Chemistry:Tantalum pentoxide

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Tantalum pentoxide
Kristallstruktur Triuranoctoxid.png
     Ta      O
Tantalum(V) oxide sample.jpg
Names
IUPAC name
Tantalum(V) oxide
Systematic IUPAC name
Ditantalum pentaoxide
Identifiers
3D model (JSmol)
ChemSpider
UNII
Properties
Ta2O5
Molar mass 441.893 g/mol
Appearance white, odorless powder
Density β-Ta2O5 = 8.18 g/cm3[1]
α-Ta2O5 = 8.37 g/cm3
Melting point 1,872 °C (3,402 °F; 2,145 K)
negligible
Solubility insoluble in organic solvents and most mineral acids, reacts with HF
Band gap 3.8–5.3 eV
−32.0×10−6 cm3/mol
2.275
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Tantalum pentoxide, also known as tantalum(V) oxide, is the inorganic compound with the formula Ta2O5. It is a white solid that is insoluble in all solvents but is attacked by strong bases and hydrofluoric acid. Ta2O5 is an inert material with a high refractive index and low absorption (i.e. colourless), which makes it useful for coatings.[2] It is also extensively used in the production of capacitors, due to its high dielectric constant.

Preparation

Occurrence

Tantalum occurs in the minerals tantalite and columbite (columbium being an archaic name for niobium), which occur in pegmatites, an igneous rock formation. Mixtures of columbite and tantalite are called coltan. Tantalite was discovered by Anders Gustaf Ekeberg[when?] at Ytterby, Sweden, and Kimoto, Finland. The minerals microlite and pyrochlore contain approximately 70% and 10% Ta, respectively.

Refining

Tantalum ores often contain significant amounts of niobium, which is itself a valuable metal. As such, both metals are extracted so that they may be sold. The overall process is one of hydrometallurgy and begins with a leaching step; in which the ore is treated with hydrofluoric acid and sulfuric acid to produce water-soluble hydrogen fluorides, such as the heptafluorotantalate. This allows the metals to be separated from the various non-metallic impurities in the rock.

(FeMn)(NbTa)2O6 + 16 HF → H2[TaF7] + H2[NbOF5] + FeF2 + MnF2 + 6 H2O

The tantalum and niobium hydrogenflorides are then removed from the aqueous solution by liquid-liquid extraction using organic solvents, such as cyclohexanone or methyl isobutyl ketone. This step allows the simple removal of various metal impurities (e.g. iron and manganese) which remain in the aqueous phase in the form of fluorides. Separation of the tantalum and niobium is then achieved by pH adjustment. Niobium requires a higher level of acidity to remain soluble in the organic phase and can hence be selectively removed by extraction into less acidic water. The pure tantalum hydrogen fluoride solution is then neutralised with aqueous ammonia to give hydrated tantalum oxide (Ta2O5(H2O)x), which is calcinated to tantalum pentoxide (Ta2O5) as described in these idealized equations:[3]

H2[TaF7] + 5 H2O + 7 NH3 → 1/2 Ta2O5(H2O)5 + 7 NH4F
Ta2O5(H2O)5 → Ta2O5 + 5 H2O

Natural pure tantalum oxide is known as the mineral tantite, although it is exceedingly rare.[4]

From alkoxides

Tantalum oxide is frequently used in electronics, often in the form of thin films. For these applications it can be produced by MOCVD (or related techniques), which involves the hydrolysis of its volatile halides or alkoxides:

Ta2(OEt)10 + 5 H2O → Ta2O5 + 10 EtOH
2 TaCl5 + 5 H2O → Ta2O5 + 10 HCl

Structure and properties

The crystal structure of tantalum pentoxide has been the matter of some debate. The bulk material is disordered,[5] being either amorphous or polycrystalline; with single crystals being difficult to grow. As such Xray crystallography has largely been limited to powder diffraction, which provides less structural information.

At least 2 polymorphs are known to exist. A low temperature form, known as L- or β-Ta2O5, and the high temperature form known as H- or α-Ta2O5. The transition between these two forms is slow and reversible; taking place between 1000 and 1360 °C, with a mixture of structures existing at intermediate temperatures.[5] The structures of both polymorphs consist of chains built from octahedral TaO6 and pentagonal bipyramidal TaO7 polyhedra sharing opposite vertices; which are further joined by edge-sharing.[6][7] The overall crystal system is orthorhombic in both cases, with the space group of β-Ta2O5 being identified as Pna2 by single crystal X-ray diffraction.[8] A high pressure form (Z-Ta2O5) has also been reported, in which the Ta atoms adopt a 7 coordinate geometry to give a monoclinic structure (space group C2).[9]

Purely amorphous tantalum pentoxide has a similar local structure to the crystalline polymorphs, built from TaO6 and TaO7 polyhedra, while the molten liquid phase has a distinct structure based on lower coordination polyhedra, mainly TaO5 and TaO6.[10]

The difficulty in forming material with a uniform structure has led to variations in its reported properties. Like many metal oxides Ta2O5 is an insulator and its band gap has variously been reported as being between 3.8 and 5.3 eV, depending on the method of manufacture.[11][12][13] In general the more amorphous the material the greater its observed band gap. These observed values are significantly higher than those predicted by computational chemistry (2.3 - 3.8 eV).[14][15][16]

Its dielectric constant is typically about 25[17] although values of over 50 have been reported.[18] In general tantalum pentoxide is considered to be a high-k dielectric material.

Reactions

Ta2O5 does not react appreciably with either HCl or HBr, however it will dissolve in hydrofluoric acid, and reacts with potassium bifluoride and HF according to the following equation:[19][20]

Ta2O5 + 4 KHF2 + 6 HF → 2 K2[TaF7] + 5 H2O

Ta2O5 can be reduced to metallic Ta via the use of metallic reductants such as calcium and aluminium.

Ta2O5 + 5 Ca → 2 Ta + 5 CaO
Several 10 μF × 30 V DC rated tantalum capacitors, solid-bodied epoxy-dipped type. Polarity is explicitly marked.

Uses

In electronics

Owing to its high band gap and dielectric constant, tantalum pentoxide has found a variety of uses in electronics, particularly in tantalum capacitors. These are used in automotive electronics, cell phones, and pagers, electronic circuitry; thin-film components; and high-speed tools. In the 1990s, interest grew in the use of tantalum oxide as a high-k dielectric for DRAM capacitor applications.[21][22]

It is used in on-chip metal-insulator-metal capacitors for high frequency CMOS integrated circuits. Tantalum oxide may have applications as the charge trapping layer for non-volatile memories.[23][24] There are applications of tantalum oxide in resistive switching memories.[25]

In optics

Due to its high refractive index, Ta2O5 has been utilized in the fabrication of the glass of photographic lenses.[2][26] It can also be deposited as an optical coating with typical applications being antireflection and multilayer filter coatings in near UV to near infrared. [27]

Ta2O5 has also been found to have a high nonlinear refractive index,[28][29] on the order of three times that of silicon nitiride, which has led to interest in the utilization of Ta2O5 in photonic integrated circuits. Ta2O5 has been recently utilized as the material platform for the generation of supercontinuum[30][31] and Kerr frequency combs[29] in waveguides and optical ring resonators. Through the addition of rare-earth dopants in the deposition process, Ta2O5 waveguide lasers have been presented for a variety of applications, such as remote sensing and LiDAR.[32][33][34]

References

  1. ↑ Reisman, Arnold; Holtzberg, Frederic; Berkenblit, Melvin; Berry, Margaret (20 September 1956). "Reactions of the Group VB Pentoxides with Alkali Oxides and Carbonates. III. Thermal and X-Ray Phase Diagrams of the System K2O or K2CO3 with Ta2O5". Journal of the American Chemical Society 78 (18): 4514–4520. doi:10.1021/ja01599a003. 
  2. ↑ 2.0 2.1 Fairbrother, Frederick (1967). The Chemistry of Niobium and Tantalum. New York: Elsevier Publishing Company. pp. 1–28. ISBN 978-0-444-40205-9. https://archive.org/details/chemistryofniobi0000fair. 
  3. ↑ Anthony Agulyanski (2004). "Fluorine chemistry in the processing of tantalum and niobium". in Anatoly Agulyanski. Chemistry of Tantalum and Niobium Fluoride Compounds (1st ed.). Burlington: Elsevier. ISBN 9780080529028. 
  4. ↑ "Tantite: Tantite mineral information and data". http://www.mindat.org/min-3884.html. 
  5. ↑ 5.0 5.1 Askeljung, Charlotta; Marinder, Bengt-Olov; Sundberg, Margareta (1 November 2003). "Effect of heat treatment on the structure of L-Ta2O5". Journal of Solid State Chemistry 176 (1): 250–258. doi:10.1016/j.jssc.2003.07.003. Bibcode: 2003JSSCh.176..250A. 
  6. ↑ Stephenson, N. C.; Roth, R. S. (1971). "Structural systematics in the binary system Ta2O5–WO3. V. The structure of the low-temperature form of tantalum oxide L-Ta2O5". Acta Crystallographica Section B 27 (5): 1037–1044. doi:10.1107/S056774087100342X. 
  7. ↑ Wells, A.F. (1947). Structural Inorganic Chemistry. Oxford: Clarendon Press. 
  8. ↑ Wolten, G. M.; Chase, A. B. (1 August 1969). "Single-crystal data for β Ta2O5 and A KPO3". Zeitschrift für Kristallographie 129 (5–6): 365–368. doi:10.1524/zkri.1969.129.5-6.365. Bibcode: 1969ZK....129..365W. 
  9. ↑ Zibrov, I. P.; Filonenko, V. P.; Sundberg, M.; Werner, P.-E. (1 August 2000). "Structures and phase transitions of B-Ta2O5 and Z-Ta2O5: two high-pressure forms of Ta2O5". Acta Crystallographica Section B 56 (4): 659–665. doi:10.1107/S0108768100005462. PMID 10944257. 
  10. ↑ Alderman, O. L. G.; Benmore, C.J.; Neuefeind, J.; Coillet, E.; Mermet, A.; Martinez, V.; Tamalonis, A.; Weber, R. (2018). "Amorphous tantala and its relationship with the molten state". Physical Review Materials 2 (4): 043602. doi:10.1103/PhysRevMaterials.2.043602. Bibcode: 2018PhRvM...2d3602A. 
  11. ↑ Kukli, Kaupo; Aarik, Jaan; Aidla, Aleks; Kohan, Oksana; Uustare, Teet; Sammelselg, Väino (1995). "Properties of tantalum oxide thin films grown by atomic layer deposition". Thin Solid Films 260 (2): 135–142. doi:10.1016/0040-6090(94)06388-5. Bibcode: 1995TSF...260..135K. 
  12. ↑ Fleming, R. M.; Lang, D. V.; Jones, C. D. W.; Steigerwald, M. L.; Murphy, D. W.; Alers, G. B.; Wong, Y.-H.; van Dover, R. B. et al. (1 January 2000). "Defect dominated charge transport in amorphous Ta2O5 thin films". Journal of Applied Physics 88 (2): 850. doi:10.1063/1.373747. Bibcode: 2000JAP....88..850F. 
  13. ↑ Murawala, Prakash A.; Sawai, Mikio; Tatsuta, Toshiaki; Tsuji, Osamu; Fujita, Shizuo; Fujita, Shigeo (1993). "Structural and Electrical Properties of Ta2O5 Grown by the Plasma-Enhanced Liquid Source CVD Using Penta Ethoxy Tantalum Source". Japanese Journal of Applied Physics 32 (Part 1, No. 1B): 368–375. doi:10.1143/JJAP.32.368. Bibcode: 1993JaJAP..32..368M. 
  14. ↑ Ramprasad, R. (1 January 2003). "First principles study of oxygen vacancy defects in tantalum pentoxide". Journal of Applied Physics 94 (9): 5609–5612. doi:10.1063/1.1615700. Bibcode: 2003JAP....94.5609R. 
  15. ↑ Sawada, H.; Kawakami, K. (1 January 1999). "Electronic structure of oxygen vacancy in Ta2O5". Journal of Applied Physics 86 (2): 956. doi:10.1063/1.370831. Bibcode: 1999JAP....86..956S. 
  16. ↑ Nashed, Ramy; Hassan, Walid M. I.; Ismail, Yehea; Allam, Nageh K. (2013). "Unravelling the interplay of crystal structure and electronic band structure of tantalum oxide (Ta2O5)". Physical Chemistry Chemical Physics 15 (5): 1352–7. doi:10.1039/C2CP43492J. PMID 23243661. Bibcode: 2013PCCP...15.1352N. 
  17. ↑ Macagno, V.; Schultze, J.W. (1 December 1984). "The growth and properties of thin oxide layers on tantalum electrodes". Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 180 (1–2): 157–170. doi:10.1016/0368-1874(84)83577-7. 
  18. ↑ Hiratani, M.; Kimura, S.; Hamada, T.; Iijima, S.; Nakanishi, N. (1 January 2002). "Hexagonal polymorph of tantalum–pentoxide with enhanced dielectric constant". Applied Physics Letters 81 (13): 2433. doi:10.1063/1.1509861. Bibcode: 2002ApPhL..81.2433H. 
  19. ↑ Agulyansky, A (2003). "Potassium fluorotantalate in solid, dissolved and molten conditions". J. Fluorine Chemistry 123 (2): 155–161. doi:10.1016/S0022-1139(03)00190-8. 
  20. ↑ Brauer, Georg (1965). Handbook of preparative inorganic chemistry. Academic Press. pp. 256. ISBN 978-0-12-395591-3. 
  21. ↑ Ezhilvalavan, S.; Tseng, T. Y. (1999). "Preparation and properties of tantalum pentoxide (Ta2O5) thin films for ultra large scale integrated circuits (ULSIs) application - a review". Journal of Materials Science: Materials in Electronics 10 (1): 9–31. doi:10.1023/A:1008970922635. 
  22. ↑ Chaneliere, C; Autran, J L; Devine, R A B; Balland, B (1998). "Tantalum pentoxide (Ta2O5) thin films for advanced dielectric applications". Materials Science and Engineering: R 22 (6): 269–322. doi:10.1016/S0927-796X(97)00023-5. 
  23. ↑ Wang, X (2004). "A Novel MONOS-Type Nonvolatile Memory Using High-κ Dielectrics for Improved Data Retention and Programming Speed". IEEE Transactions on Electron Devices 51 (4): 597–602. doi:10.1109/TED.2004.824684. Bibcode: 2004ITED...51..597W. 
  24. ↑ Zhu, H (2013). "Design and Fabrication of Ta2O5 Stacks for Discrete Multibit Memory Application". IEEE Transactions on Nanotechnology 12 (6): 1151–1157. doi:10.1109/TNANO.2013.2281817. Bibcode: 2013ITNan..12.1151Z. 
  25. ↑ Lee, M-.J (2011). "A fast, high-endurance and scalable non-volatile memory device made from asymmetric Ta2O5−x/TaO2−x bilayer structures". Nature Materials 10 (8): 625–630. doi:10.1038/NMAT3070. PMID 21743450. Bibcode: 2011NatMa..10..625L. 
  26. ↑ Musikant, Solomon (1985). "Optical Glas Composition". Optical Materials: An Introduction to Selection and Application. CRC Press. p. 28. ISBN 978-0-8247-7309-0. https://books.google.com/books?id=iJEXMF3JBtQC&pg=PA28. 
  27. ↑ "Tantalum Oxide for Optical Coating Applications". https://materion.com/resource-center/product-data-and-related-literature/inorganic-chemicals/oxides/tantalum-oxide-ta205-for-optical-coating. 
  28. ↑ Tai, Chao-Yi; Wilkinson, James S.; Perney, Nicolas M. B.; Netti, M. Caterina; Cattaneo, F.; Finlayson, Chris E.; Baumberg, Jeremy J. (2004-10-18). "Determination of nonlinear refractive index in a Ta2O5 rib waveguide using self-phase modulation" (in EN). Optics Express 12 (21): 5110–5116. doi:10.1364/OPEX.12.005110. ISSN 1094-4087. PMID 19484065. Bibcode: 2004OExpr..12.5110T. https://opg.optica.org/oe/abstract.cfm?uri=oe-12-21-5110. 
  29. ↑ 29.0 29.1 Jung, Hojoong; Yu, Su-Peng; Carlson, David R.; Drake, Tara E.; Briles, Travis C.; Papp, Scott B. (2021-06-20). "Tantala Kerr nonlinear integrated photonics" (in EN). Optica 8 (6): 811–817. doi:10.1364/OPTICA.411968. ISSN 2334-2536. Bibcode: 2021Optic...8..811J. https://opg.optica.org/optica/abstract.cfm?uri=optica-8-6-811. 
  30. ↑ Woods, Jonathan R. C.; Daykin, Jake; Tong, Amy S. K.; Lacava, Cosimo; Petropoulos, Periklis; Tropper, Anne C.; Horak, Peter; Wilkinson, James S. et al. (2020-10-12). "Supercontinuum generation in tantalum pentoxide waveguides for pump wavelengths in the 900 nm to 1500 nm spectral region" (in en). Optics Express 28 (21): 32173–32184. doi:10.1364/OE.403089. ISSN 1094-4087. PMID 33115180. Bibcode: 2020OExpr..2832173W. https://opg.optica.org/abstract.cfm?URI=oe-28-21-32173. 
  31. ↑ Fan, Ranran; Lin, Yuan-Yao; Chang, Lin; Boes, Andreas; Bowers, John; Liu, Jia-Wei; Lin, Chao-Hong; Wang, Te-Keng et al. (2021-04-12). "Higher order mode supercontinuum generation in tantalum pentoxide (Ta2O5) channel waveguide" (in en). Scientific Reports 11 (1): 7978. doi:10.1038/s41598-021-86922-8. ISSN 2045-2322. PMID 33846403. Bibcode: 2021NatSR..11.7978F. 
  32. ↑ Tong, Amy S. K.; Mitchell, Colin J.; Aghajani, Armen; Sessions, Neil; Senthil Murugan, G.; Mackenzie, Jacob I.; Wilkinson, James S. (2020-09-01). "Spectroscopy of thulium-doped tantalum pentoxide waveguides on silicon" (in en). Optical Materials Express 10 (9): 2201. doi:10.1364/OME.397011. ISSN 2159-3930. Bibcode: 2020OMExp..10.2201T. https://opg.optica.org/abstract.cfm?URI=ome-10-9-2201. 
  33. ↑ Aghajani, A; Murugan, G S; Sessions, N P; Apostolopoulos, V; Wilkinson, J S (2015-06-17). "Spectroscopy of high index contrast Yb:Ta 2 O 5 waveguides for lasing applications". Journal of Physics: Conference Series 619 (1): 012031. doi:10.1088/1742-6596/619/1/012031. ISSN 1742-6596. Bibcode: 2015JPhCS.619a2031A. 
  34. ↑ Subramani, Ananth Z.; Oton, Claudio J.; Shepherd, David P.; Wilkinson, James S. (November 2010). "Erbium-Doped Waveguide Laser in Tantalum Pentoxide". IEEE Photonics Technology Letters 22 (21): 1571–1573. doi:10.1109/LPT.2010.2072495. ISSN 1041-1135. Bibcode: 2010IPTL...22.1571S. https://ieeexplore.ieee.org/document/5560730. 



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