Chemistry:Carbonate chloride

From HandWiki
Short description: Class of chemical compounds

The carbonate chlorides are double salts containing both carbonate and chloride anions. Quite a few minerals are known. Several artificial compounds have been made. Some complexes have both carbonate and chloride ligands. They are part of the family of halocarbonates. In turn these halocarbonates are a part of mixed anion materials.

The carbonate chlorides do not have a bond from chlorine to carbon, however "chlorocarbonate" has also been used to refer to the chloroformates which contain the group ClC(O)O-.

Formation

Natural

Scapolite is produced in nature by metasomatism, where hot high pressure water solutions of carbon dioxide and sodium chloride modify plagioclase.[1]

Chloroartinite is found in Sorel cements exposed to air.[2]

Minerals

In 2016 27 chloride containing carbonate minerals were known.[3]

name formula crystal system space group unit cell density Optics refractive index Raman spectrum comments reference
Alexkhomyakovite K6(Ca2Na)(CO3)5Cl∙6H2O hexagonal P63/mcm a=9.2691, c=15.8419, V=1178.72 Z = 2 2.25 uniaxial (–), ω=1.543, ε=1.476 [4]
Ashburtonite HPb4Cu4(Si4O12)(HCO3)4(OH)4Cl [3]
Balliranoite (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) hexagonal P63 a=12.695 c=5.325 V=743.2 Z=1 2.48 uniaxial (+), ω=1.523, ε=1.525 [5]
Barstowite Pb4(CO3)Cl6.H2O
Chlorartinite Mg2(CO3)Cl(OH).3H2O
Chlormagaluminite (Mg,Fe2+)4Al2(OH)12(Cl, 0.5 CO3)2·2H2O 6/mmm 1.98-2.09 ε=1.560 ω=1.540 [6]
Davyne can substitute CO3 for SO4 [7]
Decrespignyite-(Y) Y4Cu(CO3)4Cl(OH)5·2H2O V4 bending 694, 718 and 746; V2 bending 791, 815, 837 and 849;v3 antisymmetric stretching 1391, 1414, 1489, 1547; also OH stretching[8] light blue [9]
Defernite Ca3CO3(OH,Cl)4.H2O
Hanksite Na22K(SO4)9(CO3)2Cl hexagonal P63/m a = 10.46 Å

c = 21.19 Å; Z = 2

iowaite Mg6Fe2(Cl,(CO3)0.5)(OH)16·4H2O [10]
Kampfite Ba12(Si11Al5)O31(CO3)8Cl5 monoclinic Cc a = 31.2329, b=5.2398, c=9.0966

β = 106.933°

uniaxial (–), nω = 1.642 nε = 1.594 [11]
Marialite Na4(AlSi3O8)3(Cl2,CO3,SO4)
Mineevite-(Y) Na25BaY2(CO3)11(HCO3)4(SO4)2F2Cl [12]
Northupite Na3Mg(CO3)2Cl octahedral Fd3 Z=16 1.514 v4 bending 714; v3 antisymmetric stretching 1554[8] [13][14]
Phosgenite Pb2CO3Cl2 tetragonal a=8.15 c=8.87 [13]
Reederite-(Y) Na15Y2(CO3)9(SO3F)Cl [12]
Sakhaite (with Harkerite) Ca48Mg16Al(SiO3OH)4(CO3)16(BO3)28·(H2O)3(HCl)3or Ca12Mg4(BO3)7(CO3)4Cl(OH)2·H2O [3]
Scapolite Ca3Na5[Al8Si16O48]Cl(CO3) P42/n a=12.07899 c=7.583467 V=1106.443 [15]
Tatarskite Ca6Mg2(SO4)2(CO3)2(OH)4Cl4•7H2O orthorhombic Biaxial (-) nα = 1.567 nβ = 1.654 nγ = 1.722 [16]
Tunisite NaCa2Al4(CO3)4Cl(OH)8 tetragonal P4/nmm a=11.198 c=6.5637 Z=2
Vasilyevite (Hg2)10O6I3Br2Cl(CO3) P1 overbar a 9.344, b 10.653, c 18.265, α=93.262 β=90.548 γ=115.422° V=1638.3 Z=2 9.57

Artificial

name formula crystal system space group unit cell in Å density comment reference
K5Na2Cu24(CO3)16Cl3(OH)20•12H2O cubic F23 a=15.463 V=3697.5 Z=2 3.044 dark blue [17]
Y8O(OH)15(CO3)3Cl 1197.88 hexagonal P63 a=9.5089 c=14.6730 Z=2 V=1148.97 3.462 [18]
Lu8O(OH)15(CO3)3Cl 1886.32 hexagonal P63 a=9.354 c=14.415 V=1092.3 Z=2 5.689 colourless [19]
Y3(OH)6(CO3)Cl cubic Im3m a=12.66 V=2032 Z=8 3.035 colourless [20]
Dy3(OH)6(CO3)Cl cubic Im3 a=12.4754 V=1941.6 Z=8 4.687 colourless [20]
Er3(OH)6(CO3)Cl cubic Im3m a=12.4127 V=1912.5 Z=8 4.857 pink [20]
K{Mg(H2O)6}2[Ru2(CO3)4Cl2]·4H2O 889.06 monoclinic P21/c a=11.6399 b=11.7048 c=11.8493 β=119.060 V=1411.6 Z=2 2.092 red-brown [21]
K2[{Mg(H2O)4}2Ru2(CO3)4(H2O)Cl]Cl2·2H2O 880.58 orthorhombic Fmm2 a=14.392 b=15.699 c=10.741 V=2426.8 Z=4 2.391 dark brown [21]
trisodium cobalt dicarbonate chloride Na3Co(CO3)2Cl cubic Fd3 a=13.9959 Z=16 2.75 spin-frustrated antiferromagnetic [3][22]
trisodium manganese dicarbonate chloride Na3Mn(CO3)2Cl cubic a=14.163 brown [23]
di-magnesium hexahydrate trihydrogencarbonate chloride Mg2(H2O)6(HCO3)3Cl R3c a=8.22215 c=39.5044 V=2312.85 Z=6 1.61 decompose 125 °C [2]
tripotassium tricalcium selenite tricarbonate chloride K3Ca3(SeO3)(CO3)3Cl 579.97 hexagonal P63 a=10.543 c=7.060 V=706.0 Z=2 2.991 [24]
LiBa9[Si10O25]Cl7(CO3) Z=2 3.85 layer silicate [25][26]
Ba3Cl4CO3 orthorhombic Pnma a=8.407, b=9.589, c=12.483 Z=4 [27]

Complexes

The "lanthaballs" are lanthanoid atom clusters held together by carbonate and other ligands. They can form chlorides. Examples are [La13(ccnm)6(CO3)14(H2O)6(phen)18] Cl3(CO3)·25H2O where ccnm is carbamoylcyanonitrosomethanide and phen is 1,10-phenanthroline. Praseodymium (Pr) or cerium (Ce) can substitute for lanthanum (La).[28] Other lanthanide cluster compounds include :(H3O)6[Dy76O10(OH)138(OAc)20(L)44(H2O)34]•2CO3•4 Cl2•L•2OAc (nicknamed Dy76) and (H3O)6[Dy48O6(OH)84(OAc)4(L)15(hmp)18(H2O)20]•CO3•14Cl•2H2O (termed Dy48-T) with OAc=acetate, and L=3-furancarboxylate and Hhmp=2,2-bis(hydroxymethyl)propionic acid.[29]

Platinum can form complexes with carbonate and chloride ligands, in addition to an amino acid. Examples include the platinum compound [Pt(gluH)Cl(CO3)]2.2H2O gluH=glutamic acid, and Na[Pt(gln)Cl2(CO3)].H2O gln=glutamine.[30] Rhodium complexes include Rh2(bipy)2(CO3)2Cl (bipy=bipyridine)[31]

References

  1. ↑ Harlov, D. E.; Budzyn, B. (December 2008). "The stability of Cl-CO3-scapolite relative to plagioclase + CaCO3 + CaSO4 in the presence of NaCl brines as a function of P-T-XNaCl" (in en). AGUFM 2008: V31C–2156–2156. Bibcode: 2008AGUFM.V31C2156H. 
  2. ↑ 2.0 2.1 Dinnebier, Robert E.; Jansen, Martin (2008-12-01). "The Crystal Structure of [Mg2(H2O)6(HCO3)3]+Cl–, Containing a Magnesium-based Hetero-polycation". Zeitschrift für Naturforschung B 63 (12): 1347–1351. doi:10.1515/znb-2008-1201. ISSN 1865-7117. 
  3. ↑ 3.0 3.1 3.2 3.3 Hazen, Robert M.; Hummer, Daniel R.; Hystad, Grethe; Downs, Robert T.; Golden, Joshua J. (April 2016). "Carbon mineral ecology: Predicting the undiscovered minerals of carbon" (in en). American Mineralogist 101 (4): 889–906. doi:10.2138/am-2016-5546. ISSN 0003-004X. Bibcode: 2016AmMin.101..889H. 
  4. ↑ Pekov, Igor V.; Zubkova, Natalia V.; Yapaskurt, Vasiliy O.; Lykova, Inna S.; Chukanov, Nikita V.; Belakovskiy, Dmitry I.; Britvin, Sergey N.; Turchkova, Anna G. et al. (2019-02-21). "Alexkhomyakovite, K6(Ca2Na)(CO3)5Cl∙6H2O, a new mineral from the Khibiny alkaline complex, Kola peninsula, Russia" (in en). European Journal of Mineralogy 31 (1): 135–143. doi:10.1127/ejm/2018/0030-2798. ISSN 0935-1221. Bibcode: 2019EJMin..31..135P. 
  5. ↑ Chukanov, Nikita V.; Zubkova, Natalia V.; Pekov, Igor V.; Olysych, Lyudmila V.; Bonaccorsi, Elena; Pushcharovsky, Dmitry YU. (2010-03-18). "Balliranoite, (Na,K)6Ca2(Si6Al6O24)Cl2(CO3), a new cancrinite-group mineral from Monte Somma Vesuvio volcanic complex, Italy" (in en). European Journal of Mineralogy 22 (1): 113–119. doi:10.1127/0935-1221/2010/0022-1983. ISSN 0935-1221. Bibcode: 2010EJMin..22..113C. 
  6. ↑ Kashayev, A. A.; Feoktistov, G. D.; Petrova, S. V. (July 1983). "Chlormagaluminite (Mg, Fe 2+ ) 4 Al 2 (OH) 12 (Cl, 1/2 CO 3 ) 2 ·2H 2 O-a new mineral of the manasseite-sjogrenite group" (in en). International Geology Review 25 (7): 848–853. doi:10.1080/00206818309466774. ISSN 0020-6814. Bibcode: 1983IGRv...25..848K. 
  7. ↑ BALLIRANO, PAOLO (1998). "CARBONATEGROUPSIN DAWNE:STRUCTURAL AND CRYSTAL.CHEMICAL CONSIDERATIONs". The Canadian Mineralogist 36: 1285–1292. http://rruff.info/doclib/cm/vol36/CM36_1285.pdf. 
  8. ↑ 8.0 8.1 Frost, Ray L.; Palmer, Sara J. (2011-11-15). "Raman spectrum of decrespignyite [(Y,REE)4Cu(CO3)4Cl(OH)5·2H2O] and its relation with those of other halogenated carbonates including bastnasite, hydroxybastnasite, parisite and northupite" (in en). Journal of Raman Spectroscopy 42 (11): 2042–2048. doi:10.1002/jrs.2959. Bibcode: 2011JRSp...42.2042F. 
  9. ↑ Wallwork, K.; Kolitsch, U.; Pring, A.; Nasdala, L. (February 2002). "Decrespignyite-(Y), a new copper yttrium rare earth carbonate chloride hydrate from Paratoo, South Australia" (in en). Mineralogical Magazine 66 (1): 181–188. doi:10.1180/0026461026610021. ISSN 0026-461X. Bibcode: 2002MinM...66..181W. 
  10. ↑ Frost, R. L.; Erickson, K. L. (2004). "Thermal decomposition of natural iowaite" (in en). Journal of Thermal Analysis and Calorimetry 78 (2): 367–373. doi:10.1023/B:JTAN.0000046103.00586.61. ISSN 1388-6150. https://eprints.qut.edu.au/823/1/Thermal_analysis_of_natural_iowaite2.pdf. 
  11. ↑ "Kampfite: Mineral information, data and localities.". https://www.mindat.org/min-10386.html. 
  12. ↑ 12.0 12.1 Harlov, Daniel E.; Aranovich, Leonid (2018-01-30) (in en). The Role of Halogens in Terrestrial and Extraterrestrial Geochemical Processes: Surface, Crust, and Mantle. Springer. ISBN 978-3-319-61667-4. https://books.google.com/books?id=GtBJDwAAQBAJ&pg=PA135. 
  13. ↑ 13.0 13.1 Ivan Kostov, Ruslan I. Kostov (2016). "Systematics and crystal genesis of carbonate minerals". ANNUAL OF THE UNIVERSITY OF MINING AND GEOLOGY "ST. IVAN RILSKI", Part I, Geology and Geophysics 49: 111–118. http://www.mgu.bg/annual/public_html/2006/bg/svityk1/dokladi_pdf/kostov.pdf. 
  14. ↑ Batsanov, Stepan S.; Ruchkin, Evgeny D.; Poroshina, Inga A. (2016-08-10) (in en). Refractive Indices of Solids. Springer. pp. 61. ISBN 978-981-10-0797-2. https://books.google.com/books?id=yF_SDAAAQBAJ&pg=PA61. 
  15. ↑ Antao, S. M.; Hassan, I. (2011-04-01). "COMPLETE Al-Si ORDER IN SCAPOLITE Me37.5, IDEALLY Ca3Na5[Al8Si16O48]Cl(CO3), AND IMPLICATIONS FOR ANTIPHASE DOMAIN BOUNDARIES (APBs)" (in en). The Canadian Mineralogist 49 (2): 581–586. doi:10.3749/canmin.49.2.581. ISSN 0008-4476. Bibcode: 2011CaMin..49..581A. 
  16. ↑ "Tatarskite: Mineral information, data and localities.". https://www.mindat.org/min-3894.html. 
  17. ↑ Sokolova, Elena; Hawthorne, Frank C. (2003). "The Crystal Structure Of An Anthropogenic Cu–k–na–hydro-Hydroxyl–carbonate–chloride From Johanngeorgenstadt, Saxony, Germany". The Canadian Mineralogist 41 (4): 929–936. doi:10.2113/gscanmin.41.4.929. Bibcode: 2003CaMin..41..929S. 
  18. ↑ Zhang, Yiting; Long, Ying; Dong, Xuehua; Wang, Lei; Huang, Ling; Zeng, Hongmei; Lin, Zhien; Wang, Xin et al. (2019). "Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework" (in en). Chemical Communications 55 (31): 4538–4541. doi:10.1039/C9CC00581A. ISSN 1359-7345. PMID 30924839. 
  19. ↑ Cao, Liling; Song, Yunxia; Peng, Guang; Luo, Min; Yang, Yi; Lin, Chen-sheng; Zhao, Dan; Xu, Feng et al. (2019-03-26). "Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials" (in en). Chemistry of Materials 31 (6): 2130–2137. doi:10.1021/acs.chemmater.9b00068. ISSN 0897-4756. 
  20. ↑ 20.0 20.1 20.2 Wang, Yanyan; Han, Tian; Ding, You-Song; Zheng, Zhiping; Zheng, Yan-Zhen (2016). "Sodalite-like rare-earth carbonates: a study of structural transformation and diluted magnetism" (in en). Dalton Transactions 45 (3): 1103–1110. doi:10.1039/C5DT03314D. ISSN 1477-9226. PMID 26660232. 
  21. ↑ 21.0 21.1 Yang, Jian-Hui; Cheng, Ru-Mei; Jia, Yan-Yan; Jin, Jin; Yang, Bing-Bing; Cao, Zhi; Liu, Bin (2016). "Chlorine and temperature directed self-assembly of Mg–Ru 2 ( ii , iii ) carbonates and particle size dependent magnetic properties" (in en). Dalton Transactions 45 (7): 2945–2954. doi:10.1039/C5DT04463D. ISSN 1477-9226. PMID 26750871. 
  22. ↑ Fu, Zhendong (2012) (in en). Spin Correlations and Excitations in Spin-frustrated Molecular and Molecule-based Magnets. Forschungszentrum Jülich. pp. 97–165. ISBN 978-3-89336-797-9. https://books.google.com/books?id=8rYlCYeLA8cC&pg=PA158. 
  23. ↑ Nawa, Kazuhiro; Okuyama, Daisuke; Avdeev, Maxim; Nojiri, Hiroyuki; Yoshida, Masahiro; Ueta, Daichi; Yoshizawa, Hideki; Sato, Taku J. (2018-10-18). "Degenerate ground state in the classical pyrochlore antiferromagnet Na 3 Mn ( CO 3 ) 2 Cl" (in en). Physical Review B 98 (14): 144426. doi:10.1103/PhysRevB.98.144426. ISSN 2469-9950. Bibcode: 2018PhRvB..98n4426N. 
  24. ↑ Schmitz, Dieter (2001) (in de). Synthese, Charakterisierung und Bildungsprinzipien von sauren und neutralen Oxoselenaten(IV) und Oxoselenat(IV)-hydraten. pp. 182. https://dspace.ub.uni-siegen.de/handle/ubsi/166. 
  25. ↑ "LiBa9[Si10O25Cl7(CO3) (LiBa9Si10[CO3]Cl7O25) Crystal Structure - SpringerMaterials"]. https://materials.springer.com/isp/crystallographic/docs/sd_1005099. 
  26. ↑ Il'Inets, A. M.; Nevskii, N. N.; Ilyukhin, V. V.; Belov, N. V. (March 1983). "A new type of infinite silicate radical [Si10O25] in the synthetic compound LiBa9[Si10O25]CI7(CO3)" (in en). SPHD 28: 213. Bibcode: 1983SPhD...28..213I. 
  27. ↑ Leyva-Bailen, Patricia; Vaqueiro, Paz; Powell, Anthony V. (September 2009). "Ionothermal synthesis of the mixed-anion material, Ba3Cl4CO3" (in en). Journal of Solid State Chemistry 182 (9): 2333–2337. doi:10.1016/j.jssc.2009.06.019. Bibcode: 2009JSSCh.182.2333L. 
  28. ↑ Chesman, Anthony S. R.; Turner, David R.; Langley, Stuart K.; Moubaraki, Boujemaa; Murray, Keith S.; Deacon, Glen B.; Batten, Stuart R. (2015-02-02). "Synthesis and Structure of New Lanthanoid Carbonate "Lanthaballs"" (in en). Inorganic Chemistry 54 (3): 792–800. doi:10.1021/ic5016115. ISSN 0020-1669. PMID 25349948. 
  29. ↑ Li, Xiao-Yu; Su, Hai-Feng; Li, Quan-Wen; Feng, Rui; Bai, Hui-Yun; Chen, Hua-Yu; Xu, Jian; Bu, Xian-He (22 July 2019). "A Giant Dy76 Cluster: A Fused Bi-Nanopillar Structural Model for Lanthanide Clusters". Angewandte Chemie International Edition 58 (30): 10184–10188. doi:10.1002/anie.201903817. PMID 31090998. 
  30. ↑ Shatnawi, Razan Ahmad Mahmoud (November 2013). Synthesis and Characterization of Some Amino Acid Complexes with Metal Ions. Yarmouk University (Article).
  31. ↑ Davidson, G.; Ebsworth, E. A. V. (2007) (in en). Spectroscopic Properties of Inorganic and Organometallic Compounds. Royal Society of Chemistry. p. 294. ISBN 978-1-84755-506-9. https://books.google.com/books?id=VG8oDwAAQBAJ&pg=PA294. 


Carbonates
H2CO3 He
Li2CO3,
LiHCO3 		BeCO3 B C (NH4)2CO3,
NH4HCO3 		O F Ne
Na2CO3,
NaHCO3,
Na3H(CO3)2 		MgCO3,
Mg(HCO3)2 		Al2(CO3)3 Si P S Cl Ar
K2CO3,
KHCO3 		CaCO3,
Ca(HCO3)2 		Sc Ti V Cr MnCO3 FeCO3 CoCO3 NiCO3 CuCO3 ZnCO3 Ga Ge As Se Br Kr
Rb2CO3 SrCO3 Y Zr Nb Mo Tc Ru Rh Pd Ag2CO3 CdCO3 In Sn Sb Te I Xe
Cs2CO3,
CsHCO3 		BaCO3   Hf Ta W Re Os Ir Pt Au Hg Tl2CO3 PbCO3 (BiO)2CO3 Po At Rn
Fr Ra   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La2(CO3)3 Ce2(CO3)3 Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Ac Th Pa UO2CO3 Np Pu Am Cm Bk Cf Es Fm Md No Lr



Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Carbonate_chloride&oldid=3323399"