Chemistry:Tellurite fluoride
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Short description: Class of chemical compounds
A tellurite fluoride is a mixed anion compound containing tellurite and fluoride ions. They have also been called oxyfluorotellurate(IV) where IV is the oxidation state of tellurium in tellurite.
Comparable compounds are sulfite fluorides or selenite fluorides.
List
| name | formula | ratio
TeO3:F |
mw | crystal system |
space group | unit cell Å | volume | density | optical | comment | references |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Li7(TeO3)3F | P63 | a =11.4178 c =4.8433 | band gap 4.75 eV | ||||||||
| KTe3O6F | 3:1 | rhombohedral | R3 | a=9.486, c=13.774, Z=6 | [1] | ||||||
| ScTeO3F | 239.56 | orthorhombic | Pnma | a = 5.7740 b = 22.062 c = 5.500 | 700.6 | colourless | [2] | ||||
| titanium(IV) tellurium(IV) trioxide difluoride | TiTeO3F2 | 1:1 | 361.50 | orthorhombic | Pnma | a = 7.392 b = 16.369 c=6.4886 Z=8 | 785.1 | colourless | [3] | ||
| divanadium(IV) ditellurium(IV) heptaoxide difluoride | V2Te2O7F2 | 2:2 | 507.38 | triclinic | P1 | a = 4.882 b = 5.112 c = 7.243 α = 108.17° β = 91.64° γ = 92.63° | 171.4 | green-brown | [3] | ||
| CrIIITeO3F | 1:1 | [4] | |||||||||
| FeTeO3F | 1:1 | 250.45 | monoclinic | P21/n | a = 5.0667 b = 5.0550 c = 12.397 β = 97.63° Z=4 | 314.72 | green | [4] | |||
| Co2TeO3F2 | 1:2 | 331.46 | orthorhombic | Pnma | a=7.3810 b=10.1936 c=5.3013 Z=4 | 398.86 | 5.520 | purple | [5] | ||
| Co15F2(TeO3)14 | 14:2 | 3380.35 | trigonal | R3 | a =11.6649 c =27.317 Z=3 | 3219.1 | 5.231 | blue | [6] | ||
| Cu7(TeO3)6F2 | 6:2 | triclinic | P1 | a =4.9844 b =9.4724 c =9.958, α =82.318° β =76.275° γ =78.847° | [7] | ||||||
| GaTeO3F | 1:1 | monoclinic | P21/n | a = 5.0625 b = 4.9873 c = 12.166 β = 97.952 (13)° Z=4 | 304.22 | colourless | [4] | ||||
| RbTe3O6F | 3:1 | ||||||||||
| InTeO3F | 1:1 | 309.42 | a = 7.939 b = 5.3867 c = 8.053 β = 91.06° | 344.35 | colourless | [8][2] | |||||
| InTe2O5F | 2:1 | orthorhombic | Cmmm | a = 7.850, b = 27.637, c = 4.098, Z = 4 | 889.1 | [8] | |||||
| In3TeO3F7 | 1:7 | orthorhombic | Cmmm | a = 7.850(2) A, b = 27.637(6) A, c = 4.098 | [8][9] | ||||||
| In3(SO4)(TeO3)2F3(H2O) | P212121 | a =8.3115 b =9.4341 c =14.807 | band gap 4.10 eV | [10] | |||||||
| BaF2TeF2(OH)2 | Pmn21 | SHG ~3 × KDP | fluorotellurite | [11] | |||||||
| Ba2Ga3F3(Te6F2O16) | a =8.8753 b =8.8753 c =11.655 | band gap 4.4 eV | [12] | ||||||||
| Ba(MoOF2)(TeO4) | 1:2 | 478.87 | monoclinic | P21/c | a 5.4281 b 10.1306 c 12.3186 β 116.145° Z=4 | 608.09 | 5.231 | colourless | [13] | ||
| Ba(MoO2F)2(TeO3)2 | 2:2 | 782.42 | orthorhombic | Aba2 | a=12.5605 b=11.0264 c=7.2858 Z=4 | 1009.1 | 5.150 | colourless | [14] | ||
| Ba(WOF2)(TeO4) | 566.77 | monoclinic | P21/c | a 5.4483 b 10.0179 c 12.3134 β 115.422(6)° Z=4 | 607.00 | 6.202 | green | [13] | |||
| Pb2Al3F3(Te6F2O16) | orthorhombic | P4/mbm | a =8.7627 b =8.7627 c =11.235 | band gap 4.1 eV | [12] | ||||||
| Pb2Ga3F3(Te6F2O16) | orthorhombic | P4/mbm | a =8.8439 b =8.8439 c =11.580 | band gap 4.2 eV | [12] | ||||||
| Bi4TeO4F2(TeO3)2(SeO3)2 | 2:2 | 1670.64 | monoclinic | P21/c | a=7.0304 b=6.6782 c=17.355 β=106.155 Z=2 | 782.66 | 7.089 | colourless | [15] |
References
- ↑ Laval, J.P.; Guillet, L.; Frit, B. (April 2002). "KTe3O6F: a new layer TeO2 structure, stuffed with KF units" (in en). Solid State Sciences 4 (4): 549–556. doi:10.1016/S1293-2558(02)01290-6. Bibcode: 2002SSSci...4..549L. https://linkinghub.elsevier.com/retrieve/pii/S1293255802012906.
- ↑ 2.0 2.1 Jennene Boukharrata, Nefla; Laval, Jean-Paul; Thomas, Philippe (2008-07-15). "Two new types of oxyfluorotellurates(IV): ScTeO 3 F and InTeO 3 F". Acta Crystallographica Section C Crystal Structure Communications 64 (7): i57–i61. doi:10.1107/S0108270108017150. ISSN 0108-2701. PMID 18599966. Bibcode: 2008AcCrC..64I..57J. http://scripts.iucr.org/cgi-bin/paper?S0108270108017150.
- ↑ 3.0 3.1 Laval, Jean Paul; Jennene Boukharrata, Nefla (2009-01-15). "New vanadium(IV) and titanium(IV) oxyfluorotellurates(IV): V 2 Te 2 O 7 F 2 and TiTeO 3 F 2". Acta Crystallographica Section C Crystal Structure Communications 65 (1): i1–i6. doi:10.1107/S0108270108036755. ISSN 0108-2701. PMID 19129587. Bibcode: 2009AcCrC..65I...1L. http://scripts.iucr.org/cgi-bin/paper?S0108270108036755.
- ↑ 4.0 4.1 4.2 Laval, Jean Paul; Jennene Boukharrata, Nefla; Thomas, Philippe (2008-02-15). "New oxyfluorotellurates(IV): M TeO 3 F ( M = Fe III , Ga III and Cr III )". Acta Crystallographica Section C Crystal Structure Communications 64 (2): i12–i14. doi:10.1107/S0108270107062683. ISSN 0108-2701. PMID 18252985. Bibcode: 2008AcCrC..64I..12L. http://scripts.iucr.org/cgi-bin/paper?S0108270107062683.
- ↑ Hu, Shichao; Johnsson, Mats (2012). "Synthesis and crystal structure of two synthetic oxofluoride framework compounds – Co2TeO3F2 and Co2SeO3F2" (in en). Dalton Transactions 41 (41): 12786–12789. doi:10.1039/c2dt31188g. ISSN 1477-9226. PMID 22968840. http://xlink.rsc.org/?DOI=c2dt31188g.
- ↑ Lü, Minfeng; Jiang, Jianhua; Zhu, Bei; Zhao, Yuwei; Zhu, Tianyu; Yang, Haoming; Jin, Yong; Kabbour, Houria et al. (2020). "Lone-pair self-containment in pyritohedron-shaped closed cavities: optimized hydrothermal synthesis, structure, magnetism and lattice thermal conductivity of Co 15 F 2 (TeO 3 ) 14" (in en). Dalton Transactions 49 (7): 2234–2243. doi:10.1039/C9DT04176A. ISSN 1477-9226. PMID 32003383. http://xlink.rsc.org/?DOI=C9DT04176A.
- ↑ Hu, Shichao; Mace, Amber; Johnsson, Mats; Gnezdilov, Vladimir; Lemmens, Peter; Tapp, Joshua; Möller, Angela (2014-07-21). "Crystal Structure and Magnetic Properties of the S = 1 / 2 Quantum Spin System Cu 7 (TeO 3 ) 6 F 2 with Mixed Dimensionality" (in en). Inorganic Chemistry 53 (14): 7661–7667. doi:10.1021/ic5009686. ISSN 0020-1669. PMID 24956023. https://pubs.acs.org/doi/10.1021/ic5009686.
- ↑ 8.0 8.1 8.2 Jennene Boukharrata, N.; Laval, J.P. (February 2011). "Synthesis and structure determination of In3TeO3F7: An indium oxyfluorotellurate IV derived from W bronze structure with Te4+ in hexagonal tunnels" (in en). Journal of Alloys and Compounds 509 (5): 1517–1522. doi:10.1016/j.jallcom.2010.10.139. https://linkinghub.elsevier.com/retrieve/pii/S0925838810026691.
- ↑ Jennene Boukharrata, N.; Laval, J.P. (February 2011). "Synthesis and structure determination of In3TeO3F7: An indium oxyfluorotellurate IV derived from W bronze structure with Te4+ in hexagonal tunnels" (in en). Journal of Alloys and Compounds 509 (5): 1517–1522. doi:10.1016/j.jallcom.2010.10.139. https://linkinghub.elsevier.com/retrieve/pii/S0925838810026691.
- ↑ Gong, Ya-Ping; Ma, Yun-Xiang; Ying, Shao-Ming; Mao, Jiang-Gao; Kong, Fang (2019-08-19). "Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)" (in en). Inorganic Chemistry 58 (16): 11155–11163. doi:10.1021/acs.inorgchem.9b01730. ISSN 0020-1669. PMID 31365247. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b01730.
- ↑ Zhou, Jinjie; Wu, Hongping; Yu, Hongwei; Jiang, Shutong; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng; Halasyamani, P. Shiv (2020-03-11). "BaF 2 TeF 2 (OH) 2 : A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering" (in en). Journal of the American Chemical Society 142 (10): 4616–4620. doi:10.1021/jacs.0c00702. ISSN 0002-7863. PMID 32096982. https://pubs.acs.org/doi/10.1021/jacs.0c00702.
- ↑ 12.0 12.1 12.2 Li, Peng-Fei; Kong, Fang; Mao, Jiang-Gao (June 2020). "MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings" (in en). Journal of Solid State Chemistry 286: 121288. doi:10.1016/j.jssc.2020.121288. Bibcode: 2020JSSCh.28621288L. https://linkinghub.elsevier.com/retrieve/pii/S0022459620301183.
- ↑ 13.0 13.1 Liang, Ming-Li; Ma, Yun-Xiang; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2018). "A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron" (in en). Dalton Transactions 47 (5): 1513–1519. doi:10.1039/C7DT04442A. ISSN 1477-9226. PMID 29313546. http://xlink.rsc.org/?DOI=C7DT04442A.
- ↑ Liang, Ming-Li; Ma, Yun-Xiang; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2020-11-24). "Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response" (in en). Chemistry of Materials 32 (22): 9688–9695. doi:10.1021/acs.chemmater.0c03353. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.0c03353.
- ↑ Gong, Ya-Ping; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2019-03-07). "Exploration of New Birefringent Crystals in Bismuth d 0 Transition Metal Selenites" (in en). Chemistry – A European Journal 25 (14): 3685–3694. doi:10.1002/chem.201806328. ISSN 0947-6539. PMID 30637825.
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