Chemistry:Fluoride nitrate

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Fluoride nitrates are mixed anion compounds that contain both fluoride ions and nitrate ions. Compounds are known for some amino acids and for some heavy elements. Some transition metal fluorido complexes that are nitrates are also known. There are also fluorido nitrato complex ions known in solution.

List

name formula mw crystal system space group unit cell Å volume density comment reference
L-Argininium L-Arg2+•F−•NO3− triclinic P1 a=5.0130 b=10.6161 c=11.0352 α=87.471 β=86.038 γ=78.157 Z=2 [1]
2L-Arg2+•F−•3NO3−•HF orthorhombic P212121 a=7.3960 b=12.8672 c=26.990 Z=4 [1]
L-histidine L-His2+•F−•NO3− [1]
[Cr(NH3)5F](NO3)2 [2]
hexakis(1H-imidazole)-cobalt(ii) fluoride nitrate tetrahydrate [Co(Im)6][F·NO3•(H2O)4] hexagonal P63/m a 8.972 c 21.077 Z=2 1469.3 1.402 pink [3]
[Co(NH3)4(OH)F]NO3 [4]
[Co(NH3)5F](NO3)2 [5]
[Co(NH3)6]F(NO3)2 [4]
[Co(en)2F2]NO3 [4]
[As(ONO2)4]+[AsF6]− pale yellow; hydroscopic [6]
[Zr2F3OH(NO3)2(H2O)5]2+ in solution [7]
SnF2(ONO2)2 [6]
SnF3(ONO2) stable < 40°C; hydroscopic [6]
SbF(ONO2)4 [6]
SbF3(ONO2)2 [6]
Xenon fluoride nitrate FXeONO2 monoclinic a = 4.6663 b = 8.799 c = 9.415 β = 90.325° 386.6 3.648
CsFHONO2 [8]
[HfF4NO3]− in solution [7]
[HfF3(NO3)2]− in solution [7]
Hg3O2(NO3)F orthorhombic Pnma a=7.547 b=10.990 c=6.9906 birefringence Δn = 0.23 @ 1064 nm [9]
Pb3F5NO3 triclinic P1 a 7.3796 b 12.147 c 16.8549, α 100.46° β 90.076° γ 95.517° layered; stable to 450°C [10][11]
Pb(OF)Cu3(SeO3)2(NO3) trigonal R3m a 6.6973 c 18.5548 Z=3 720.75 5.175 yellow; stable to 400°C [12]
PbCdF(SeO3)(NO3) orthorhombic Pca21 a=11.121 b=10.366 c=5.3950 NLO 2.6×KDP; band gap 4.42 eV [13]
BaPb2F5NO3 [14]
[(UO2)4F13][Sr3(H2O)8](NO3)·H2O 1814.13 triclinic P1 a = 10.793, b = 10.918, c = 13.231 α = 92.570°, β = 109.147°, γ = 92.778° Z = 2. 1468.1 4.105 yellow [15]

References

  1. ↑ 1.0 1.1 1.2 Fleck, Michel; Petrosyan, Aram M. (2014). Salts of amino acids: crystallization, structure and properties. Cham Heidelberg: Springer. pp. 503–507. ISBN 978-3-319-06298-3. 
  2. ↑ Merabet, K. E.; Burriel, Ramón; Carlin, Richard L. (1988-12-01). "Magnetochemistry of chromium(III): Linear-chain – to – simple-cubic crossover magnetic interactions in several halopentammines" (in en). Physical Review B 38 (16): 11589–11592. doi:10.1103/PhysRevB.38.11589. ISSN 0163-1829. https://link.aps.org/doi/10.1103/PhysRevB.38.11589. 
  3. ↑ Jian, Fang Fang; Liu, E.; Ma, Jun Ying (2018). "Interesting fluorine anion water clusters [F − ·(H 2 O) n in metal complex crystals"] (in en). CrystEngComm 20 (27): 3849–3857. doi:10.1039/C8CE00532J. ISSN 1466-8033. http://xlink.rsc.org/?DOI=C8CE00532J. 
  4. ↑ 4.0 4.1 4.2 Chan, S. C.; Poon, C. K. (1966). "Preparation, properties, and isomerisation of aquofluorobis(ethylenediamine)cobalt(III) cations" (in en). Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 146–150. doi:10.1039/j19660000146. ISSN 0022-4944. http://xlink.rsc.org/?DOI=j19660000146. 
  5. ↑ Balt, S.; Pothoff, G. F. (April 1975). "A conductance study of some cobalt(III) complexes in liquid ammonia" (in en). Journal of Solution Chemistry 4 (4): 359–367. doi:10.1007/BF00650393. ISSN 0095-9782. http://link.springer.com/10.1007/BF00650393. 
  6. ↑ 6.0 6.1 6.2 6.3 6.4 Weidlein, Johann; Dehnicke, Kurt (September 1965). "Über die Fluoridnitrate der Elemente Arsen, Antimon und Zinn" (in en). Chemische Berichte 98 (9): 3053–3059. doi:10.1002/cber.19650980939. ISSN 0009-2940. https://onlinelibrary.wiley.com/doi/10.1002/cber.19650980939. 
  7. ↑ 7.0 7.1 7.2 Bertoli, Alexandre C.; Miguita, Ana Gabriella C.; Mingote, Raquel M.; Augusti, Rodinei; Duarte, Hélio A. (2021-03-26). "Unveiling the Zirconium and Hafnium Speciation in Fluoride‐Nitric Acid Solutions by Paper Spray Ionization Mass Spectrometry Combined with DFT Calculations" (in en). European Journal of Inorganic Chemistry 2021 (12): 1175–1185. doi:10.1002/ejic.202001140. ISSN 1434-1948. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202001140. 
  8. ↑ Al-Zamil, Nabila; Delf, Brian W.; Gillard, R.D. (January 1980). "The fluoro-nitrato-hydrogenate(I) anion, [F··H··ONO2−"] (in en). Journal of Inorganic and Nuclear Chemistry 42 (8): 1117–1122. doi:10.1016/0022-1902(80)80420-9. https://linkinghub.elsevier.com/retrieve/pii/0022190280804209. 
  9. ↑ Lv, Yi-Lei; Huai, Lei; Wei, Yu-Long; Ma, Liang; Wei, Yue-Qi; Liu, Wenlong; Tang, Ru-Ling (2023). "Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ∞ cationic framework and excellent optical anisotropy"] (in en). Inorganic Chemistry Frontiers 10 (16): 4845–4853. doi:10.1039/D3QI01146A. ISSN 2052-1553. http://xlink.rsc.org/?DOI=D3QI01146A. 
  10. ↑ Rogow, David L.; Russell, Matthew P.; Wayman, Lora M.; Swanson, Claudia H.; Oliver, Allen G.; Oliver, Scott R. J. (2010-02-03). "Hydrothermal Synthesis and Characterization of Three Cationic Inorganic−Organic Hybrid Materials Based on Lead Fluoride" (in en). Crystal Growth & Design 10 (2): 823–829. doi:10.1021/cg9011923. ISSN 1528-7483. https://pubs.acs.org/doi/10.1021/cg9011923. 
  11. ↑ Tran, Dat T.; Zavalij, Peter Y.; Oliver, Scott R. J. (2002-04-01). "Pb 3 F 5 NO 3 , a Cationic Layered Material for Anion-Exchange" (in en). Journal of the American Chemical Society 124 (15): 3966–3969. doi:10.1021/ja017333w. ISSN 0002-7863. PMID 11942835. https://pubs.acs.org/doi/10.1021/ja017333w. 
  12. ↑ Zhang, Mengsi; Zhao, Zhiying; Zhang, Wanwan; Li, Jinyang; Huang, Xiaoying; He, Zhangzhen (2020). "Pb(OF)Cu 3 (SeO 3 ) 2 (NO 3 ): a selenite fluoride nitrate with a breathing kagomé lattice" (in en). Chemical Communications 56 (80): 11965–11968. doi:10.1039/D0CC03684F. ISSN 1359-7345. PMID 33033813. http://xlink.rsc.org/?DOI=D0CC03684F. 
  13. ↑ Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units" (in en). Inorganic Chemistry 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b02044. 
  14. ↑ CHARKIN, DMITRI O. (2019). "NEW STRUCTURAL ANALOGIES AMONG LAYERED NITRATES AND HALIDES: SYNTHESIS AND STRUCTURE OF A NEW SILLéN-DERIVED FLUORIDE NITRATE, BAPB2F5NO3". https://www.elibrary.ru/item.asp?id=42697541. 
  15. ↑ Jouffret, Laurent J.; Hiltbrunner, Jean-Michel; Rivenet, Murielle; Sergent, Nicolas; Obbade, Saïd; Avignant, Daniel; Dubois, Marc (2016-12-05). "Insight into the Uranyl Oxyfluoride Topologies through the Synthesis, Crystal Structure, and Evidence of a New Oxyfluoride Layer in [(UO 2 ) 4 F 13 [Sr 3 (H 2 O) 8 ](NO 3 )·H 2 O"] (in en). Inorganic Chemistry 55 (23): 12185–12192. doi:10.1021/acs.inorgchem.6b01765. ISSN 0020-1669. PMID 27934437. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01765. 
Salts and covalent derivatives of the fluoride ion
HF He
LiF BeF2 BF
BF3
B2F4 		CF4
other compounds 		NF3
FN3
N2F2
N2F4
NF5§ 		F2O
F2O2
other compounds 		F2 Ne
NaF MgF2 AlF
AlF3 		SiF4 P2F4
PF3
PF5 		S2F2
SF2
SF4
SF6 		ClF
ClF3
ClF5 		Ar
KF CaF
CaF2 		ScF3 TiF2
TiF3
TiF4 		VF2
VF3
VF4
VF5 		CrF2
CrF3
CrF4
CrF5
CrF6§ 		MnF2 FeF2
FeF3 		CoF2
CoF3 		NiF2 CuF
CuF2 		ZnF2 GaF2
GaF3 		GeF2
GeF4 		AsF3
AsF5 		Se2F2
SeF4
SeF6 		BrF
BrF3
BrF5 		KrF2
RbF SrF
SrF2 		YF3 ZrF3
ZrF4 		NbF4
NbF5 		MoF2
MoF3
MoF4
MoF5
MoF6 		TcF4
TcF6 		RuF3
RuF5
RuF6 		RhF3
RhF5
RhF6 		PdF2 AgF CdF2 InF
InF2
InF3 		SnF2
SnF4 		SbF3
SbF5 		Te3F2
TeF4
TeF6 		IF
IF3</br>IF5</br>IF7 		XeF2
XeF4
XeF6
CsF BaF2   HfF4 TaF5 WF2
WF3
WF4
WF5
WF6 		Re3F9
ReF4
ReF5
ReF6
ReF7 		OsF4
OsF5
OsF6 		IrF2
IrF3
IrF4
IrF5
IrF6 		PtF2
PtF4
PtF5
PtF6 		AuF
AuF3
Au2F10
AuF5•F2 		Hg2F2
HgF2
HgF4 		TlF PbF2
PbF4 		BiF3
BiF5 		PoF2
PoF4
PoF6 		AtF RnF2
FrF RaF2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
LaF3 CeF3
CeF4 		PrF3 NdF2,
NdF3 		PmF3 SmF2,
SmF3 		EuF2,
EuF3 		GdF3 TbF3 DyF2,
DyF3 		HoF3 ErF3 TmF2
TmF3 		YbF2
YbF3 		LuF3
AcF3 ThF4 PaF5 UF3
UF4
UF5
UF6 		NpF4
NpF6 		PuF3
PuF6 		AmF2
AmF3 		CmF3 BkF3 CfF3 EsF3 Fm Md No LrF3

§ means the substance has not been made.

Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 C NO−3,
NH4NO3 		O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3,
Fe(NO3)2 		Co(NO3)2,
Co(NO3)3 		Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb(NO3)3 Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2 		Tl(NO3)3,
TlNO3 		Pb(NO3)2 Bi(NO3)3
BiO(NO3) 		Po At Rn
FrNO3 Ra(NO3)2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La(NO3)3 Ce(NO3)3,
Ce(NO3)4 		Pr Nd(NO3)3 Pm Sm Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy Ho Er Tm Yb Lu
Ac(NO3)3 Th(NO3)4 Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr



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