Chemistry:Nitride iodide

From HandWiki
Short description: Class of chemical compounds

An iodide nitride is a mixed anion compound containing both iodide (I−) and nitride ions (N3−). Another name is metalloiodonitrides. They are a subclass of halide nitrides or pnictide halides.[1] Some different kinds include ionic alkali or alkaline earth salts, small clusters where metal atoms surround a nitrogen atom, layered group 4 element 2-dimensional structures (which could be exfoliated to a monolayer), and transition metal nitrido complexes counter-balanced with iodide ions. There is also a family with rare earth elements and nitrogen and sulfur in a cluster.

Related mixed-anion compounds include halogen variations: nitride fluoride, nitride chloride, and nitride bromide, and pnictogen variations phosphide iodide, arsenide iodide and antimonide iodides.

Production

Nitride iodides may be produced by heating metal nitrides with metal iodides. The ammonolysis process heats a metal iodide with ammonia.[2] A related method heats a metal or metal hydride with ammonium iodide. The nitrogen source could also be an azide or an amide.[2]

List

name formula formula
weight 		crystal
system 		space
group 		unit cell Å volume density comments ref
Li4NCl hexagonal R3 a=366.225 c=1977.18 Z=3 [3]
calcium nitride iodide Ca2NI P63/mmc a = 3.8095, c = 14.530, Z = 2 [4]
α-TiNI orthorhombic Pmmn a=3.941 b=3.51.5 c=8.955 Z=2 black [5]
NCr(I)(NiPr2)2 [6]
Cr(I)(N)(N(C(CD3)2CH3)(C6H3FMe))2 [7]
Zn2NI orthorhombic Pnma a=6.3590 b=6.2529 c=7.9549 <6 GPa [8]
strontium nitride iodide Sr2NI 316.15 trigonal R3m a = 4.0049 c = 23.055 Z=3 320.24 4.918 orange [9]
α-ZrNI orthorhombic Pmmn a=4.114 b=3.724 c=9.431 Z=2 orange [10][5]
β-ZrNI trigonal R3m a=3.718 c=31.381 Z=6 brown [5]
[(pcp)Mo(IV)(N)(I)][Na(15-crown-5)] pcp=C6H3(OPiPr2)2 [11]
Ba2NI
LiLa4N2I7 orthorhombic Pnma a = 13.7417, b = 12.1345, c = 10.7991 Z=4 @100K [12]
NaLa4N2I7 orthorhombic Pna21 a=14.0018 b=10.9315 c=12.1021 Z=4 5.361 colourless air sensitive [13]
Ce15N7I24 4245.6 orthorhombic Pnma a=12.060 b=32.216 c=16.360 Z=4 5.48 red; air sensitive [14]
NaCe4N2I7 orthorhombic Pna21 a=13.9703 b=10.8932 c=12.0194 Z=4 5.446 red air sensitive [13]
NaPr4N2I7 orthorhombic Pna21 a=13.9412 b=10.8578 c=11.9389 Z=4 5.524 yellowish green air sensitive [13]
NaNd4N2I7 orthorhombic Pna21 a=13.9135 b=10.86 c=11.86 Z=4 5.638 pinkish blue air sensitive [13]
(NdI2)3N [15]
(NdI2)3N(DME)4 [16]
NdI(S2N2)(THF) [17]
Nd3I5(S2N2)(S2)(THF)10 2088.72 monoclinic P21 a=12.393 b=43.389 c=12.684 β=90.013 Z=4 6820 2.034 yellow [15]
Ln3I5(S2)(S2N2)(THF)4(Phen)3 [18]
Ln3I5(S2)(S2N2)(THF)3(Py)7 [18]
(SmI)3N2(THF) [16]
ErI(S2N2)(THF) [17]
Nd2ErClI4-(S2)(S2N2)(THF)7 [17]
Nd2ErCl2I3(S2)(S2N2)(THF)7 [17]
(DyI2)3N [19]
Dy3I5(S2)(S2N2)(THF)10 [19]
Nd2DyI5(S2)(S2N2)(THF)7 [17]
Nd2DyI5(S3)(S2N2)(THF)9 2034.88 monoclinic P21/c a=23.1102 b=12.6551 c=23.8268 β =111.201 Z=4 6496.8 2.080 [20]
Nd2TbI5(S2)(S2N2)(THF)9 monoclinic P21/c a =23.1704 b =12.6340 c =23.8340, β =111.274° Z=4 [21]
Nd2TmI5(S2)(S2N2)(THF)9 monoclinic P21/c a =23.075 b =12.6540 c =23.809, β =111.460° Z=4 [21]
Nd2YbI5(S3)(S2N2)(THF)9 monoclinic P21/c a=23.0959 b=12.6632 c=23.8387 β =111.363 Z=4 6493.0 2.092 [20]
α-HfNI orthorhombic Pmmn a=4.10.67 b=3.6944 c=9.382 Z=2 [5][10]
β-HfNI trigonal R3m a=3.689 c=31.329 Z=6 brown [5]
ThNI tetragonal P4/nmm a=4.107 c=9.242 orange to golden grey [5][22]
UNI tetragonal P4/nmm a=3.99 c=9.20 Z=2 [5][23]

References

  1. ↑ Headspith, David A.; Francesconi, M. Grazia (October 2009). "Transition Metal Pnictide-Halides: A Class of Under-Explored Compounds" (in en). Topics in Catalysis 52 (11): 1611–1627. doi:10.1007/s11244-009-9282-5. ISSN 1022-5528. http://link.springer.com/10.1007/s11244-009-9282-5. 
  2. ↑ 2.0 2.1 Schurz, Christian M.; Shlyk, Larysa; Schleid, Thomas; Niewa, Rainer (January 2011). "Superconducting nitride halides MNX (M = Ti, Zr, Hf; X = Cl, Br, I)". Zeitschrift für Kristallographie 226 (4): 395. doi:10.1524/zkri.2011.1350. ISSN 0044-2968. Bibcode: 2011ZK....226..395S. 
  3. ↑ Marx, Rupert (February 1997). "Preparation and Crystal Structure of Lithium Nitride Chloride Li4NCl" (in en). Journal of Solid State Chemistry 128 (2): 241–246. doi:10.1006/jssc.1996.7196. Bibcode: 1997JSSCh.128..241M. https://linkinghub.elsevier.com/retrieve/pii/S0022459696971960. 
  4. ↑ Hadenfeldt, C.; Herdejürgen, H. (February 1987). "Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr" (in de). Zeitschrift für anorganische und allgemeine Chemie 545 (2): 177–183. doi:10.1002/zaac.19875450220. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19875450220. 
  5. ↑ 5.0 5.1 5.2 5.3 5.4 5.5 5.6 Schurz, Christian M.; Shlyk, Larysa; Schleid, Thomas; Niewa, Rainer (January 2011). "Superconducting nitride halides MNX (M = Ti, Zr, Hf; X = Cl, Br, I)". Zeitschrift für Kristallographie 226 (4): 395. doi:10.1524/zkri.2011.1350. ISSN 0044-2968. Bibcode: 2011ZK....226..395S. 
  6. ↑ Odom, Aaron L.; Cummins, Christopher C. (1996-02-06). "A Chromium(VI) Nitrido−Silylmethyl Complex and a Chromium(V) μ-Nitrido Dimer: Synthetic and Structural Details" (in en). Organometallics 15 (3): 898–900. doi:10.1021/om950842k. ISSN 0276-7333. https://pubs.acs.org/doi/10.1021/om950842k. 
  7. ↑ Mindiola, Daniel J.; Cummins, Christopher C. (1998). "Deprotonated 2,3:5,6-Dibenzo-7- aza bicyclo[2.2.1]hepta-2,5-diene as a Nitrido Nitrogen Source by Anthracene Elimination: Synthesis of an Iodide(nitride)chromium(VI) Complex". Angewandte Chemie International Edition 37 (7): 945–947. doi:10.1002/(SICI)1521-3773(19980420)37:7<945::AID-ANIE945>3.0.CO;2-X. PMID 29711483. 
  8. ↑ Li, Xiaofeng; Xue, Lin; Tang, Lijuan; Hu, Ziyu (2015). "Pressure modulates the phase stability and physical properties of zinc nitride iodine" (in en). RSC Advances 5 (96): 78754–78759. doi:10.1039/C5RA14426D. ISSN 2046-2069. Bibcode: 2015RSCAd...578754L. http://xlink.rsc.org/?DOI=C5RA14426D. 
  9. ↑ Bailey, Andrew S.; Gregory, Duncan H.; Hubberstey, Peter; Wilson, Claire (2007-09-15). "Crystal growth and redetermination of strontium nitride iodide, Sr 2 NI". Acta Crystallographica Section E 63 (9): i177. doi:10.1107/S1600536807039797. ISSN 1600-5368. http://scripts.iucr.org/cgi-bin/paper?S1600536807039797. 
  10. ↑ 10.0 10.1 Yamanaka, Shoji; Itoh, Kojiro; Fukuoka, Hiroshi; Yasukawa, Masahiro (2000-02-01). "High-Pressure Synthesis of the Polymorph of Layer Structured Compounds MNX (M = Zr, Hf; X = Cl, Br, I)" (in en). Inorganic Chemistry 39 (4): 806–809. doi:10.1021/ic991058l. ISSN 0020-1669. PMID 11272580. https://pubs.acs.org/doi/10.1021/ic991058l. 
  11. ↑ Song, Jinyi; Liao, Qian; Hong, Xin; Jin, Li; Mézailles, Nicolas (2021-05-25). "Conversion of Dinitrogen into Nitrile: Cross‐Metathesis of N 2 ‐Derived Molybdenum Nitride with Alkynes" (in en). Angewandte Chemie International Edition 60 (22): 12242–12247. doi:10.1002/anie.202015183. ISSN 1433-7851. PMID 33608987. https://onlinelibrary.wiley.com/doi/10.1002/anie.202015183. 
  12. ↑ Schurz, Christian M.; Niewa, Rainer; Schleid, Thomas (January 2020). "LiLa4N2I7 as the first lithium-containing nitride halide of the lanthanides: Synthesis, crystal structure and spectroscopic characterization" (in en). Solid State Sciences 99: 106047. doi:10.1016/j.solidstatesciences.2019.106047. Bibcode: 2020SSSci..9906047S. https://linkinghub.elsevier.com/retrieve/pii/S1293255819308039. 
  13. ↑ 13.0 13.1 13.2 13.3 Schurz, Christian M.; Schleid, Thomas (October 2010). "The first quaternary lanthanide(III) nitride iodides: NaM4N2I7 (M=La–Nd)" (in en). Journal of Solid State Chemistry 183 (10): 2253–2260. doi:10.1016/j.jssc.2010.07.025. Bibcode: 2010JSSCh.183.2253S. https://linkinghub.elsevier.com/retrieve/pii/S0022459610003075. 
  14. ↑ Mattausch, Hansj Ürgen; Kremer, Reinhard K.; Simon, Arndt (April 1996). "Synthese, Kristallstruktur und magnetische Eigenschaften von Ce15N7I24" (in de). Zeitschrift für anorganische und allgemeine Chemie 622 (4): 649–654. doi:10.1002/zaac.19966220413. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19966220413. 
  15. ↑ 15.0 15.1 Fagin, A. A.; Fukin, G. K.; Cherkasov, A. V.; Shestakov, A. F.; Pushkarev, A. P.; Balashova, T. V.; Maleev, A. A.; Bochkarev, M. N. (2016). "Ln 3 I 5 (S 2 N 2 )(S 2 )(THF) 10 – a new type of molecular compounds" (in en). Dalton Transactions 45 (11): 4558–4562. doi:10.1039/C5DT04742K. ISSN 1477-9226. PMID 26842841. http://xlink.rsc.org/?DOI=C5DT04742K. 
  16. ↑ 16.0 16.1 Kuzyaev, Dmitry M.; Maleev, Alexander A.; Kulikova, Tatyana I.; Vorozhtsov, Dmitry L.; Bochkarev, Mikhail N. (February 2017). "Reactivity of Neodymium and Samarium Nitrides" (in en). Journal of Chemical Research 41 (2): 82–84. doi:10.3184/174751917X14839766277332. ISSN 1747-5198. http://journals.sagepub.com/doi/10.3184/174751917X14839766277332. 
  17. ↑ 17.0 17.1 17.2 17.3 17.4 Fagin, A. A.; Kuznetsova, O. V.; Rumyantsev, R. V.; Baranov, E. V.; Fukin, G. K.; Bochkarev, M. N. (March 2022). "Lanthanide Iodide Nitride Sulfide Clusters" (in en). Russian Journal of Coordination Chemistry 48 (3): 146–152. doi:10.1134/S1070328422020026. ISSN 1070-3284. https://link.springer.com/10.1134/S1070328422020026. 
  18. ↑ 18.0 18.1 Fagin, A. A.; Kuzyaev, D. M.; Burin, M. A.; Kuznetsova, O. V.; Khamaletdinova, N. M.; Kulikova, T. I.; Shestakov, A. F.; Lopatina, T. I. et al. (February 2018). "On the Reactivity and Stability of Iodide–Nitride–Sulfide Clusters of Neodymium and Dysprosium" (in en). Russian Journal of Coordination Chemistry 44 (2): 127–131. doi:10.1134/S1070328418020045. ISSN 1070-3284. http://link.springer.com/10.1134/S1070328418020045. 
  19. ↑ 19.0 19.1 Fagin, A.A.; Kuznetsova, O.V.; Balashova, T.V.; Cherkasov, A.V.; Fukin, G.K.; Bochkarev, M.N. (January 2018). "Iodide-sulfides of dysprosium: Elucidation of the pathway to lanthanide iodide-sulfide-nitride clusters" (in en). Inorganica Chimica Acta 469: 227–230. doi:10.1016/j.ica.2017.09.030. https://linkinghub.elsevier.com/retrieve/pii/S0020169317307818. 
  20. ↑ 20.0 20.1 Fagin, A. A.; Kuznetsova, O. V.; Rumyantcev, R. V.; Fukin, G. K.; Marugin, A. V.; Bochkarev, M. N. (September 2019). "Neodymium–Dysprosium and Neodymium–Ytterbium Iodide–Sulfide–Nitride Clusters: Synthesis and Luminescence" (in en). Journal of Cluster Science 30 (5): 1277–1281. doi:10.1007/s10876-019-01552-5. ISSN 1040-7278. http://link.springer.com/10.1007/s10876-019-01552-5. 
  21. ↑ 21.0 21.1 Fagin, A.A.; Kuzyaev, D.M.; Maleev, A.A.; Baranov, E.V.; Rumyantcev, R.V.; Fukin, G.K.; Shestakov, A.F.; Suchkov, A.I. et al. (May 2019). "Heterolanthanide three-nuclear iodide-sulfide-nitride clusters. Unusual synthesis way and structure" (in en). Inorganica Chimica Acta 490: 200–203. doi:10.1016/j.ica.2019.03.021. https://linkinghub.elsevier.com/retrieve/pii/S0020169318315640. 
  22. ↑ Juza, Robert; Sievers, Rolf (December 1968). "Nitridhalogenide des Thoriums" (in de). Zeitschrift für anorganische und allgemeine Chemie 363 (5–6): 258–272. doi:10.1002/zaac.19683630505. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19683630505. 
  23. ↑ Juza, R.; Meyer, W. (April 1969). "Über Uran-Nitrid-Chlorid, -Bromid und -Jodid" (in de). Zeitschrift für anorganische und allgemeine Chemie 366 (1–2): 43–50. doi:10.1002/zaac.19693660105. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19693660105. 
HI He
LiI BeI2 BI3 CI4 NI3 I2O4,
I2O5,
I4O9 		IF,
IF3,
IF5,
IF7 		Ne
NaI MgI2 AlI3 SiI4 PI3,
P2I4 		S ICl,
ICl3 		Ar
KI CaI2 Sc TiI4 VI3 CrI3 MnI2 FeI2 CoI2 NiI2 CuI ZnI2 Ga2I6 GeI2,
GeI4 		AsI3 Se IBr Kr
RbI SrI2 YI3 ZrI4 NbI5 Mo Tc Ru Rh Pd AgI CdI2 InI3 SnI4,
SnI2 		SbI3 TeI4 I Xe
CsI BaI2   HfI4 TaI5 W Re Os Ir Pt AuI Hg2I2,
HgI2 		TlI PbI2 BiI3 Po AtI Rn
Fr RaI2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La Ce Pr Nd Pm SmI2 Eu Gd TbI3 Dy Ho Er Tm Yb Lu
Ac ThI4 Pa UI3,
UI4 		Np Pu Am Cm Bk Cf EsI3 Fm Md No Lr
Salts and covalent derivatives of the nitride ion
NH3 He(N2)11
Li3N Be3N2 BN β-C3N4
g-C3N4 		N2 NxOy NF3 Ne
Na3N Mg3N2 AlN Si3N4 PN
P3N5 		SxNy
SN
S4N4 		NCl3 Ar
K3N Ca3N2 ScN TiN VN CrN
Cr2N 		MnxNy FexNy CoN Ni3N CuN Zn3N2 GaN Ge3N4 As Se NBr3 Kr
Rb3N Sr3N2 YN ZrN NbN β-Mo2N Tc Ru Rh PdN Ag3N CdN InN Sn Sb Te NI3 Xe
Cs3N Ba3N2   Hf3N4 TaN WN Re Os Ir Pt Au Hg3N2 TlN Pb BiN Po At Rn
Fr3N Ra3N   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La CeN Pr Nd Pm Sm Eu GdN Tb Dy Ho Er Tm Yb Lu
Ac Th Pa UN Np Pu Am Cm Bk Cf Es Fm Md No Lr



Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Nitride_iodide&oldid=3336046"