Chemistry:Americium hexafluoride
From HandWiki
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| Names | |
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| Other names
Americium(VI) fluoride
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| Identifiers | |
3D model (JSmol)
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| Properties | |
| AmF6 | |
| Molar mass | 357 g·mol−1 |
| Related compounds | |
Related compounds
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Uranium hexafluoride Curium hexafluoride Einsteinium hexafluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Americium hexafluoride is an inorganic chemical compound of americium metal and fluorine with the chemical formula AmF6. It is still a hypothetical compound.[1][2] Synthesis by fluorination of americium tetrafluoride was unsuccessfully attempted in 1990.[3] A thermochromatographic identification in 1986 remains inconclusive.[4] Calculations suggest that it may be distorted from octahedral symmetry.[4]
Synthesis
It is proposed that AmF6 can be prepared by in both the condensed and gaseous states by the reaction of KrF2 with AmF3 in anhydrous HF at 313–333 K.[5]
- AmF
3 + KrF
2 → AmF
6 + Kr[6]
- AmF
References
- ↑ Meyer, G.; Morss, L. R. (6 December 2012) (in en). Synthesis of Lanthanide and Actinide Compounds. Springer Science & Business Media. p. 80. ISBN 978-94-011-3758-4. https://books.google.com/books?id=z0jvCAAAQBAJ&dq=Americium+hexafluoride&pg=PA80. Retrieved 29 March 2023.
- ↑ O'Donnell, T. A. (8 June 2017) (in en). The Chemistry of Fluorine: Comprehensive Inorganic Chemistry. Elsevier. p. 1093. ISBN 978-1-4831-4642-3. https://books.google.com/books?id=ED79BAAAQBAJ&dq=Americium+hexafluoride&pg=PA1093. Retrieved 29 March 2023.
- ↑ Malm, J. G.; Weinstock, B.; Weaver, E. E. (1958). "The Preparation and Properties of NpF6; a Comparison with PuF6". The Journal of Physical Chemistry 62 (12): 1506–1508. doi:10.1021/j150570a009.
- ↑ 4.0 4.1 Seppelt, Konrad (2015). "Molecular Hexafluorides". Chemical Reviews 115 (2): 1296–1306. doi:10.1021/cr5001783. PMID 25418862.
- ↑ Silva, R. J.; Bidoglio, G.; Robouch, P. B.; Puigdomenech, I.; Wanner, H.; Rand, M. H. (2 December 2012) (in en). Chemical Thermodynamics of Americium. Newnes. p. 114. ISBN 978-0-444-59935-3. https://books.google.com/books?id=yK3sMN_6llAC&dq=Americium+hexafluoride&pg=PA114. Retrieved 29 March 2023.
- ↑ Прусаков, Владимир Николаевич (2013) (in ru). Избранные научные труды. Rosatom. p. 59. http://elib.biblioatom.ru/text/prusakov_2013/go,58/. Retrieved 29 March 2023.
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