Chemistry:Fluoride nitrate
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Fluoride nitrates are mixed anion compounds that contain both fluoride ions and nitrate ions. Compounds are known for some amino acids and for some heavy elements. Some transition metal fluorido complexes that are nitrates are also known. There are also fluorido nitrato complex ions known in solution.
List
| name | formula | mw | crystal system | space group | unit cell Å | volume | density | comment | reference |
|---|---|---|---|---|---|---|---|---|---|
| L-Argininium | L-Arg2+•F−•NO3− | triclinic | P1 | a=5.0130 b=10.6161 c=11.0352 α=87.471 β=86.038 γ=78.157 Z=2 | [1] | ||||
| 2L-Arg2+•F−•3NO3−•HF | orthorhombic | P212121 | a=7.3960 b=12.8672 c=26.990 Z=4 | [1] | |||||
| L-histidine | L-His2+•F−•NO3− | [1] | |||||||
| [Cr(NH3)5F](NO3)2 | [2] | ||||||||
| hexakis(1H-imidazole)-cobalt(ii) fluoride nitrate tetrahydrate | [Co(Im)6][F·NO3•(H2O)4] | hexagonal | P63/m | a 8.972 c 21.077 Z=2 | 1469.3 | 1.402 | pink | [3] | |
| [Co(NH3)4(OH)F]NO3 | [4] | ||||||||
| [Co(NH3)5F](NO3)2 | [5] | ||||||||
| [Co(NH3)6]F(NO3)2 | [4] | ||||||||
| [Co(en)2F2]NO3 | [4] | ||||||||
| [As(ONO2)4]+[AsF6]− | pale yellow; hydroscopic | [6] | |||||||
| [Zr2F3OH(NO3)2(H2O)5]2+ | in solution | [7] | |||||||
| SnF2(ONO2)2 | [6] | ||||||||
| SnF3(ONO2) | stable < 40°C; hydroscopic | [6] | |||||||
| SbF(ONO2)4 | [6] | ||||||||
| SbF3(ONO2)2 | [6] | ||||||||
| Xenon fluoride nitrate | FXeONO2 | monoclinic | a = 4.6663 b = 8.799 c = 9.415 β = 90.325° | 386.6 | 3.648 | ||||
| CsFHONO2 | [8] | ||||||||
| [HfF4NO3]− | in solution | [7] | |||||||
| [HfF3(NO3)2]− | in solution | [7] | |||||||
| Hg3O2(NO3)F | orthorhombic | Pnma | a=7.547 b=10.990 c=6.9906 | birefringence Δn = 0.23 @ 1064 nm | [9] | ||||
| Pb3F5NO3 | triclinic | P1 | a 7.3796 b 12.147 c 16.8549, α 100.46° β 90.076° γ 95.517° | layered; stable to 450°C | [10][11] | ||||
| Pb(OF)Cu3(SeO3)2(NO3) | trigonal | R3m | a 6.6973 c 18.5548 Z=3 | 720.75 | 5.175 | yellow; stable to 400°C | [12] | ||
| PbCdF(SeO3)(NO3) | orthorhombic | Pca21 | a=11.121 b=10.366 c=5.3950 | NLO 2.6×KDP; band gap 4.42 eV | [13] | ||||
| BaPb2F5NO3 | [14] | ||||||||
| [(UO2)4F13][Sr3(H2O)8](NO3)·H2O | 1814.13 | triclinic | P1 | a = 10.793, b = 10.918, c = 13.231 α = 92.570°, β = 109.147°, γ = 92.778° Z = 2. | 1468.1 | 4.105 | yellow | [15] |
References
- ↑ 1.0 1.1 1.2 Fleck, Michel; Petrosyan, Aram M. (2014). Salts of amino acids: crystallization, structure and properties. Cham Heidelberg: Springer. pp. 503–507. ISBN 978-3-319-06298-3.
- ↑ Merabet, K. E.; Burriel, Ramón; Carlin, Richard L. (1988-12-01). "Magnetochemistry of chromium(III): Linear-chain – to – simple-cubic crossover magnetic interactions in several halopentammines" (in en). Physical Review B 38 (16): 11589–11592. doi:10.1103/PhysRevB.38.11589. ISSN 0163-1829. https://link.aps.org/doi/10.1103/PhysRevB.38.11589.
- ↑ Jian, Fang Fang; Liu, E.; Ma, Jun Ying (2018). "Interesting fluorine anion water clusters [F − ·(H 2 O) n in metal complex crystals"] (in en). CrystEngComm 20 (27): 3849–3857. doi:10.1039/C8CE00532J. ISSN 1466-8033. http://xlink.rsc.org/?DOI=C8CE00532J.
- ↑ 4.0 4.1 4.2 Chan, S. C.; Poon, C. K. (1966). "Preparation, properties, and isomerisation of aquofluorobis(ethylenediamine)cobalt(III) cations" (in en). Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 146–150. doi:10.1039/j19660000146. ISSN 0022-4944. http://xlink.rsc.org/?DOI=j19660000146.
- ↑ Balt, S.; Pothoff, G. F. (April 1975). "A conductance study of some cobalt(III) complexes in liquid ammonia" (in en). Journal of Solution Chemistry 4 (4): 359–367. doi:10.1007/BF00650393. ISSN 0095-9782. http://link.springer.com/10.1007/BF00650393.
- ↑ 6.0 6.1 6.2 6.3 6.4 Weidlein, Johann; Dehnicke, Kurt (September 1965). "Über die Fluoridnitrate der Elemente Arsen, Antimon und Zinn" (in en). Chemische Berichte 98 (9): 3053–3059. doi:10.1002/cber.19650980939. ISSN 0009-2940. https://onlinelibrary.wiley.com/doi/10.1002/cber.19650980939.
- ↑ 7.0 7.1 7.2 Bertoli, Alexandre C.; Miguita, Ana Gabriella C.; Mingote, Raquel M.; Augusti, Rodinei; Duarte, Hélio A. (2021-03-26). "Unveiling the Zirconium and Hafnium Speciation in Fluoride‐Nitric Acid Solutions by Paper Spray Ionization Mass Spectrometry Combined with DFT Calculations" (in en). European Journal of Inorganic Chemistry 2021 (12): 1175–1185. doi:10.1002/ejic.202001140. ISSN 1434-1948. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202001140.
- ↑ Al-Zamil, Nabila; Delf, Brian W.; Gillard, R.D. (January 1980). "The fluoro-nitrato-hydrogenate(I) anion, [F··H··ONO2−"] (in en). Journal of Inorganic and Nuclear Chemistry 42 (8): 1117–1122. doi:10.1016/0022-1902(80)80420-9. https://linkinghub.elsevier.com/retrieve/pii/0022190280804209.
- ↑ Lv, Yi-Lei; Huai, Lei; Wei, Yu-Long; Ma, Liang; Wei, Yue-Qi; Liu, Wenlong; Tang, Ru-Ling (2023). "Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ∞ cationic framework and excellent optical anisotropy"] (in en). Inorganic Chemistry Frontiers 10 (16): 4845–4853. doi:10.1039/D3QI01146A. ISSN 2052-1553. http://xlink.rsc.org/?DOI=D3QI01146A.
- ↑ Rogow, David L.; Russell, Matthew P.; Wayman, Lora M.; Swanson, Claudia H.; Oliver, Allen G.; Oliver, Scott R. J. (2010-02-03). "Hydrothermal Synthesis and Characterization of Three Cationic Inorganic−Organic Hybrid Materials Based on Lead Fluoride" (in en). Crystal Growth & Design 10 (2): 823–829. doi:10.1021/cg9011923. ISSN 1528-7483. https://pubs.acs.org/doi/10.1021/cg9011923.
- ↑ Tran, Dat T.; Zavalij, Peter Y.; Oliver, Scott R. J. (2002-04-01). "Pb 3 F 5 NO 3 , a Cationic Layered Material for Anion-Exchange" (in en). Journal of the American Chemical Society 124 (15): 3966–3969. doi:10.1021/ja017333w. ISSN 0002-7863. PMID 11942835. https://pubs.acs.org/doi/10.1021/ja017333w.
- ↑ Zhang, Mengsi; Zhao, Zhiying; Zhang, Wanwan; Li, Jinyang; Huang, Xiaoying; He, Zhangzhen (2020). "Pb(OF)Cu 3 (SeO 3 ) 2 (NO 3 ): a selenite fluoride nitrate with a breathing kagomé lattice" (in en). Chemical Communications 56 (80): 11965–11968. doi:10.1039/D0CC03684F. ISSN 1359-7345. PMID 33033813. http://xlink.rsc.org/?DOI=D0CC03684F.
- ↑ Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units" (in en). Inorganic Chemistry 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b02044.
- ↑ CHARKIN, DMITRI O. (2019). "NEW STRUCTURAL ANALOGIES AMONG LAYERED NITRATES AND HALIDES: SYNTHESIS AND STRUCTURE OF A NEW SILLéN-DERIVED FLUORIDE NITRATE, BAPB2F5NO3". https://www.elibrary.ru/item.asp?id=42697541.
- ↑ Jouffret, Laurent J.; Hiltbrunner, Jean-Michel; Rivenet, Murielle; Sergent, Nicolas; Obbade, Saïd; Avignant, Daniel; Dubois, Marc (2016-12-05). "Insight into the Uranyl Oxyfluoride Topologies through the Synthesis, Crystal Structure, and Evidence of a New Oxyfluoride Layer in [(UO 2 ) 4 F 13 [Sr 3 (H 2 O) 8 ](NO 3 )·H 2 O"] (in en). Inorganic Chemistry 55 (23): 12185–12192. doi:10.1021/acs.inorgchem.6b01765. ISSN 0020-1669. PMID 27934437. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01765.
Salts and covalent derivatives of the nitrate ion
| HNO3 | He | ||||||||||||||||
| LiNO3 | Be(NO3)2 | B(NO3)−4 | C | NO−3, NH4NO3 |
O | FNO3 | Ne | ||||||||||
| NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si | P | S | ClONO2 | Ar | ||||||||||
| KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3, Fe(NO3)2 |
Co(NO3)2, Co(NO3)3 |
Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge | As | Se | Br | Kr |
| RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb | Mo | Tc | Ru | Rh | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In | Sn | Sb(NO3)3 | Te | I | Xe(NO3)2 |
| CsNO3 | Ba(NO3)2 | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg2(NO3)2, Hg(NO3)2 |
Tl(NO3)3, TlNO3 |
Pb(NO3)2 | Bi(NO3)3 BiO(NO3) |
Po | At | Rn | |
| FrNO3 | Ra(NO3)2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La(NO3)3 | Ce(NO3)3, Ce(NO3)4 |
Pr | Nd(NO3)3 | Pm | Sm | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy | Ho | Er | Tm | Yb | Lu | |||
| Ac(NO3)3 | Th(NO3)4 | Pa | UO2(NO3)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||
 |  |
