Chemistry:Periodyl fluoride

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Periodyl fluoride
Names
Other names
Periodylfluoride
Identifiers
3D model (JSmol)
Properties
FIO3
Molar mass 193.900 g·mol−1
Appearance colorless crystals
Related compounds
Related compounds
 Iodosyl trifluoride
Perchloryl fluoride
Perbromyl fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Periodyl fluoride is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IO
3F.[1] The compound has been initially synthesized around 1950.[2]

Synthesis

Synthesis of periodyl fluoride is by fluorination of KIO
4 in liquid HF:[3]

KIO
4 + 2HF → IO
3F + KF + H
2O

Physical properties

Periodyl fluoride forms colorless crystals.[4] Decomposes at 90 to 100 °C.[5]

References

  1. ↑ (in en) Advances in Inorganic Chemistry and Radiochemistry. Academic Press. 1 January 1963. p. 84. ISBN 978-0-08-057854-5. https://books.google.com/books?id=pRXIwIV-hB8C&dq=%22Periodyl+fluoride%22&pg=PA84. Retrieved 24 May 2023. 
  2. ↑ So, S. P.; Chau, F. T. (June 1973). "Urey-Bradley Force Field of Perhalyl Fluorides". Zeitschrift für Physikalische Chemie 85 (1–4): 69–75. doi:10.1524/zpch.1973.85.1-4.069. https://www.degruyter.com/document/doi/10.1524/zpch.1973.85.1-4.069/pdf. Retrieved 24 May 2023. 
  3. ↑ Wiberg, Egon; Wiberg, Nils (2001) (in en). Inorganic Chemistry. Academic Press. p. 468. ISBN 978-0-12-352651-9. https://books.google.com/books?id=Mtth5g59dEIC&dq=Iodosyl+trifluoride&pg=PA468. Retrieved 24 May 2023. 
  4. ↑ Haynes, William M. (4 June 2014) (in en). CRC Handbook of Chemistry and Physics. CRC Press. p. 4-67. ISBN 978-1-4822-0868-9. https://books.google.com/books?id=bNDMBQAAQBAJ&dq=iodyl+trifluoride&pg=SA4-PA67. Retrieved 24 May 2023. 
  5. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V5. Elsevier. p. 91. ISBN 978-0-323-14724-8. https://books.google.com/books?id=9AbqU4cI93wC&dq=%22Periodyl+fluoride%22&pg=PA91. Retrieved 24 May 2023. 



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