Chemistry:Palladium hexafluoride

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Palladium hexafluoride
Names
Other names
Palladium(VI) fluoride
Identifiers
3D model (JSmol)
Properties
F6Pd
Molar mass 220.41 g·mol−1
Appearance dark red solid[citation needed]
Related compounds
Related compounds
Platinum hexafluoride, osmium hexafluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Palladium hexafluoride is an inorganic chemical compound of palladium metal and fluorine with the chemical formula PdF
6
.[1] It is reported to be a still hypothetical compound.[2] This is one of many palladium fluorides.

Synthesis

Fluorination of palladium powder with atomic fluoride at 900–1700 Pa.[3]

Physical properties

Palladium hexafluoride is predicted to be stable.[4] The compound is reported to form dark red solid that decomposes to PdF
4
. Palladium hexafluoride is a very powerful oxidizing agent.[3]

References

  1. "Palladium hexafluoride" (in en). Russian Journal of Inorganic Chemistry (British Library Lending Division with the cooperation of the Royal Society of Chemistry) 29 (1–6): 283. 1984. https://books.google.com/books?id=K1pHAQAAIAAJ&q=palladium+hexafluoride. Retrieved 29 March 2023. 
  2. David, Jorge; Fuentealba, Patricio; Restrepo, Albeiro. "Relativistic effects on the hexafluorides of group 10 metals". https://repositorio.uchile.cl/bitstream/handle/2250/118930/David_Jorge.pdf?sequence=1. 
  3. 3.0 3.1 Griffith, William P.; Robinson, Stephen D.; Swars, Kurt (29 June 2013) (in en). Pd Palladium: Palladium Compounds. Springer Science & Business Media. p. 48. ISBN 978-3-662-09188-3. https://books.google.com/books?id=Y2XsCAAAQBAJ&dq=palladium+hexafluoride&pg=PA48. Retrieved 29 March 2023. 
  4. Aullón, Gabriel; Alvarez, Santiago (1 April 2007). "On the Existence of Molecular Palladium(VI) Compounds: Palladium Hexafluoride" (in en). Inorganic Chemistry 46 (7): 2700–2703. doi:10.1021/ic0623819. ISSN 0020-1669. PMID 17326630. https://pubs.acs.org/doi/10.1021/ic0623819. Retrieved 29 March 2023.