PmF3 SmF2,
SmF3 		EuF2,
EuF3 		GdF3 TbF3 DyF2,
DyF3 		HoF3 ErF3 TmF2
TmF3 		YbF2
YbF3 		LuF3
AcF3 ThF4 PaF5 UF3
UF4
UF5
UF6 		NpF4
NpF6 		PuF3
PuF6 		AmF2
AmF3 		CmF3 BkF3 CfF3 EsF3 Fm Md No LrF3

§ means the substance has not been made.



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