Chemistry:Osmium heptafluoride
From HandWiki
| Names | |
|---|---|
| Other names
Osmium(VII) fluoride
| |
| Identifiers | |
3D model (JSmol)
|
|
| |
| |
| Properties | |
| F7Os | |
| Molar mass | 323.22 g·mol−1 |
| Structure | |
| Pentagonal bipiramidal (calculated)[1] | |
| Related compounds | |
Related compounds
|
Rhenium heptafluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Osmium heptafluoride is an inorganic chemical compound of osmium metal and fluorine with the chemical formula OsF7.[2][3] It was first reported in 1966 by the reaction of fluorine and osmium at 600 °C and 400 atm,[4] but later experiments can’t reproduce this compound.[5]
Physical properties
Osmium(VII) fluoride forms a bluish-yellow hygroscopic substance, extremely unstable.[6] The compound starts decomposing at –100 °C. It should be stored in a nickel vessel at the temperature of liquid nitrogen.
Chemical properties
Osmium heptafluoride decomposes to osmium hexafluoride when slightly heated:
- 2OsF
7 → 2OsF
6 + F
2
- 2OsF
References
- ↑ Bayerische Julius-Maximilians-Universität Würzburg (2006). The Highest Oxidation States of the 5d Transition Metals: a Quantum-Chemical Study (Report). Chemical Society. http://opus.bibliothek.uni-wuerzburg.de/volltexte/2006/1940/pdf/The_Highest_Oxidation_States_of_the_5d_Transition_Metals.pdf. Retrieved 2011-06-20.
- ↑ "WebElements Periodic Table » Osmium » osmium heptafluoride". webelements.com. https://www.webelements.com/compounds/osmium/osmium_heptafluoride.html.
- ↑ Hawkins, Donald T. (6 December 2012) (in en). Binary Fluorides: Free Molecular Structures and Force Fields A Bibliography (1957–1975). Springer Science & Business Media. p. 42. ISBN 978-1-4684-6147-3. https://books.google.com/books?id=kOHgBwAAQBAJ&dq=osmium+heptafluoride&pg=PA42. Retrieved 19 April 2023.
- ↑ Glemser, Oskar; Roesky, Herbert W.; Hellberg, Karl-Heinz; Werther, Heinz-Ulrich (1966). "Darstellung und Eigenschaften von Osmiumheptafluorid". Chemische Berichte (Wiley) 99 (8): 2652–2662. doi:10.1002/cber.19660990834. ISSN 0009-2940.
- ↑ Shorafa, Hashem; Seppelt, Konrad (1 September 2006). "Osmium(VII) Fluorine Compounds". Inorganic Chemistry 45 (19): 7929–7934. doi:10.1021/ic0608290. PMID 16961386. https://pubs.acs.org/doi/10.1021/ic0608290.
- ↑ Edwards, A. J. (1 November 1983). "Structures of the binary fluorides" (in en). Advances in Inorganic Chemistry (Academic Press) 27: 108. ISBN 9780080578767. https://books.google.com/books?id=W4RngLN275wC&dq=osmium+heptafluoride&pg=PA108. Retrieved 19 April 2023.
 |  |
