Chemistry:Ammonium hexafluorogallate
From HandWiki
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| Names | |
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| IUPAC name
triazanium;gallium;hexafluoride
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| Other names
Triammonium hexafluorogallate(3-)
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| F6GaH12N3 | |
| Molar mass | 237.830 g·mol−1 |
| Appearance | colorless crystals |
| Density | 2.10 g/cm3 |
| soluble | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Ammonium hexafluorogallate is an inorganic chemical compound with the chemical formula (NH
4)
3GaF
6.[1][2]
Synthesis
A mechanochemical reaction between ammonium fluoride and gallium fluoride trihydrate (GaF
3·3H
2O) at a ratio of 3:1 produces the compound.[3]
Also, a reaction of gallium(III) hydroxide, HF, and ammonium fluoride.[4]
- Ga(OH)
3 + 3 HF + 3 NH
4F → (NH)
3GaF
6 + 3 H
2O[5]
- Ga(OH)
Physical properties
Ammonium hexafluorogallate occurs in two polymorphic forms: tetragonal at low temperature and cubic at high temperature, with both transforming reversibly.[6]
It has colorless crystals, which are soluble in water.[7]
References
- ↑ "NCATS Inxight Drugs — AMMONIUM HEXAFLUOROGALLATE" (in en). drugs.ncats.io. https://drugs.ncats.io/drug/4X2AHU48WW.
- ↑ Lide, David R. (29 June 2004) (in en). CRC Handbook of Chemistry and Physics, 85th Edition. CRC Press. p. 4-41. ISBN 978-0-8493-0485-9. https://books.google.com/books?id=WDll8hA006AC&dq=Ammonium+hexafluorogallate&pg=PA14-IA83. Retrieved 31 August 2024.
- ↑ Lu, Jinfeng; Zhang, Qiwu; Wang, Jun; Saito, Fumio (September 2004). "Mechanochemical Synthesis of Ammonium Hexafluorogallate" (in en). Journal of the American Ceramic Society 87 (9): 1814–1816. doi:10.1111/j.1551-2916.2004.01814.x. ISSN 0002-7820. https://ceramics.onlinelibrary.wiley.com/doi/abs/10.1111/j.1551-2916.2004.01814.x. Retrieved 31 August 2024.
- ↑ Perry, Dale L. (19 April 2016) (in en). Handbook of Inorganic Compounds. CRC Press. p. 25. ISBN 978-1-4398-1462-8. https://books.google.com/books?id=SFD30BvPBhoC&dq=Ammonium+hexafluorogallate&pg=PA528. Retrieved 31 August 2024.
- ↑ Brauer, Georg (2 December 2012) (in en). Handbook of Preparative Inorganic Chemistry V1. Elsevier. p. 228. ISBN 978-0-323-16127-5. https://books.google.com/books?id=kaa2qeFRXmUC&dq=Ammonium+hexafluorogallate&pg=PR11. Retrieved 31 August 2024.
- ↑ Beck, Lynda K.; Haendler Kugler, Blanca; Haendler, Helmut M. (1 December 1973). "The thermal decomposition of ammonium hexafluorogallate and ammonium hexafluoroindate. New crystalline forms of gallium fluoride and indium fluoride". Journal of Solid State Chemistry 8 (4): 312–317. doi:10.1016/S0022-4596(73)80027-1. ISSN 0022-4596. https://www.sciencedirect.com/science/article/abs/pii/S0022459673800271. Retrieved 31 August 2024.
- ↑ Grushko, Ya M. (10 September 2020) (in en). Handbook of Dangerous Properties of Inorganic And Organic Substances in Industrial Wastes. CRC Press. p. 79. ISBN 978-1-000-11164-4. https://books.google.com/books?id=1nf8DwAAQBAJ&dq=Ammonium+hexafluorogallate&pg=PA79. Retrieved 31 August 2024.
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