Chemistry:Sulfate fluoride

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Short description: Class of chemical compounds

The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.

Fluoride sulfates were first discovered by Jean Charles de Marignac in 1859.[1][2]

Some elements such as cobalt or uranium can form complexes that contain fluoride and sulfate groups, and would be referred to as fluoro and sulfato metallates.

List

Minerals

name formula ratio system space group unit cell Å volume density optical references
Chukhrovite-(Ca) Ca4.5Al2(SO4)F13·12H2O 1:13 Isometric Fd3 a = 16.749 Z=8 4698.6 2.23 isotropic n = 1.432 [3]
Chukhrovite-(Ce) Ca3(Y,Ce)(AlF6)2(SO4)F · 10H2O 1:13 Isometric Fd3 [4]
Chukhrovite-(Y) Ca3(Ce,Y)(AlF6)2(SO4)F · 10H2O 1:13 Isometric Fd3 [5]
Chukhrovite-(Nd) Ca3(Nd,Y)Al2(SO4)F13·12H2O 1:13 Isometric Fd3 a = 16.759 Z=8 4,707.0 2.42 isotropic nα = 1.443 [6]
Meniaylovite Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O 1:13 Isometric Fd3 a = 16.722 Z=8 4,675.89 Isotropic n = 1.43
Pseudograndreefite Pb6(SO4)F10 1:10 Orthorhombic F2 2 2 a = 8.51 b = 19.57 c = 8.49 Z=4 1,413.93 Biaxial (+) nα = 1.864 nβ = 1.865 nγ = 1.873

2V: measured: 30° , calculated: 40°

Max birefringence: δ = 0.009

[7]
Creedite Ca3SO4Al2F8(OH)2 · 2H2O 1:8 Monoclinic B2/b a = 13.936, b = 8.606, c = 9.985 β = 94.39° Z=4 1,194.02 2.713 Biaxial (-) nα = 1.461 nβ = 1.478 nγ = 1.485

Max birefringence: δ = 0.024

[8]
Thermessaite K2AlF3(SO4) 1:3 Orthorhombic Pbcn a = 10.81 b = 8.336 c = 6.822 614.75 2.77
Grandreefite Pb2(SO4)F2 1:2 monoclinic A2/a a = 8.667 b = 4.4419 c = 14.242 β = 107.418 Z=4 523.15 7.15 Biaxial (+) nα = 1.872 nβ = 1.873 nγ = 1.897

2V: Measured: 23°

Max Birefringence: δ = 0.025

[9]
Arangasite Al2F(PO4)(SO4) · 9H2O 1:1 monoclinic P2/a a = 7.073 b = 9.634 c = 10.827 β = 100.40 Z = 2 725.7 2.01 Biaxial (+) ?nα = 1.493(5) nγ = 1.485(5)

Max birefringence: δ = 0.008

[10][11]
Khademite Al(SO4)F · 5H2O 1:1 orthorhombic a = 11.17 b = 13.05 c = 10.88 1,585.96 1.925 Biaxial (-) nα = 1.440 nβ = 1.460 nγ = 1.487

2V: measured: 68° calculated: 84°

Max birefringence δ = 0.047

colourless

[12]
Kogarkoite Na3(SO4)F 1:1 Monoclinic ?P21 a = 18.07 b = 6.94 c = 11.44 β = 107.72° Z=12 1,366.58 2.676 Biaxial (+) nα = 1.439 nβ = 1.439 nγ = 1.442

Max Birefringence: δ = 0.003

[13]
kononovite NaMg(SO4)F 1:1 monoclinic C2/c a = 6.662 b = 8.584 c = 7.035 β = 114.06 Z=4 367.4 2.91 biaxial (+), nα = 1.488 nβ = 1.491 nγ = 1.496 2Vmeas = 75°

Max birefringence: δ = 0.008

[14]
Lannonite Mg2Ca4Al4(SO4)8F8 · 24H2O 8:8 Tetragonal I4/m a = 6.860 c = 28.053 1,320.16 2.22 Uniaxial (+) nω = 1.460 nε = 1.478

Max Birefringence:δ = 0.018

[15]
Sulphohalite Na6(SO4)2FCl 2:1 Isometric Fm3m Isotropic [16]
Uklonskovite NaMgSO4F•2H2O 1:1 monoclinic a = 7.2 Å, b = 7.21 Å, c = 5.73 β = 113.23° 273.34 Biaxial (+) nα = 1.476 nγ = 1.500

Max Birefringence δ = 0.024

[17]
Vlodavetsite AlCa2(SO4)2F2Cl · 4H2O 2:2 Tetragonal I4/m a = 6.870, c = 13.342 Z=2 629.70 Uniaxial (+) nω = 1.509 nε = 1.526

Max birefringence: δ = 0.017

[18]
Schairerite Na21(SO4)7ClF6 7:6 trigonal 3_2/m a = 12.17 c = 19.29 2,474.25 2.67 Uniaxial (+) nω = 1.440 nε = 1.445

Max birefringence: δ = 0.005

[19]
Galeite Na15(SO4)5F4Cl 5:4 Trigonal a = 12.17 c = 13.94 1,788.03 Uniaxial (+) nω = 1.447 nε = 1.449

Max Birefringence: δ = 0.002

[20]
Fluorellestadite Ca10(SiO4)3(SO4)3F2 3:2 hexagonal a = 9.53 c = 6.91 543.49 3.03 Uniaxial (-) nω = 1.655 nε = 1.650

Max birefringence:δ = 0.005

[21]
Straßmannite Al(UO2)(SO4)2F·16H2O 2:1 monoclinic C2/c a = 11.0187 b = 8.3284 c = 26.673 β = 97.426° 2427.2 2.20 pale yellowish green

Biaxial (-) nα = 1.477(2) nβ = 1.485(2) nγ = 1.489(2)

2V: measured: 70° calculated: 70.2°

Max birefringence: δ = 0.012

[22]
Svyazhinite (Mg,Mn2+,Ca)(Al,Fe3+)(SO4)2F · 14H2O 2:1 triclinic a = 6.21 b = 13.3 c = 6.25 α = 90.15°, β = 93.56°, γ = 82.08° 510.29 Biaxial (-) nα = 1.423 nβ = 1.439 nγ = 1.444

2V: calculated: 56°

Max birefringence: δ = 0.021

[23]
Wilcoxite MgAl(SO4)2F · 17H2O 2:1 triclinic P1 a = 6.644, b = 6.749, c = 14.892 α = 79.664°, β = 80.113°, γ = 62.487 579.6 1.58 Biaxial (-) nα = 1.424 nβ = 1.436 nγ = 1.438

2V: measured: 48° , calculated: 44°

Max birefringence: δ = 0.014

[24]
Krasheninnikovite KNa2CaMg(SO4)3F 3:1 hexagonal P63/mcm a = 16.6682 c = 6.9007 Z = 6 1660.36 2.68 Uniaxial (-) nω = 1.500 nε = 1.492

Max birefringence: δ = 0.008

[25]
Shuvalovite K2(Ca2Na)(SO4)3F 3:1 orthorhombic Pnma a = 13.2383 b = 10.3023 c = 8.9909 Z = 4 1226.22 2.64 biaxial (−), nα = 1.493 nβ = 1.498 nγ = 1.498 2Vmeasured ≤ 20 [26]

Artificial

name formula MW ratio system space group unit cell volume density optical CAS references
LiMgFSO4 1:1 triclinic P1 a = 5.1623 b = 5.388 c = 7.073 α = 106.68 β=107.40 and γ=97.50° Z=2 [27]
NaMgSO4F 1:1 monoclinic C2/c Z=4 109.802 2.84 [28]
Na4TiF4(SO4)2 2:4 [29]
β-K3[SO4]F 1:1 tetragonal I4/mcm a= 7.2961 c= 10.854 [30]
α-K3[SO4]F 1:1 cubic Pm3m a≈5.43 ≥585 °C [30]
KMgSO4F 178.47 1:1 orthorhombic Pna21 a=12.973 b=6.4585 c=10.635 Z=8 891.1 2.661 colourless [31][32]
sodium calcium sulfapatite Na6Ca4(SO4)6F2 6:2
K3Ca2(SO4)3F 3:1 orthorhombic Pn21a a=13.467 b=10.521 c=9.167 Z=4 1299.9 [33]
[N2C10H12] TiF4SO4 378.16? 1:4 triclinic P1 a=8.691 b=9.208 c=9.288 α=68.56 β=84.30 γ=81.59 Z=2               683.6 1.837 colourless [29]
[N2C10H12]TiF2(SO4)2 436.22? 2:2 triclinic P1 a=4.5768 b=8.9162 c=10.1236 α=112.888 β=95.196 γ=98.706 Z=1               371.11 1.952 colourless [29]
Rb2TiF2(SO4)2 · 2H2O 1:1 [34]
Cs2TiF2(SO4)2 · 3H2O 1:1 [34]
[N2C6H16]V(SO4)2F 378.27 2:1 monoclinic P21/c a=10.262 b =17.761 c=7.0518 β=93.93 Z=4                  1282.3 1.959 green [29]
Na2VF3SO4 1:3 [29]
Na3CrF2(SO4)2 2:2 [29]
LiMnSO4F 1:1 monoclinic a=13.2406 b=6.4082 c=10.0229 β=120.499 732.76 [35]
[N2C6H16]2+Mn2F2(SO4)2 2:2 [29]
Li2MnF3(SO4) 1:3 pink-brown [36]
(NH4)2MnF3(SO4) 1:3 pink-brown [36]
Na2MnF3(SO4) 1:3 pink-brown [36]
Dipotassium trifluorosulfato manganate(III) K2MnF3(SO4) 1:3 pink-brown [36]
FeFSO4 170.91 1:1 monoclinic C2/c a = 7.3037 b = 7.0753 c = 7.3117 β = 119.758° 328.017 3.461 [37]
K2FeF3SO4 1:3 [29]
Li3FeF2(SO4)2·H2O 2:2 [29]
[N2C6H16]Fe(SO4)2F 383.18 2:1 monoclinic P21/c a=10.2220 b=17.6599 c=7.0437 β=93.894 Z=4 1268.59 2.006 brown [29]
LiFeFSO4 177.85 1:1 triclinic P1 a = 5.1751 b = 5.4915 c = 7.2211 α = 106.506° β = 107.178° γ=97.865° 182.44 3.237 grass green [37]
sodium ferrous sulfate fluoride NaFeFSO4 193.91 1:1 monoclinic P21/c a = 6.6739 b = 8.6989 c = 7.1869 β = 113.525° 382.567 3.366 [37]
sodium ferrous sulfate fluoride dihydrate NaFeFSO4·2H2O 1:1 monoclinic P21/m a=5.75959 b=7.38273 c=7.25047 β=113.3225 283.109 white [38]
trisodium ferric disulfate difluoride Na3Fe(SO4)2F2 2:2 orthorhombic Pnca a = 6.6419 b = 8.8115 c = 14.0023 [39]
NaCoFSO4 1:1 monoclinic C2/c a=6.6687 b=8.6251 c=7.1444 β=114.323 374.46 [40]
NaCoFSO4·2H2O 1:1 monoclinic P21/m a=5.73364 b=7.31498 c=7.18640 β=113.5028 276.40 pink [38]
NH4CoFSO4·2H2O 1:1 [41]
KCoFSO4·2H2O 1:1 [41]
NaNiFSO4·2H2O 1:1 monoclinic P21/m a=5.70118 b=7.27603 c=7.15634 β=113.8883 271.429 green [38]
LiZnSO4F 1:1 orthorhombic Pnma 7.40357 b=6.32995 c=7.42016 347.740 [42]
KZnSO4F 219.53 1:1 orthorhombic Pna21 a=13.0602 b=6.4913 c=10.7106 Z=8 908.02 3.212 transparent <190 nm [32]
K2Zn3(SO4)(HSO4)2F4 1:4 orthorhombic Cmc21 a=17.725 b=7.6650 c=9.7505 Z=4 1324.7 3.212 colourless [43]
Y(SO4)F 203.97 1:1 orthorhombic Pnma a=8.3128, b=6.9255, c=6.3905 Z=4 367.90 3.682 [44]
YSO4F·H2O 1:1 monoclinic P21/n a=4.9707 b=7.306 c=11.493 β =96.95° birefringence 0.0357 at 546 nm [45]
Y2Cu(OH)3(SO4)2F·H2O 521.52 2:1 monoclinic P21/n a=11.6889, b=6.8660, c=12.5280, β=97.092° Z=4 997.8 3.472 blue [44]
Zr2O2F2SO4 · 6H2O 1:2 [46]
α-K3ZrF5SO4 · H2O 1:5 [34]
K2ZrF4SO4 1:4 [34]
K2ZrF2(SO4)2 · 2.5H2O 2:2 [34]
K3Zr2F9SO4 · 2H2O 1:9 [34]
(NH4)3Zr2F9SO4 · 2H2O 1:9 [34]
(NH4)2ZrF4SO4 1:4 [34]
(NH4)2ZrF2(SO4)2 · 2.5H2O 2:2 [34]
Rb2ZrF4SO4 1:4 [34]
Rb2ZrF2(SO4)2 · 3H2O 2:2 [34]
Rb3Zr2F9SO4 ·2H2O 1:9 [34]
RbZr2O2F(SO4)2 · 5H2O 2:1 [34]
Cs2ZrF4SO4 1:4 [34]
Cs2ZrF2(SO4)2 · 2H2O 2:2 [34]
Cs8Zr4F2(SO4)11 · 16H2O 11:2 [34]
CsZr2O2F(SO4)2 · 6H2O 2:1 [34]
Zr2O2F2SO4 · 5H2O 1:2 [34]
triindium trifluoride sulfate ditellurite hydrate In3(SO4)(TeO3)2F3(H2O) 866.74 1:3 orthorhombic P212121 a=8.3115 b=9.4341 c=14.8068 1161.0 4.959 band gap 4.10 eV; white [47]
4,4'-bipyridine distannous difluoride disulfate (C10H10N2)0.5[SnF(SO4)] 2:2 triclinic P1 a=4.726 b=7.935 c=11.203 α = 81.05° β = 87.59° γ=73.70° Z=2 398.3 2.608 colourless [48]
diantimony dipotassium hexafluoride sulfate K2SO4·(SbF3)2 531.76 1:6 monoclinic P21/c a=9.1962 b=5.6523 c=19.2354 β =103.209 Z=4 973.40 3.629 colourless [49]
diantimony dirubidium hexafluoride sulfate Rb2SO4·(SbF3)2 624.50 1:6 monoclinic P21 a=9.405 b=5.7210 c=9.879 β = 103.850 Z=2 516.1 4.018 colourless [49]
tetraantimony hexarubidium dodecafluoride trisulfate Rb6Sb4F12(SO4)3 1515.989 3:12 trigonal P3 a=16.9490 c=7.5405 Z=2 1875.94 4.026 white 53168-89-1 [50][51]
hexaammonium dodecafluorotrisulfatotetraantimonate(III) [NH4]6Sb4F12(SO4)3 3:12 trigonal P3 a=17.07 c=7.515 Z=3 1896 2.92 [52]
hexarubidium dodecafluorotrisulfatotetraantimonate(III) Rb6Sb4F12(SO4)3 3:12 [52]
tetraantimony hexacaesium dodecafluoride trisulfate Cs6Sb4F12(SO4)3 1800.601 3:12 triclinic P1 a=7.9044 b=10.5139 c=17.3534 al=90.350 β = 90.151 ga=104.797 Z=4 1394.3 4.289 white 53200-54-7 [50][53]
antimony caesium difluoride sulfate CsSbF2SO4 388.72 1:2 orthorhombic Pna21 a=9.9759 b=11.6616 c=5.2968 515.20 4.19 clear, non-linear SH [54]
LiLa2F3(SO4)2 2:3 monoclinic I2/a a = 8.283, b = 6.947, c = 14.209 β = 95.30° Z=4 [55]
CeF2(SO4) 1:2 orthorhombic Pca21 a=8.3668 b=6.3600 c=8.3862 birefringence 0.361@ 546 nm; SHG 8×KDP [56]
NdFSO4·H2O 277.32 1:1 monoclinic P21/n a = 4.9948 b = 7.3684 c = 11.6366 β = 96.672° Z=4 425.37 4.330 pink [57]
NaPr2F3(SO4)2 2:3 monoclinic I2/a a = 8.223, b = 6.9212, c = 14.199, β = 95.88° Z=4 light green [58]
LiEr2F3(SO4)2 2:3 orthorhombic Pbcn a = 14.791, b = 6.336, c = 8.137 [55]
hexa(triethylenetriammonium) tetrasamarium tetradecasulfate difluoride [C4H16N3]6[Sm4F2(SO4)14] 2621.43 14:2 triclinic P1 a = 11.1988 b = 11.4073 c = 16.2666 α = 89.901°, β = 82.406°, γ = 67.757° Z=1 1903.9 2.286 colourless [57]
TbFSO4·H2O 292.00 1:1 monoclinic P21/n a = 5.0014 b = 7.377 c = 11.651 β = 96.692° Z=4 426.9 4.543 colourless [57]
gadolinium fluoride sulfate GdF[SO4] 1:1 orthorhombic Pnma a=8.436 b=7.0176 c=6.4338 Z=4 [59]
γ-K2HfF2(SO4)2 · 2H2O 2:2 [34]
K2HfF2(SO4)2 · 2.5H2O 2:2 [34]
Na6Pb4(SO4)6F2 6:2 [60]
ThSO4F2.H2O 1:2 monoclinic P21n a = 6.9065 b = 6.9256 c = 10.589 β = 96.755° Z = 4 502.98 colourless [61]
potassium catena-di—fluoro-difluorotetraoxo-di—sulphato-diuranate(VI) hydrate K2UF2O2(SO4)·H2O 1:2 monoclinic P21/c a = 9.263 b = 8.672 c = 11.019 β= 101.60° Z = 4 867.1 3.83 greenish yellow [62][63]
(NH4)2[UO2F2(SO4)] triclinic P1 a=9.73 b=10.28 c=11.37 α = 107.4°, β = 111.9°, γ =106.9 Z=2 greenish yellow [63]
(NH4)6[(UO2)2F4(SO4)3] triclinic P1 a=9.35 b=9.85 c=11.25 α = 109.2°, β = 113.1°, γ =102.5 Z=1 greenish yellow [63]
Cs2[(UO2)2F4(SO4)] greenish yellow [63]
(NH4)[UO2F(SO4)] triclinic P1 a=8.99 b=7.12 c=7.42 α = 114.5°, β = 117.4°, γ =103.2 Z=1 1.92 greenish yellow [63]
RbUO2SO4F orthorhombic Pca21 a=25.353 b=6.735 c=11.496 Z=12 [64][65]
[N2C6H16][UO2F2(SO4)] 520.29 1:2 triclinic P1 a=6.9105 b=9.6605 =10.1033 α=72.6594(14) β=87.068 γ=77.9568 Z=2 629.62 2.744 yellow [66]
[N2C6H16][UO2F(SO4)]2 884.37 2:2 orthorhombic Pmmn a=6.9503 b=17.2147 c=7.0867 Z=2 847.90 3.464 yellow [66]
[N2C3H12][UO2F(SO4)]2·H2O 862.32 2:2 orthorhombic Pnma a=13.5775 b=14.6180 c=8.1168 Z=4 1610.99 3.555 yellow [66]
[N2C5H14][UO2F(H2O)(SO4)]2 907.38 2:2 monoclinic P121/n1 a=8.4354 b=15.5581 c=14.8442 β =96.666 Z=4 1935.0 3.115 yellow [66]
[N2C6H18]2[UO2F(SO4)]4·H2O 1792.80 4:4 triclinic P1 a=10.8832 b=10.9386 c=16.5325 α=75.6604 β=73.6101 γ=89.7726 Z=2 1824.73 3.263 yellow [66]
[N2C3H12][UO2F(SO4)]2·H2O 864.34 2:2 monoclinic P121/n1 a=6.7745 b=8.1589 c=14.3661 β =94.556 Z=2 791.54 3.626 yellow [66]
diammonium hydrazinium triuranium(IV) tetrafluoride hexasulfate U4+3F4(SO4)6·2NH4·H3N-NH3 1436.6 6:4 monoclinic C2/c a=15.2309 b=8.77998 c=18.8590 β=105.5030 Z=4 2432.69 4.392 green [67]

References

  1. ↑ Avdontceva, Margarita S.; Zolotarev, Andrey A.; Krivovichev, Sergey V. (November 2015). "Order–disorder phase transition in the antiperovskite-type structure of synthetic kogarkoite, Na3SO4F". Journal of Solid State Chemistry 231: 42–46. doi:10.1016/j.jssc.2015.07.033. Bibcode: 2015JSSCh.231...42A. 
  2. ↑ de Marignac, Jean Charles (1859). Recherches sur les formes cristallines et la composition chimique de divers sels. p. 221. https://gallica.bnf.fr/ark:/12148/bpt6k90442v/f681. 
  3. ↑ "Chukhrovite-(Ca): Mineral information, data and localities.". https://www.mindat.org/min-41907.html. 
  4. ↑ "Chukhrovite-(Ce): Mineral information, data and localities.". https://www.mindat.org/min-1044.html. 
  5. ↑ "Chukhrovite-(Y): Mineral information, data and localities.". https://www.mindat.org/min-1045.html. 
  6. ↑ "Chukhrovite-(Nd): Mineral information, data and localities.". https://www.mindat.org/min-27474.html. 
  7. ↑ "Pseudograndreefite: Mineral information, data and localities.". https://www.mindat.org/min-3298.html. 
  8. ↑ "Creedite: Mineral information, data and localities.". https://www.mindat.org/min-1151.html. 
  9. ↑ "Grandreefite: Mineral information, data and localities.". https://www.mindat.org/min-1738.html. 
  10. ↑ Yakubovich, O. V.; Steele, I. M.; Chernyshev, V. V.; Zayakina, N. V.; Gamyanin, G. N.; Karimova, O. V. (August 2014). "The crystal structure of arangasite, Al 2 F(PO 4 )(SO 4 )·9H 2 O determined using low-temperature synchrotron data" (in en). Mineralogical Magazine 78 (4): 889–903. doi:10.1180/minmag.2014.078.4.09. ISSN 0026-461X. Bibcode: 2014MinM...78..889Y. https://www.cambridge.org/core/product/identifier/S0026461X00003571/type/journal_article. 
  11. ↑ "Arangasite: Mineral information, data and localities.". https://www.mindat.org/min-43332.html. 
  12. ↑ "Khademite: Mineral information, data and localities.". https://www.mindat.org/min-2193.html. 
  13. ↑ "Kogarkoite: Mineral information, data and localities.". https://www.mindat.org/min-2236.html. 
  14. ↑ Pekov, Igor V.; Krzhizhanovskaya, Maria G.; Yapaskurt, Vasiliy O.; Belakovskiy, Dmitry I.; Chukanov, Nikita V.; Lykova, Inna S.; Sidorov, Evgeny G. (2015-07-27). "Kononovite, NaMg(SO4)F, a new mineral from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia" (in en). European Journal of Mineralogy 27 (4): 575–580. doi:10.1127/ejm/2015/0027-2457. ISSN 0935-1221. Bibcode: 2015EJMin..27..575P. http://www.schweizerbart.de/papers/ejm/detail/27/84951/Kononovite_NaMg_SO4_F_a_new_mineral_from_the_Arsen?af=crossref. 
  15. ↑ "Lannonite: Mineral information, data and localities.". https://www.mindat.org/min-2323.html. 
  16. ↑ "Sulphohalite: Mineral information, data and localities.". https://www.mindat.org/min-3824.html. 
  17. ↑ "Uklonskovite: Mineral information, data and localities.". https://www.mindat.org/min-4084.html. 
  18. ↑ "Vlodavetsite: Mineral information, data and localities.". https://www.mindat.org/min-7357.html. 
  19. ↑ "Schairerite: Mineral information, data and localities.". https://www.mindat.org/min-3555.html. 
  20. ↑ "Galeite: Mineral information, data and localities.". https://www.mindat.org/min-1640.html. 
  21. ↑ "Fluorellestadite: Mineral information, data and localities.". https://www.mindat.org/min-1575.html. 
  22. ↑ "Straßmannite: Mineral information, data and localities.". https://www.mindat.org/min-52751.html. 
  23. ↑ "Svyazhinite: Mineral information, data and localities.". https://www.mindat.org/min-3841.html. 
  24. ↑ "Wilcoxite: Mineral information, data and localities.". https://www.mindat.org/min-4288.html. 
  25. ↑ Pekov, I. V.; Zelenski, M. E.; Zubkova, N. V.; Ksenofontov, D. A.; Kabalov, Y. K.; Chukanov, N. V.; Yapaskurt, V. O.; Zadov, A. E. et al. (2012-10-01). "Krasheninnikovite, KNa2CaMg(SO4)3F, a new mineral from the Tolbachik volcano, Kamchatka, Russia" (in en). American Mineralogist 97 (10): 1788–1795. doi:10.2138/am.2012.4104. ISSN 0003-004X. Bibcode: 2012AmMin..97.1788P. https://pubs.geoscienceworld.org/ammin/article/97/10/1788-1795/45567. 
  26. ↑ Pekov, Igor V.; Zubkova, Natalia V.; Britvin, Sergey N.; Chukanov, Nikita V.; Yapaskurt, Vasiliy O.; Sidorov, Evgeny G.; Pushcharovsky, Dmitry Y. (2016-03-23). "Shuvalovite, K2(Ca2Na)(SO4)3F, a new mineral from the Tolbachik volcano, Kamchatka, Russia" (in en). European Journal of Mineralogy 28 (1): 53–62. doi:10.1127/ejm/2015/0027-2471. ISSN 0935-1221. Bibcode: 2016EJMin..28...53P. http://www.schweizerbart.de/papers/ejm/detail/28/85612/Shuvalovite_K2_Ca2Na_SO4_3F_a_new_mineral_from_the?af=crossref. 
  27. ↑ Sebastian, Litty; Gopalakrishnan, Jagannatha; Piffard, Yves (2002-01-24). "Synthesis, crystal structure and lithium ion conductivity of LiMgFSO4". Journal of Materials Chemistry 12 (2): 374–377. doi:10.1039/b108289m. http://xlink.rsc.org/?DOI=b108289m. 
  28. ↑ Persson, Kristin (2016) (in en), Materials Data on NaMgSO4F (SG:15) by Materials Project, LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States), doi:10.17188/1310136, http://www.osti.gov/servlets/purl/1310136/, retrieved 2020-06-15 
  29. ↑ 29.0 29.1 29.2 29.3 29.4 29.5 29.6 29.7 29.8 29.9 Marshall, Kayleigh L.; Wang, Qianlong; Sullivan, Hannah S. I.; Weller, Mark T. (2016). "Synthesis and structural characterisation of transition metal fluoride sulfates" (in en). Dalton Transactions 45 (21): 8854–8861. doi:10.1039/C6DT00582A. ISSN 1477-9226. PMID 27151299. http://xlink.rsc.org/?DOI=C6DT00582A. 
  30. ↑ 30.0 30.1 Skakle, Janet M. S.; Fletcher, James G.; West, Anthony R. (1996). "Polymorphism, structures and phase transformation of K3[SO4F"] (in en). Journal of the Chemical Society, Dalton Transactions (12): 2497–2501. doi:10.1039/dt9960002497. ISSN 0300-9246. http://xlink.rsc.org/?DOI=dt9960002497. 
  31. ↑ Poddar, Anuradha; Gedam, S.C.; Dhoble, S.J. (November 2013). "Photoluminescence study of KMgSO4F:X (X=Cu+ or Dy3+ or Eu3+) halosulfate phosphor" (in en). Journal of Luminescence 143: 579–582. doi:10.1016/j.jlumin.2013.06.010. Bibcode: 2013JLum..143..579P. 
  32. ↑ 32.0 32.1 Zhou, Yang; Liu, Xiaomeng; Lin, Zheshuai; Li, Yanqiang; Ding, Qingran; Liu, Youchao; Chen, Yangxin; Zhao, Sangen et al. (2021-12-20). "Pushing KTiOPO 4 -like Nonlinear Optical Sulfates into the Deep-Ultraviolet Spectral Region" (in en). Inorganic Chemistry 60 (24): 18950–18956. doi:10.1021/acs.inorgchem.1c02764. ISSN 0020-1669. PMID 34881864. https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c02764. 
  33. ↑ Triviño Vázquez, F. (July 1985). "A new compound: K3Ca2 (SO4)3F, identified in coatings of heat recover cyclones" (in en). Cement and Concrete Research 15 (4): 581–584. doi:10.1016/0008-8846(85)90055-9. 
  34. ↑ 34.00 34.01 34.02 34.03 34.04 34.05 34.06 34.07 34.08 34.09 34.10 34.11 34.12 34.13 34.14 34.15 34.16 34.17 34.18 34.19 Boroznovskaya, N. N.; Godneva, M. M.; Motov, D. L.; Klimkin, V. M. (April 2007). "Synthesis and luminescent properties of alkali-metal and ammonium fluorosulfatozirconates and fluorosulfatohafnates" (in en). Inorganic Materials 43 (4): 425–429. doi:10.1134/S0020168507040176. ISSN 0020-1685. 
  35. ↑ Tripathi, Rajesh; Popov, Guerman; Ellis, Brian L.; Huq, Ashfia; Nazar, L. F. (2012). "Lithium metal fluorosulfate polymorphs as positive electrodes for Li-ion batteries: synthetic strategies and effect of cation ordering" (in en). Energy & Environmental Science 5 (3): 6238. doi:10.1039/c2ee03222h. ISSN 1754-5692. http://xlink.rsc.org/?DOI=c2ee03222h. 
  36. ↑ 36.0 36.1 36.2 36.3 Bhattacharjee, M.N.; Chaudhuri, M.K. (January 1984). "Alkali-metal trifluoromonosulphatomanganates (III) A2[MnF3(SO4)] (A = NH4, Li, Na or K)" (in en). Polyhedron 3 (5): 599–602. doi:10.1016/S0277-5387(00)88094-8. 
  37. ↑ 37.0 37.1 37.2 Tripathi, Rajesh; Ramesh, T. N.; Ellis, Brian L.; Nazar, Linda F. (2010-11-08). "Scalable Synthesis of Tavorite LiFeSO4F and NaFeSO4F Cathode Materials" (in en). Angewandte Chemie International Edition 49 (46): 8738–8742. doi:10.1002/anie.201003743. PMID 20941717. 
  38. ↑ 38.0 38.1 38.2 Ati, M.; Dupont, L.; Recham, N.; Chotard, J.N.; Walker, W.T.; Davoisne, C.; Barpanda, P.; Sarou-Kanian, V. et al. (2010-07-13). "Synthesis, Structural, and Transport Properties of Novel Bihydrated Fluorosulphates NaMSO 4 F·2H 2 O (M = Fe, Co, and Ni)" (in en). Chemistry of Materials 22 (13): 4062–4068. doi:10.1021/cm1010482. ISSN 0897-4756. 
  39. ↑ Long, Zhao; Wei, Liu; Shuang, Liu; lixin, Cao; Ge, Su; Rongjie, Gao (November 2015). "The first anhydrous metal fluorosulfate Na3Fe(SO4)2F2 with layered structure prepared via the interesting "tailor" role of fluorine ions based on Na3Fe(SO4)2" (in en). Inorganica Chimica Acta 438: 191–195. doi:10.1016/j.ica.2015.09.020. 
  40. ↑ Melot, B. C.; Rousse, G.; Chotard, J.-N.; Kemei, M. C.; Rodríguez-Carvajal, J.; Tarascon, J.-M. (2012-03-12). "Magnetic structure and properties of NaFeSO 4 F and NaCoSO 4 F" (in en). Physical Review B 85 (9): 094415. doi:10.1103/PhysRevB.85.094415. ISSN 1098-0121. Bibcode: 2012PhRvB..85i4415M. 
  41. ↑ 41.0 41.1 Bhattacharjee, Manabendra N.; Chaudhuri, Mihir K.; Devi, Meenakshi; Yhome, Khriesavilie (1987). "Direct synthesis of alkali trifluorocobaltate( II ) monohydrates, A[CoF 3 ·H 2 O (A = NH 4 , Na, or K). First synthesis and structural assessment of mixed-ligand fluoro complexes of cobalt( II ), [Co(NH 3 ) 4 F 2 ] and A[CoF(SO 4 )(H 2 O) 2 ](A = NH 4 , Na, or K)"] (in en). J. Chem. Soc., Dalton Trans. (5): 1055–1057. doi:10.1039/DT9870001055. ISSN 0300-9246. http://xlink.rsc.org/?DOI=DT9870001055. 
  42. ↑ Barpanda, Prabeer; Chotard, Jean-Noël; Delacourt, Charles; Reynaud, Marine; Filinchuk, Yaroslav; Armand, Michel; Deschamps, Michael; Tarascon, Jean-Marie (2011-03-07). "LiZnSO4F Made in an Ionic Liquid: A Ceramic Electrolyte Composite for Solid-State Lithium Batteries" (in en). Angewandte Chemie International Edition 50 (11): 2526–2531. doi:10.1002/anie.201006331. PMID 21370330. 
  43. ↑ Zhou, Yang; Zhang, Xingyu; Xiong, Zheyao; Long, Xifa; Li, Yanqiang; Chen, Yangxin; Chen, Xin; Zhao, Sangen et al. (2021-08-23). "Non-π-Conjugated Deep-Ultraviolet Nonlinear Optical Crystal K 2 Zn 3 (SO 4 )(HSO 4 ) 2 F 4" (in en). The Journal of Physical Chemistry Letters 12 (34): 8280–8284. doi:10.1021/acs.jpclett.1c01533. ISSN 1948-7185. PMID 34425677. https://pubs.acs.org/doi/10.1021/acs.jpclett.1c01533. 
  44. ↑ 44.0 44.1 Wang, Xiqu; Liu, Lumei; Ross, Kent; Jacobson, Allan J. (January 2000). "Synthesis and crystal structures of yttrium sulfates Y(OH)(SO4), Y(SO4)F, YNi(OH)3(SO4)-II and Y2Cu(OH)3(SO4)2F·H2O" (in en). Solid State Sciences 2 (1): 109–118. doi:10.1016/S1293-2558(00)00107-2. 
  45. ↑ Jiao, Dong-Xue; Zhang, Hui-Li; Li, Xiao-Fei; He, Chao; Li, Jin-Hua; Wei, Qi; Yang, Guo-Yu (2023-10-12). "YSO 4 F·H 2 O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra" (in en). Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c02632. ISSN 0020-1669. PMID 37823856. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c02632. 
  46. ↑ Godneva, M. M.; Motov, D. L.; Kuznetsov, V. Ya (2002). "Phase formation in the ZrO2 – H2SO4 – LiF(HF) – H2O system" (in ru). Zhurnal Neorganicheskoj Khimii 47 (2): 312–318. ISSN 0044-457X. http://inis.iaea.org/Search/search.aspx?orig_q=RN:34014605. 
  47. ↑ Gong, Ya-Ping; Ma, Yun-Xiang; Ying, Shao-Ming; Mao, Jiang-Gao; Kong, Fang (2019-08-19). "Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)" (in en). Inorganic Chemistry 58 (16): 11155–11163. doi:10.1021/acs.inorgchem.9b01730. ISSN 0020-1669. PMID 31365247. 
  48. ↑ Detkov, D. G.; Gorbunova, Yu. E.; Kazarinova, A. S.; Mikhailov, Yu. N.; Kokunov, Yu. V. (2003). "Polymeric Tin(II) Complexes with Dibasic Nitrogen-Containing Organic Cations. Synthesis and Crystal Structure of (C10H10N2)0.5[SnF(SO4]". Russian Journal of Coordination Chemistry 29 (7): 451–454. doi:10.1023/A:1024721310366. 
  49. ↑ 49.0 49.1 Wang, Qian; Wang, Lei; Zhao, Xiaoyu; Huang, Ling; Gao, Daojiang; Bi, Jian; Wang, Xin; Zou, Guohong (2019). "Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size" (in en). Inorganic Chemistry Frontiers 6 (11): 3125–3132. doi:10.1039/C9QI01036J. ISSN 2052-1553. http://xlink.rsc.org/?DOI=C9QI01036J. 
  50. ↑ 50.0 50.1 Dong, Xuehua; Long, Ying; Zhao, Xiaoyu; Huang, Ling; Zeng, Hongmei; Lin, Zhien; Wang, Xin; Zou, Guohong (22 May 2020). "A6Sb4F12(SO4)3 (A = Rb, Cs): Two Novel Antimony Fluoride Sulfates with Unique Crown-like Clusters". Inorganic Chemistry 59 (12): 8345–8352. doi:10.1021/acs.inorgchem.0c00756. PMID 32441103. 
  51. ↑ "Landolt-Börnstein Substance / Property Index". https://lb.chemie.uni-hamburg.de/static/CN/2_R_rubid.php?content=169/lv12567. 
  52. ↑ 52.0 52.1 Waśkowska, A.; Lis, T. (1988-08-15). "Structure of hexaammonium dodecafluorotrisulfatotetraantimonate(III) at 300 K". Acta Crystallographica Section C: Crystal Structure Communications 44 (8): 1342–1345. doi:10.1107/S0108270188003774. http://scripts.iucr.org/cgi-bin/paper?S0108270188003774. 
  53. ↑ "Landolt-Börnstein Online Search". https://lb.chemie.uni-hamburg.de/search/index.php?content=168/nY8aBeFg. 
  54. ↑ Dong, Xuehua; Huang, Ling; Hu, Cuifang; Zeng, Hongmei; Lin, Zhien; Wang, Xin; Ok, Kang Min; Zou, Guohong (2019-05-13). "CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)‐type Structure" (in en). Angewandte Chemie International Edition 58 (20): 6528–6534. doi:10.1002/anie.201900637. ISSN 1433-7851. PMID 30805990. 
  55. ↑ 55.0 55.1 Wickleder, Mathias S. (1999). "LiLa2F3(SO4)2 und LiEr2F3(SO4)2: Fluoridsulfate der Selten-Erd-Elemente mit Lithium" (in de). Zeitschrift für anorganische und allgemeine Chemie 625 (2): 302–308. doi:10.1002/(SICI)1521-3749(199902)625:2<302::AID-ZAAC302>3.0.CO;2-Y. ISSN 1521-3749. 
  56. ↑ Wu, Chao; Wu, Tianhui; Jiang, Xingxing; Wang, Zujian; Sha, Hongyuan; Lin, Lin; Lin, Zheshuai; Huang, Zhipeng et al. (2021-03-24). "Large Second-Harmonic Response and Giant Birefringence of CeF 2 (SO 4 ) Induced by Highly Polarizable Polyhedra" (in en). Journal of the American Chemical Society 143 (11): 4138–4142. doi:10.1021/jacs.1c00416. ISSN 0002-7863. PMID 33625206. https://pubs.acs.org/doi/10.1021/jacs.1c00416. 
  57. ↑ 57.0 57.1 57.2 Zhou, Wanli; Xu, Yan; Han, Lijie; Zhu, Dunru (2010). "Solvothermal syntheses, crystal structures and luminescence properties of three new lanthanide sulfate fluorides" (in en). Dalton Transactions 39 (15): 3681–6. doi:10.1039/b926131a. ISSN 1477-9226. PMID 20354621. http://xlink.rsc.org/?DOI=b926131a. 
  58. ↑ Wickleder, Mathias S. (2000). "Synthese und Kristallstruktur von NaPr2F3(SO4)2" (in en). Zeitschrift für anorganische und allgemeine Chemie 626 (8): 1723–1724. doi:10.1002/1521-3749(200008)626:8<1723::AID-ZAAC1723>3.0.CO;2-1. ISSN 1521-3749. 
  59. ↑ Wickleder, Mathias S. (1999). "Halogenidsulfate des Gadoliniums: Synthese und Kristallstruktur von GdClSO4 und GdFSO4" (in de). Zeitschrift für anorganische und allgemeine Chemie 625 (5): 725–728. doi:10.1002/(SICI)1521-3749(199905)625:5<725::AID-ZAAC725>3.0.CO;2-T. ISSN 1521-3749. 
  60. ↑ Ptáček, Petr (2016-04-13) (in en). Apatites and their Synthetic Analogues: Synthesis, Structure, Properties and Applications. BoD – Books on Demand. pp. 227. ISBN 978-953-51-2265-4. https://books.google.com/books?id=dmqQDwAAQBAJ&pg=PA227. 
  61. ↑ Zhao, Yanyan; Wang, Chunxiang; Su, Jing; Wang, Yaxing; Wang, Yanlong; Wang, Shuao; Diwu, Juan; Liu, Zhihong (October 2015). "Insights into the new Th (IV) sulfate fluoride complex: Synthesis, crystal structures, and temperature dependent spectroscopic properties" (in en). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 149: 295–303. doi:10.1016/j.saa.2015.04.037. PMID 25965512. 
  62. ↑ Alcock, N. W.; Roberts, M. M.; Chakravorti, M. C. (1980-03-01). "Structure of potassium catena -di-μ-fluoro-difluorotetraoxo-di-μ-sulphato-diuranate(VI) hydrate". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry 36 (3): 687–690. doi:10.1107/S0567740880004141. ISSN 0567-7408. http://scripts.iucr.org/cgi-bin/paper?S0567740880004141. 
  63. ↑ 63.0 63.1 63.2 63.3 63.4 Chakravorti, M.C.; Bharadwaj, P.K. (January 1979). "Fluoro complexes of hexavalent uranium—VII" (in en). Journal of Inorganic and Nuclear Chemistry 41 (8): 1149–1152. doi:10.1016/0022-1902(79)80474-1. 
  64. ↑ Lussier, Aaron J.; Lopez, Rachel A.K.; Burns, Peter C. (January 2016). "A Revised and Expanded Structure Hierarchy of Natural and Synthetic Hexavalent Uranium Compounds" (in en). The Canadian Mineralogist 54 (1): 177–283. doi:10.3749/canmin.1500078. ISSN 0008-4476. Bibcode: 2016CaMin..54..177L. 
  65. ↑ Mikhailov, Yu. N.; Gorbunova, Yu. E.; Mit'kovskaya, E. V.; Serezhkina, L. B.; Serezhkin, V. N. (2002). "Crystal Structure of Rb[UO2(SO4)F]". Radiochemistry 44 (4): 315–318. doi:10.1023/A:1020652306275. 
  66. ↑ 66.0 66.1 66.2 66.3 66.4 66.5 Doran, Michael B.; Cockbain, Ben E.; O'Hare, Dermot (2005). "Structural variation in organically templated uranium sulfate fluorides" (in en). Dalton Transactions (10): 1774–80. doi:10.1039/b504457j. ISSN 1477-9226. PMID 15877147. http://xlink.rsc.org/?DOI=b504457j. 
  67. ↑ Olchowka, Jakub; Volkringer, Christophe; Henry, Natacha; Loiseau, Thierry (March 2014). "Crystal structures of tetravalent uranium fluorides obtained in the presence of hydrazine from uranyl source" (in en). Journal of Fluorine Chemistry 159: 1–7. doi:10.1016/j.jfluchem.2013.12.003. 
Salts and covalent derivatives of the fluoride ion
HF He
LiF BeF2 BF
BF3
B2F4 		CF4
other compounds 		NF3
FN3
N2F2
N2F4
NF5§ 		F2O
F2O2
other compounds 		F2 Ne
NaF MgF2 AlF
AlF3 		SiF4 P2F4
PF3
PF5 		S2F2
SF2
SF4
SF6 		ClF
ClF3
ClF5 		Ar
KF CaF
CaF2 		ScF3 TiF2
TiF3
TiF4 		VF2
VF3
VF4
VF5 		CrF2
CrF3
CrF4
CrF5
CrF6§ 		MnF2 FeF2
FeF3 		CoF2
CoF3 		NiF2 CuF
CuF2 		ZnF2 GaF2
GaF3 		GeF2
GeF4 		AsF3
AsF5 		Se2F2
SeF4
SeF6 		BrF
BrF3
BrF5 		KrF2
RbF SrF
SrF2 		YF3 ZrF3
ZrF4 		NbF4
NbF5 		MoF2
MoF3
MoF4
MoF5
MoF6 		TcF4
TcF6 		RuF3
RuF5
RuF6 		RhF3
RhF5
RhF6 		PdF2 AgF CdF2 InF
InF2
InF3 		SnF2
SnF4 		SbF3
SbF5 		Te3F2
TeF4
TeF6 		IF
IF3</br>IF5</br>IF7 		XeF2
XeF4
XeF6
CsF BaF2   HfF4 TaF5 WF2
WF3
WF4
WF5
WF6 		Re3F9
ReF4
ReF5
ReF6
ReF7 		OsF4
OsF5
OsF6 		IrF2
IrF3
IrF4
IrF5
IrF6 		PtF2
PtF4
PtF5
PtF6 		AuF
AuF3
Au2F10
AuF5•F2 		Hg2F2
HgF2
HgF4 		TlF PbF2
PbF4 		BiF3
BiF5 		PoF2
PoF4
PoF6 		AtF RnF2
FrF RaF2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
LaF3 CeF3
CeF4 		PrF3 NdF2,
NdF3 		PmF3 SmF2,
SmF3 		EuF2,
EuF3 		GdF3 TbF3 DyF2,
DyF3 		HoF3 ErF3 TmF2
TmF3 		YbF2
YbF3 		LuF3
AcF3 ThF4 PaF5 UF3
UF4
UF5
UF6 		NpF4
NpF6 		PuF3
PuF6 		AmF2
AmF3 		CmF3 BkF3 CfF3 EsF3 Fm Md No LrF3

§ means the substance has not been made.

Compounds containing the sulfate group
H2SO4 He
Li2SO4 BeSO4 B esters
ROSO3−
(RO)2SO2 		(NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4 		HOSO4 F Ne
Na2SO4
NaHSO4 		MgSO4 Al2(SO4)3
Al2SO4(OAc)4 		Si P SO42−
HSO3HSO4
(HSO4)2 		Cl Ar
K2SO4
KHSO4 		CaSO4 Sc2(SO4)3 TiOSO4 VSO4
V2(SO4)3
VOSO4 		CrSO4
Cr2(SO4)3 		MnSO4 FeSO4
Fe2(SO4)3 		CoSO4 NiSO4 CuSO4
Cu2SO4
[Cu(NH3)4(H2O)]SO4 		ZnSO4 Ga2(SO4)3 Ge As Se Br Kr
RbHSO4
Rb2SO4 		SrSO4 Y2(SO4)3 Zr(SO4)2 Nb Mo Tc Ru Rh2(SO4)3 PdSO4 Ag2SO4 CdSO4 In2(SO4)3 SnSO4
Sn(SO4)2 		Sb2(SO4)3 Te I Xe
Cs2SO4
CsHSO4 		BaSO4   Hf Ta W Re Os Ir Pt AuSO4
Au2(SO4)3 		Hg2SO4
HgSO4 		Tl2SO4
Tl2(SO4)3 		PbSO4 Bi2(SO4)3 Po At Rn
Fr Ra   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La Ce2(SO4)3
Ce(SO4)2 		Pr2(SO4)3 Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb2(SO4)3 Lu
Ac Th Pa U(SO4)2
UO2SO4 		Np Pu Am Cm Bk Cf Es Fm Md No Lr



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