Chemistry:Berkelium(III) chloride
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| Properties | |
| BkCl3 | |
| Molar mass | 353.36 g/mol |
| Appearance | Green solid |
| Melting point | 603 °C (1,117 °F; 876 K)[1] |
| Soluble | |
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| Hexagonal | |
| P63/m | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Berkelium(III) chloride also known as berkelium trichloride, is a chemical compound with the formula BkCl3. It is a water-soluble green salt with a melting point of 603 °C. This compound forms the hexahydrate, BkCl3·6H2O.
Preparation and reactions
This compound was first prepared in 1970 by reacting hydrogen chloride gas and berkelium(IV) oxide or berkelium(III) oxide at 520 °C:[2]
- Bk2O3 + 6HCl → 2BkCl3 + 3H2O
Berkelium(III) chloride reacts with beryllocene to produce berkelocene(Bk(C5H5)3).[3] It also reacts with oxalic acid to produce berkelium oxalate. This reaction is used to purify this compound, by reacting the oxalate with hydrochloric acid.[4]
Structure
Anhydrous berkelium(III) chloride has a hexagonal crystal structure, is isostructural to uranium trichloride, and has the person symbol hP6. When heated it its melting point, it converts to an orthorhombic phase.[2] However, the hexahydrate has a monoclinic crystal structure and is isostructural to americium trichloride hexahydrate with the lattice constants a = 966 pm, b = 654 pm and c = 797 pm.[5] This hexahydrate consists of BkCl2(OH2)6+ ions and Cl− ions.
Complexes
Caesium sodium berkelium chloride is known with the formula Cs2NaBkCl6 and is produced by the reaction of berkelium(III) hydroxide, hydrochloric acid, and caesium chloride.[6]
References
- ↑ Holleman, Arnold F. and Wiberg, Nils Textbook of Inorganic Chemistry, 102 Edition, de Gruyter, Berlin 2007, ISBN:978-3-11-017770-1
- ↑ 2.0 2.1 J. R. Peterson; B. B. Cunningham (1968). "Crystal structures and lattice parameters of the compounds of berkelium—II: Berkelium trichloride" (in en). Journal of Inorganic and Nuclear Chemistry 3 (3): 823–828. doi:10.1016/S0898-8838(08)60204-4.
- ↑ Peter G. Laubereau; John H. Burns (1970). "Microchemical preparation of tricyclopentadienyl compounds of berkelium, californium, and some lanthanide elements" (in en). Inorg. Chem. 9 (5): 1091–1095. doi:10.1021/ic50087a018.
- ↑ J. R. Peterson; J. P. Young; D. D. Ensor; R. G. Haire (1986). "Absorption spectrophotometric and x-ray diffraction studies of the trichlorides of berkelium-249 and californium-249". Inorg. Chem. (en) 25 (21): 3779–3782. doi:10.1021/ic00241a015.
- ↑ John H. Burns; Joseph Richard Peterson (1971). "Crystal structures of americium trichloride hexahydrate and berkelium trichloride hexahydrate" (in en). Inorg. Chem. 10 (1): 147–151. doi:10.1021/ic50095a029.
- ↑ Peterson J. R. and Hobart D. E. "The Chemistry of Berkelium" in Harry Julius Emeléus (Ed.) Advances in inorganic chemistry and radiochemistry, Volume 28, Academic Press, 1984 ISBN:0-12-023628-1, pp. 29–64, doi:10.1016/S0898-8838(08)60204-4
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